全文获取类型
收费全文 | 162篇 |
免费 | 6篇 |
国内免费 | 3篇 |
专业分类
化学 | 134篇 |
力学 | 5篇 |
数学 | 11篇 |
物理学 | 21篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2021年 | 2篇 |
2020年 | 6篇 |
2019年 | 3篇 |
2018年 | 1篇 |
2016年 | 1篇 |
2015年 | 4篇 |
2014年 | 4篇 |
2013年 | 4篇 |
2012年 | 7篇 |
2011年 | 14篇 |
2010年 | 13篇 |
2009年 | 7篇 |
2008年 | 12篇 |
2007年 | 10篇 |
2006年 | 8篇 |
2005年 | 10篇 |
2004年 | 9篇 |
2003年 | 4篇 |
2002年 | 2篇 |
2001年 | 4篇 |
2000年 | 3篇 |
1999年 | 2篇 |
1996年 | 2篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1990年 | 3篇 |
1989年 | 1篇 |
1988年 | 4篇 |
1986年 | 1篇 |
1985年 | 3篇 |
1982年 | 1篇 |
1981年 | 3篇 |
1980年 | 3篇 |
1979年 | 1篇 |
1976年 | 1篇 |
1973年 | 3篇 |
1972年 | 1篇 |
1969年 | 1篇 |
1958年 | 1篇 |
1942年 | 1篇 |
排序方式: 共有171条查询结果,搜索用时 19 毫秒
1.
S. Homma-Takeda Y. Nishimura Y. Watanabe H. Imaseki M. Yukawa 《Journal of Radioanalytical and Nuclear Chemistry》2004,259(3):521-525
Stage-specific and age-dependent profiles of zinc, copper, manganese, and selenium in testis were examined in Wistar rats
by both inductively coupled argon plasma-mass spectrometry (ICP-MS) with a microdissection technique and in situ elemental
imaging of micro-PIXE analysis. The young adult animals (10 weeks old) contained higher levels of zinc and manganese in the
seminiferous tubules at stages VII-VIII than stages XI through VI and IX-X and the levels were higher than those of the immature
and old animals. Copper and selenium levels at stages VII-VIII of the young adult animals were also higher than those of the
immature and old animals. In stages VII and VIII, zinc was higher in the central area of the seminiferous epithelium, where
spermatozoa were localized, demonstrating a cell-specific property.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
2.
X.P. Zhu Tomiyuki Yukawa Hisayuki Suematsu Kiyoshi Yatsui Y. Inoue 《Applied Surface Science》2006,252(16):5776-5782
X-ray photoelectron spectroscopy (XPS) is used to probe oxidation states of Si species in particles deposited using a pulsed ion-beam evaporation method. The effects of He ambient gas, ion beam intensity and post-treatments on the oxides composition and oxygen content have been studied. It is found that presence of He ambient gas led to a profound oxidation of Si species as compared to that prepared in vacuum at the same ion-beam ablation energy, i.e. both increase of SiO2 component and oxygen concentration in the oxides coverage. The deposition in He also resulted in an increase of oxygen concentration even under lower ablation intensity, but a higher Si suboxides concentration. It is revealed that the reaction between Si and O was controlled by the ion beam intensity (temperature of Si plasma) and the gas ambient (collision probability of Si and O species). The difference in structure of oxide layers for samples obtained under various conditions is discussed based on the results of XPS analyses. 相似文献
3.
We prove that the coinvariant ring of the irreducible Coxeter group of type H4 has the strong Lefschetz property. 相似文献
4.
The mechanisms of nitrosation of acetone through sodium enolate [CH3CO1CH2]-Na+ (1) or naked enolate [CH3CO1CH2]- (2) with methyl nitrite CH3O3NO2 (3), and the reactivity of the syn-form of 3 (syn-3) during the C-N bond formation process were investigated using ab initio molecular orbital (MO) methods. Our results have demonstrated the predominant formation of E-1-hydroxyimino-2-oxo-propane CH3COCH=NOH (4E) when the complex [CH3CO1CH2NO2(O3CH3)]-Na+ was produced kinetically via a metal-chelated pericyclic transition state (TS(CHELATED)), in which the O3 atom of syn-3 was coordinated to the Na+ atom of 1. 相似文献
5.
Three acyclic polythioethers containing 2-thienyl units at both ends were synthesized and the effect of substituent on the extraction of copper(II) was studied. The methyl groups in the terminal thiophene ring have imparted an appreciable degree of increase in the percent extraction of copper(II), while the introduction of chlorine atoms into the 2-thienyl unit resulted in the reverse effect. Among the counter dye anions examined, tetrabromophenolphthalein ethylester was the best one for copper(II) extraction. The composition of extracted species was evaluated to be 122 (Cu(II)/polythioether/dye anion). Quantitative extraction of copper(I) was attained as complexes with various triphenylmethane dyes, i.e., bromocresol green, bromothymol blue, bromo-phenol blue and pyrogallol red. Copper(I) in organic phase was completely back-extracted with 2 mole/l sulfuric acid containing 10% hydrogen peroxide. 相似文献
6.
Yasuhide Yukawa Hisao Morisaki Kiyoshi Tsuji Seung-Geon Kim Takashi Ando 《Tetrahedron letters》1981,22(51):5187-5190
The behavior of ion pairs in the trifluoroacetolysis of 2-arylethyl arenesulfonates was studied by means of tracer techniques with deuterium and oxygen-18. 相似文献
7.
The resonance Raman spectra of tris(acetylacetonatoiron(III)) and ruthenium(III) complexes in various solvents and in water-acetonitrile (W-AN) mixtures were measured. The resonance Raman spectra of both complexes indicated peaks near 460 and around 1580 cm–1. Thev(C-O) peak (around 1580 cm–1) is shifted to low frequency with an increase in the dielectric constant T of the solvents, whereas thev(M-O) (M=Fe and Ru, near 460 cm–1) are constant, independent of T. It implies that the C-O bond in the acac– ligand is lengthened by the polarizability effect of the solvents, while both the Fe-O and Ru-O bonds, which are located in the inside of the complexes, are not influenced by the solvents indicating that the interaction does not depend on the properties of individual solvent molecules but on those of the aggregate. 相似文献
8.
Fukui K Naito Y Akiyama Y Takahashi K 《European journal of mass spectrometry (Chichester, England)》2004,10(5):639-647
In this study, the fragmentation of gas-phase protonated Angiotensin II is investigated using electrospray ionization (ESI), Fourier-transform ion cyclotron resonance (FT-ICR), and mass spectrometry (MS) with a laser cleavage infrared multiphoton dissociation (IRMPD) technique. The experimental results show that the spectra peaks for the photoproducts are y2/b6- and y7-type ions, corresponding to the cleavage of His-Pro and Asp-Arg in the parent amino acid sequence. The fragmentation of the peptide under collision-free vacuum conditions is modeled using molecular dynamics simulations (MD). The binding energy for the peptide bonds (C'-N bond) of Angiotensin II is estimated from ab initio calculations. The calculations are directed at predicting experimental measurements of the product ions from the photodissociation of the peptide. The product distributions simulated by the MD dissociation trajectories include predominantly y7/b1 and y2/b6 pair ions. 相似文献
9.
Yasuhide Nakayama Takehisa Matsuda 《Journal of polymer science. Part A, Polymer chemistry》1992,30(11):2451-2457
The reaction of copolymer of N,N-dimethylacrylamide (DMAA) and bromoethyl methacrylate with potassium cinnamate produced water-soluble photosensitive polymers. Photosensitive polyDMAA films were irradiated with a 400 W high-pressure mercury lamp (λ > 280 nm) to produce crosslinked polymers, which were swollen in water. The degree of swelling was controlled by the irradiation time and content of cinnamate moieties in copolymers. Higher cinnamoylation and longer irradiation time resulted in higher yield of crosslinked polymers and less swellability. Partial degelation upon irradiation at λ ~ 254 nm was observed. The advantage of gelation via photodimerization over conventional chemical crosslinking methods is discussed in conjunction with biomedical applications. © 1992 John Wiley & Sons, Inc. 相似文献
10.
Ogata M Kaneya D Shin-Ya K Li L Abe Y Katoh H Seki S Seki Y Gonda R Urano S Endo T 《Chemical & pharmaceutical bulletin》2005,53(9):1167-1170
Many researchers have stated that eugenol might inhibit lipid peroxidation at the stage of initiation, propagation, or both, and many attempts have been made to elucidate the mechanism of its antioxidant activity. Nevertheless, details of its mechanism are still obscure. This study was carried out to investigate the trapping effect of eugenol on hydroxyl radical generated from L-3,4-dihydroxyphenylalanine (DOPA) in MiliQ water and the generation mechanism of the hydroxyl radical by this system which uses no metallic factor. This was studied by adding L-DOPA and 5,5-dimethyl-1-pyrroline N-oxide (DMPO) to phosphate buffered saline (PBS) or MiliQ water, and the generation of hydroxyl radical was detected on an ESR spectrum. By this method, the effect of antioxidants was detected as a modification of ESR spectra. We found that the eugenol trapped hydroxyl radicals directly, because it had no iron chelating action, did not trap L-DOPA semiquinone radical and inhibited hydroxyl radicals with or without iron ion. 相似文献