Pt对Mo基催化剂还原-硫化过程的影响

采用脉冲硫化、连续硫化、程序升温还原、程序升温及程序降温电导及X射线衍射等方法研究了贵金属Pt对MoO3催化剂还原-流化过程的影响及Pt对MOS2配位不饱和活性中心形成的影响．结果表明，Pt担载或在MoO3上可以促进MoO3的还原-硫化，使MoO3的还原-硫化温度大大降低Pt担载在MoSw上可促进MoS2的部分还原形成配位不饱和的钼中心     

Mg(ClO4)2-catalyzed intramolecular allylic amination: application to the total synthesis of demethoxyfumitremorgin C

A Mg(ClO₄)₂-catalyzed intramolecular amination of allylic alcohols with carbamate or sulfonamide nucleophiles to form substituted piperidine and pyrrolidine derivatives has been developed. This method has been successfully applied to the total synthesis of demethoxyfumitremorgin C.     

Suspension quality and power consumption of the complex multiphase flow field in a draft-tube stirred reactor

Experiment and simulation were used to study the flow fields of a liquid-solid-solid three-phase system in a draft-tube stirred reactor with a six-flat-bladed t...     

Total synthesis of (+)-lysergic acid

A stereocontrolled total synthesis of (+)-lysergic acid (1) is achieved using three metal-catalyzed methodologies for the construction of three key rings. Highlights of the synthesis include Pd-catalyzed indole synthesis to form the B ring, a RCM reaction to form the D ring, and an intramolecular Heck reaction to form the C ring.     

光纤激光阵列目标在回路自适应光学系统的数值模拟

研究了光纤激光阵列目标在回路自适应光学系统在实际大气环境中的传输.从光纤激光阵列、激光在大气中的传输、目标和优化算法四个方面,建立了光纤激光阵列目标在回路自适应光学系统的理论模型.在不同强度大气湍流下,对系统补偿大气湍流影响的效果进行了研究,并对系统控制参数优化进行了简单探讨.结果表明,目标在回路闭环控制结构能够有效补...     

质子交换MgO:LiNbO3波导的双层结构

本文报导MgO:LiN_bO₃质子交换波导X射线双晶衍射和红外吸收的实验结果。这些结果表明质子交换波导由浅表面层和深表面层构成。浅表面层是一个连续应变层,有着大量随机排列的O—H—O形式的缔合OH^-基团。深表面层是一个均匀应变层,其内H⁺以自由OH^-基团形式出现。质子交换波导折射串不稳定性与双层结构中的结构驰豫密切相关。通过对质子交换过程的分析,提出两条避免双层结构的途径,其一为降低交换剂中的H⁺浓度,另一条是采用有限源工艺。     

Simultaneous spectrum and coherent combining by active phasing dual two-tone all-fiber MOPA chains

We present a new approach for simultaneous spectral and coherent combining in a master oscillator power amplifier (MOPA) configuration with active phasing. Spectrally combined single-frequency seed lasers are employed as a master oscillator for the all-fiber power amplifier chain, which provides robust performance suppressing of the stimulated Brillouin scattering effect, while coherent combining of spectrally combined amplifiers with active phase control provides stable in-phase combining, despite the strong phase fluctuation. In experiments, two spectrally combined seed MOPA chains are coherently combined with a total output power of 390 W. The power of the main lobe in the closed loop is two times of that value in the open loop, and visibility of more than 75% of the long-exposure interference pattern at the receiving plane is obtained.     

First-principles study on the Ni@Pt12 Ih core-shell nanoparticles: A good catalyst for oxygen reduction reaction

The adsorption, diffusion and dissociation properties of O₂ on the icosahedron (Ih) Ni@Pt12 core-shell nanoparticle were investigated using the ab initio density functional theory calculations. It is found that, compared with the Pt(111) surface, the Ih Ni@Pt12 core-shell nanoparticle can enhance the adsorption, diffusion and dissociation of O₂, as well as the adsorption and diffusion of the atomic O (the dissociation product of O₂), and therefore serve as a good catalyst for oxygen reduction reaction. Our study gives a reasonable theoretical explanation to the high catalytic activity of the Ni@Pt core-shell nanoparticles for the oxygen reduction reaction.     

Formal synthesis of semiaquilegin A

A formal synthesis of semiaquilegin A is achieved starting from readily available oridonin in 19 linear steps. The absolute configuration of the natural product has been established. A variety of useful analogues were prepared through this synthetic route.