聚乙烯基咔唑与Alq3混合薄膜的发光性能与能量传递过程

研究了Alq3与聚乙烯基咔唑(PVK)按不同比例的混合体系制备的薄膜的发光特性.通过对混合薄膜的吸收光谱、激发光谱和发射光谱的分析，研究了PVK与Alq3之间的 能量传递规律.当Alq3与PVK的质量比为1∶7时，能量传递效率最高.用一个由单链模 型扩展到包括杂质的哈密顿量对实验进行模拟，发现该模型能够较好地解释有关的实验结果. 关键词： 吸收光谱 激发光谱 发射光谱 能量传递     

混合范数空间中函数的Taylor系数

本文研究了混合范数空间Ｈ（ｐ，ｑ，ａ）中解析函数ｆ的Ｔａｙｌｏｒ系数，对０＜ｐ≤２，０＜ｑ＜∞，ａ＞０和２≤ｐ＜∞，０＜ｑ＜∞，ａ＞０两种情形，分别给出了ｆ属于Ｈ（ｐ，ｑ，ａ）的必要条件和充分条件。用上述结果我们还得到了几个关于混合范数空间的乘子定理，这些结果也推广了Ｈａｒｄｙ和Ｌｉｔｔｌｅｗｏｏｄ关于Ｈ＾ｐ空间的相应结论。     

α-乙酰基二硫缩烯酮α碳原子的酰化反应

进行了α-乙酰基二硫缩烯酮与酰氯的酰化反应. 以干燥的二氯甲烷为溶剂, 在四氯化钛催化下, α-乙酰基环二硫缩烯酮(1)可与脂肪及芳酰氯(2)反应, 在化合物1的α-碳原子上发生酰化反应, 以较高的产率生成各种α-乙酰基-α-酰基二硫缩烯酮(3).     

硫/水热碳球复合材料的制备及对锂硫电池倍率性能的影响

在锂硫电池正极材料的研究中,碳材料可以有效改善电池倍率及循环性能.为了提高锂硫电池的高倍率放电性能,通过水热合成的方法,制备了由非均匀粒径碳球组成的碳材料.与硫热合成后,硫均匀分布在碳材料表面及周围,复合材料含硫量为52wt%.0.2C放电电流下,首次放电比容量为1174mAh·g^-1,100次循环后放电比容量为788mAh·g^-1.在4C的放电电流下,放电比容量稳定维持在600mAh·g^-1,循环过程中,库伦效率高于90%.该碳材料有良好的导电网络,且制备方便,成本低廉,对于穿梭效应和放电过程中的膨胀效应有一定的抑制作用,是一种优秀的正极材料.     

Synthesis and electrochemical performance of LiNi0.6Co0.2Mn0.2O2 as a concentration-gradient cathode material for lithium batteries

A well-ordered and spherical LiNi0.6Co0.2Mn0.2O2 cathode material was successfully synthesized from Ni and Mn concentration-gradient precursors via co-precipitation. The crystal structure, morphology and electrochemical properties of LiNi0.6Co0.2Mn0.2O2 were characterized by X-ray diffraction, scanning electron microscopy, energy-dispersive spectroscopy, and charge-discharge tests. The material delivered an initial discharge capacity of 174.3 mAh/g at 180 mA/g （1 C rate） between 2.8 and 4.3 V and more than 93.1% of that was retained after 100 cycles. In addition, it also exhibited excellent rate capability, high cut-off voltage and temperature performance.     

In-situ polymerized cross-linked binder for cathode in lithium-sulfur batteries

Volume expansion and polysulfide shuttle effect are the main barriers for the commercialization of lithium-sulfur(Li-S) battery.In this work,we in-situ polymerized a cross-linked binder in sulfur cathode to solve the aforementioned problems using a facile method under mild conditions.Polycarbonate diol(PCDL),triethanolamine(TEA) and hexamethylene diisocyanate(HDI) were chosen as precursors to prepare the cross-linked binder.The in-situ polymerized binder(PTH) builds a strong network in sulfur cathode,which could restrain the volume expansion of sulfu r.Moreover,by adopting functional groups of oxygen atoms and nitrogen atoms,the binder could effectively facilitate transportation of Li-ion and adsorb polysulfide chemically.The Li-S battery with bare sulfur and carbon/sulfur composite cathodes and cross-linked PTH binder displays much better electrochemical performance than that of the battery with PVDF.The PTH-bare S cathode with a mass loading of 5.97 mg/cm^2 could deliver a capacity of 733.3 mAh/g at 0.2 C,and remained 585.5 mAh/g after 100 cycles.This in-situ polymerized binder is proved to be quite effective on restraining the volume expansion and suppressing polysulfide shuttle effect,then improving the electrochemical performance of Li-S battery.     

Revisiting radiative leptonic B decay

In this paper, we summarize the existing methods of solving the evolution equation of the leading-twist \begin{document}$B$\end{document}-meson LCDA. Then, in the Mellin space, we derive a factorization formula with next-to-leading-logarithmic (NLL) resummation for the form factors \begin{document}$F_{A,V}$\end{document} in the \begin{document}$B \to \gamma \ell\nu$\end{document} decay at leading power in \begin{document}$\Lambda/m_b$\end{document}. Furthermore, we investigate the power suppressed local contributions, factorizable non-local contributions (which are suppressed by \begin{document}$1/E_\gamma$\end{document} and \begin{document}$1/m_b$\end{document}), and soft contributions to the form factors. In the numerical analysis, which employs the two-loop-level hard function and the jet function, we find that both the resummation effect and the power corrections can sizably decrease the form factors. Finally, the integrated branching ratios are also calculated for comparison with future experimental data.     

合成温度对全梯度正极材料LiNi0.7Co0.15Mn0.15O2的结构和电化学性能影响

通过控制结晶法和浓度梯度进料的方式制备了Ni、Co和Mn三元素组分含量呈全梯度分布的类球形Ni_0.7Co_0.15Mn_0.15（OH）₂前驱体,与LiOH·H₂O均匀混合并焙烧后获得LiNi_0.7Co_0.15Mn_0.15O₂正极材料,系统研究了不同焙烧温度对材料Ni、Co和Mn三元素扩散情况、晶体结构及电化学性能的影响规律。通过能谱仪（EDXS）分析不同焙烧温度下材料颗粒中Ni、Co、Mn三元素的扩散程度。研究结果表明,在800℃下焙烧得到的正极材料梯度分布特征明显且电化学性能最佳,首次放电比容量为186.1 mAh·g^-1（2.8~4.3 V,0.2C）,2C大倍率充放电条件下循环200次后容量保持率为90.1%。这种材料兼具高比容量及良好的循环稳定性,可以用作下一代高能量密度锂离子电池正极材料。