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为提高土壤多元素同时检测的效率,采用超级微波消解-电感耦合等离子体发射光谱法测定土壤中钾、钠、钙、镁、铜、铁、锰、锌、磷、硫、硼、砷、镉、铬、铅、钴、镓、锂等18种元素含量。比较了超级微波消解、常规微波消解和电热板消解的处理效果,采用超级微波消解法对样品进行前处理,并优化了消解条件。在最优条件下,各元素的检出限在0.05~20 mg/kg,加标回收率在86.2%~107.5%,RSD在0.1%~3.0%,方法准确度及精密度可以满足多元素同时测定的需求,且该方法具有简单、快速、成本低、用酸量少、重现性好等特点。 相似文献
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Svetlana I. Kulakovskaya Tatyana S. Zyubina Alexander S. Zyubin Alexander V. Kulikov Alexander G. Ryabenko Ekaterina V. Zolotukhina Yuriy A. Dobrovolskiy 《中国化学会会志》2023,70(3):394-404
Catalytic oxidation of methanol (MeOH) in the absence of noble metals and noble metal oxides as catalysts, and the use of metal-free materials are inexpensive and attractive process for practical use in electrocatalysis, sensors, and in direct methanol fuel cells. In previous works, it was found that the use of single-walled (SWCNT) or multi-walled (MWCNT) carbon nanotube paper electrodes instead of GC increases the catalytic efficiency of organic compounds oxidation in the presence of aromatic di-N-oxides by several times. In this work, the effect of non-covalent interactions on the catalytic efficiency of MeOH oxidation in the presence of 2,5-di-Me-pyrazine-di-N-oxide (Pyr1) in 0.1 M Bu4NClO4 solution in acetonitrile at SWCNT and MWСNT paper electrodes was studied by the methods of quantum chemical modeling, Raman spectroscopy, and using electrochemical data. New factors determined the features of mechanism of MeOH oxidation on CNT electrodes and lead to an increase in the catalytic efficiency of the electrode process in comparison with the GC electrode were established. 相似文献
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Oleksandr V. Dobrovolskiy Evgeniya Begun Michael Huth Valerij A. Shklovskij Menachem I. Tsindlekht 《Physica C: Superconductivity and its Applications》2011,471(15-16):449-452
An advanced mask-less nanofabrication technique, focused electron beam-induced deposition (FEBID), has been employed on epitaxial Nb thin films to prepare ferromagnetic decorations in the form of an array of Co stripes. These substantially modify the non-patterned films’ superconducting properties, providing a washboard-like pinning potential landscape for the vortex motion. At small magnetic fields B ? 0.1 T, vortex lattice matching effects have been investigated by magneto-transport measurements. Step-like drops in the field dependencies of the films resistivity ρ(B) have been observed in particular for the vortex motion perpendicular to the Co stripes. The field values, corresponding to the middle points of these drops in ρ(B), meet the vortex lattice parameter matching the pinning structure’s period. These disagree with the results of Jaque et al. (2002) [11], who observed matching effects corresponding to the stripe width in Nb films grown on periodically distributed submicrometric lines of Ni. 相似文献
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A dielectric distributed Bragg reflector (DBR) formed by four pairs of hydrogenated amorphous silicon/silicon nitride layers is used as the back reflector in thin-film silicon solar cells. The DBR was designed to perform in a broad wavelength range with the peak reflectance at 600 nm. The DBR was fabricated at low substrate temperature (172 °C) and applied at the rear side of flat and textured amorphous silicon single-junction solar cells in both superstrate (pin) and substrate (nip) configurations. The spectral response and electrical I–V characteristics were measured. Solar cells with optimized DBR exhibit an enhanced external quantum efficiency in the long wavelength range and the electrical performance is comparable to solar cells having conventional Ag back reflector. 相似文献
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Ruslan V. Vovk Georgij Ya. Khadzhai Oleksandr V. Dobrovolskiy 《Applied Physics A: Materials Science & Processing》2014,114(3):997-1002
A single-sized dielectric cylinder-based metamaterial is fabricated from TiO2 nanoparticles, using a bottom-up approach. The sub-elements constituting the metalayer are embedded in a nonmagnetic transparent host matrix in the microwave regime and arranged in a square lattice. We demonstrate numerically and experimentally a broadband magnetic activity. The key feature to achieve this performance remains in the high aspect ratio of the metamaterial building blocks. This is a very promising step towards complex electromagnetic functions, involving low-cost metamaterials with simple fabrication. 相似文献
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In this paper we study the dispersion relation of thermal non-neutral plasma column by MHD theory. We use the dispersion relation to discuss the stability and dispersive properties in a non-neutral plasma-filled waveguide. The results are in agreement with those of cold non-neutral plasma. 相似文献