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1.
2.
NaY zeolite samples loaded with sodium metal by vapor phase deposition have been investigated using129Xe NMR spectroscopy. At low sodium concentration, the129Xe NMR spectrum showed three resonance lines which clearly indicate the existence of distinct domains in the zeolite sample. Such an observation suggests that the diffusion of the xenon atoms into each domain only occurs with respect to the NMR time scale (2.9 ms). As the sodium concentration increases, observation of a single broad line indicate a macroscopic homogenization of the system. The shift of this line is explained in part due to a paramagnetic interaction between the xenon atoms and the unpaired electrons of particles containing an odd number of sodium atoms. The linewidth is due to the distribution of the local magnetic fields partially averaged by the rapid motion of the xenon atoms and to the statistical distribution of the sodium particles in the supercage cavities. The paramagnetic interaction vanishes with the oxidation of the sample leading to a narrowing and a shift of the line to higher magnetic fields. 相似文献
3.
4.
K Kawasaki T Tsuji K Hirase M Miyano Y Imoto M Iwamoto 《Chemical & pharmaceutical bulletin》1991,39(3):584-589
N-Terminal tripeptide analogs of fibrin alpha-chain were synthesized and their inhibitory effect on fibrinogen/thrombin clotting was examined. A new water-soluble active ester, 3-pyridinium ester, was used for the synthesis. Among the synthetic peptides, H-Gly-Pro-Arg-hexamethyleneimine exhibited the highest inhibitory effect on fibrinogen-thrombin clotting. 相似文献
5.
The structural properties of polycrystalline silicon films, prepared by plasma enhanced chemical vapor deposition system, with different flow rates of SiH4/SiF4 mixtures at 300 °C were investigated. This study indicates that the low hydrogen coverage on the growing surface, under optimum fluorine radicals, will be leaded to an improvement of crystallized area as compared with case of high hydrogen coverage surface. Moreover, the studies of the role of SiH4 and SiF4 radicals show that the SiH4 radicals are important in the nucleation and growth of grains. However, SiF4 radicals are effective in the structural change of grain boundaries regions and by this way, in the present system, establish the growth of grains under the dominant 〈1 1 0〉 direction. The stress investigation indicates that addition of high flow rate of SiF4 in amorphous film, results in the nearly stress free films. Finally, we found that the changes in g-value reflect the changes in the intrinsic compressive and tensile stress in the both polycrystalline and amorphous silicon films. 相似文献
6.
Three new cytotoxic polyacetylenes, PQ-1 (1), PQ-2 (2) and PQ-3 (3), have been isolated from Panax quinquefolium. The structures of these acetylenes were determined by analyses of their 1H-1H and 1H-13C COSY spectra. All these compounds exhibited strong cytotoxic activities against leukemia cells (L 1210) in tissue culture. 相似文献
7.
Y. Wardi 《Journal of Optimization Theory and Applications》1989,61(3):473-485
A stochastic algorithm for finding stationary points of real-valued functions defined on a Euclidean space is analyzed. It is based on the Robbins-Monro stochastic approximation procedure. Gradient evaluations are done by means of Monte Carlo simulations. At each iteratex
i
, one sample point is drawn from an underlying probability space, based on which the gradient is approximated. The descent direction is against the approximation of the gradient, and the stepsize is 1/i. It is shown that, under broad conditions, w.p.1 if the sequence of iteratesx
1,x
2,...generated by the algorithm is bounded, then all of its accumulation points are stationary. 相似文献
8.
José E. Valdés 《Operations Research Letters》2006,34(1):49-52
Components C1 and C2 form a series system. Suppose we can allocate the spare R1 in parallel with C1 and the spare R2 in parallel with C2, or otherwise, allocate R1 with C2 and R2 with C1. In this paper, we compare these two options using hazard rate ordering. 相似文献
9.
T. Kumita Y. Kamiya M. Babzien I. Ben-Zvi K. Kusche I. V. Pavlishin I. V. Pogorelsky D. P. Siddons V. Yakimenko T. Hirose T. Omori J. Urakawa K. Yokoya D. Cline F. Zhou 《Laser Physics》2006,16(2):267-271
Thomson scattering of high-power laser and electron beams is a good test of electrodynamics in the high-field region. We demonstrated production of high-intensity X-rays in the head-on collision of a CO2 laser and 60-MeV electron beams at Brookhaven National Laboratory, Accelerator Test Facility. The energy of an X-ray photon was limited at 6.5 keV in the linear (lowest order) Thomson scattering, but the nonlinear (higher order) process produces higher energy X-rays. We measured the angular distribution of the high-energy X-rays and confirmed that it agrees with theoretical predictions. 相似文献
10.
A. I. Magunov A. Ya. Faenov I. Yu. Skobelev T. A. Pikuz E. Biémont P. Quinet F. Blasco C. Bonte F. Dorchies T. Caillaud F. Salin C. Stenz 《Journal of Experimental and Theoretical Physics》2002,95(6):998-1005
The satellite structure of 1s2p 1,3 P 1-1s 21 S 0 lines of the He-like argon ion in plasma produced by a 45-fs laser pulse in a gas-jet cluster target is measured with a high spectral resolution. Radiation transitions 2p → 1s from autoionizing states (AISs) are detected for ions ranging from Li-like to F-like. The spectrum observed is theoretically simulated with the use of the spectroscopic data for the AISs of multicharged ions obtained within the multiconfiguration relativistic Hartree-Fock method. Good agreement with experimental data is obtained when the main population channels of these states are taken into account for typical values of cluster-target plasma parameters. 相似文献