氧化降解壳聚糖铜配合物制备低聚壳聚糖

氧化降解壳聚糖铜配合物制备低聚壳聚糖;壳聚糖铜配合物;壳聚糖;氧化降解;催化     

多峰离子源的三维数值模拟优化与设计

本文理论计算了多峰离子源永磁体, 采用二体碰撞模型处理电子之间的库仑碰撞, 运用空碰撞方法处理电子与氢元素相关粒子碰撞, 开发了全三维粒子模拟-蒙特卡罗模拟算法, 并采用此软件对热门多峰离子源JET-60U的两种优化设计模型进行数值模拟研究, 探索了两种离子源空间分布特性和体积负氢离子产率相关问题, 提出了负氢离子源设计的基本思想: 适当调整离子源多峰磁场分布情况可以输出均匀离子束; 适当调整引出磁场大小和离子源结构, 可以达到离子束空间均匀性和高产率兼顾的效果.     

基于负氢离子源的全三维PIC/MCC模拟算法研究

在分析负氢离子源中等离子体物理机理基础下, 研究并优化粒子模拟算法, 设计高效的粒子存储方法. 研究并运用粒子碰撞蒙特卡罗方法, 考虑等离子体势以及带电粒子间库仑碰撞, 研制了全三维粒子模拟/蒙特卡罗算法(PIC/MCC). 采用磁荷模型, 运用时域有限差分方法计算多峰磁场, 并结合国外负氢离子源JT-60U, 考虑负氢离子源中主要反应, 对全三维PIC/MCC模拟算法模拟验证.     

Optical Performance and Nonlinear Scattering of Soluble Polystyrene Grafted Multi-Walled Carbon Nanotubes

Three soluble polystyrene grafted multi-walled carbon nanotube （MWNT） samples are synthesized, and their optical performance and nonlinear scattering properties are investigated by z-scan method using nanosecond pulses of 532 nm from a frequency-doubled Q-switched Nd： YLF laser. Analysis of the experimental results shows that other than nonlinear scattering, nonlinear absorption plays a major role in optical limiting performance of these stable and well-dispersed suspensions. These new synthesized materials which can be better dispersed in common organic solvents than MWNT itself can be considered as potential sources for further optical applications.     

Cu(Ⅱ)对壳聚糖的配位控制降解

对壳聚糖进行液态均相络合反应制得壳聚糖铜配合物,IR、UV、元素分析及热重分析等检测证实了壳聚糖铜配合物中配位键的存在,且显示壳聚糖在形成配位结构后存在有利于降解的优势构象。以H₂O₂对壳聚糖-Cu(Ⅱ)络合物及壳聚糖进行氧化降解,考察降解过程中粘度的变化及降解产物分子量分布,在相同的降解条件下,壳聚糖铜配合物的降解速度明显高于壳聚糖,降解产物分子量分布较壳聚糖直接降解窄,结果进一步证明壳聚糖铜配合物中存在有利于降解的优势结构,同时证明以金属离子Cu(Ⅱ)对壳聚     

Benzopyran derivatives from endophytic Daldinia eschscholzii JC-15 in Dendrobium chrysotoxum and their bioactivities

Five new benzopyran derivatives (2–6) and a new natural product (1) were isolated from endophytic Daldinia eschscholzii in Dendrobium chrysotoxum and determined as (R)-2,3-dihydro-2,5-dihydroxy-2-methylchromen-4-one (1), (2R, 4S)-2,3-dihydro-2-methyl-benzopyran-4,5-diol (2), (R)-3-methoxyl-1-(2,6-dihydroxy phenyl)-butan-1-one (3), 7-O-α-d-ribosyl-5-hydroxy-2-methyl-4H-chromen-4-one (4), 7-O-α-d-ribosyl-2,3-dihydro-5-hydroxy-2-methyl-chromen-4-one (5), daldinium A (6). These compounds were evaluated for their antimicrobial activity, anti-acetylcholinesterase, nitric oxide inhibition, anticoagulant, photodynamic antimicrobial activities and glucose uptake of adipocytes. Some compounds showed photoactive antimicrobial activities and glucose uptake stimulating activities.     

Neopeapyran,an unusual furo[2,3b]pyran analogue and turnagainolide C from a soil Streptomyces sp. S2236

Neopeapyran (1), an unusual furo[2,3b]pyran analogue, together with a new cyclopeptide, turnagainolide C (2), were isolated from Streptomyces sp. S2236 associated with the rhizosphere soil of Panax notoginseng. The planar structure and relative configuration of neopeapyran (1)) were elucidated on the basis of spectroscopic techniques, while the absolute configuration was determined by TDDFT calculation. The absolute configuration of turnagainolide C (2) was determined by partial hydrolysis, together with the advanced Marfey's method and spectroscopic analysis. The antimicrobial activities of these two compounds were also investigated.     

Synthesis,Bioactivity and Crystal Structure Analysis of Novel Benzo[d]isothiazol-3（2H）-ones

Two compounds,3-oxo-N-o-tolylbenzo[d]isothiazole-2(3H)-carboxamide (1) and N-(2-methoxyphenyl)-3-oxobenzo[d]isothiazole-2(3H)-carboxamide (2),were synthesized from the initial compound benzo[d]isothiazol-3(2H)-one (BIT) and characterized by 1 H NMR,IR and elemental analysis,respectively.The single crystals of compounds 1 and 2 were obtained and determined by X-ray diffraction analysis.The preliminary results of biological activity experiment show that some of the title compounds exhibited a favorable antimicrobial activity.     

氢原子传输及负氢离子产生全三维数值模拟研究

理论分析了负氢离子源中中性粒子传输特性及引出电极表面产生负氢离子(H^-)的物理过程, 研究了引出孔传输率对氢原子传输的影响,深入剖析了氢原子与不同属性导体壁碰撞以及碰撞后反射的物理情景.基于CHIPIC软件平台,成功研制了全三维 Particle-in-cell with Monte Carlo Collision 氢原子传输及负氢离子产生物理过程的模拟算法,并采用JAEA 10A负氢离子源进行模拟验证.模拟达到稳态后,氢原子平均能量约为0.57 eV, 且H原子呈现+Y漂移,当非均匀氢原子束轰击引出壁时,导致产生的负氢离子空间分布不均匀. 这些模拟结果都与文献符合,验证了算法的可靠性.     

磁绝缘传输线中心汇流区电子能量沉积及温度变化的数值模拟研究

介绍了实现高能电子轰击阳极表面产生的能量沉积及温度变化的数值模 拟理论及方法.构建了一个简单的束发射模型,初步验证了阳极表面电子能量沉积数值计算的准确性. 选取四层圆盘锥形磁绝缘传输线中心汇流区为模型, 对其工作过程中产生的阳极能量沉积及温度变化进行数值模拟,并 将模拟结果与国外相关文献的结论进行了对比,进一步证明了模拟的 准确性.对模拟结果进行了分析,探讨了模拟中结果产生的物理机理.