多功能旋流燃烧器的工业性试验研究

秦皇岛热电厂2＃锅炉燃烧不稳定、燃烧效率低等问题主要是由于燃烧器的一次风管道结构不合理造成的。本文采用多功能旋流燃烧器的设计思想对旋流燃烧器进行了技术改造和工业性试验研究。结果表明,改造后的旋流燃烧器其着火点提前,并且仅改造6只主力燃烧器就可以使锅炉在50％负荷时达到不投油而稳定燃烧,排烟温度、飞灰含碳量和NOx排放量明显下降。     

ZnO超微粒子光催化氧化降解n-C7H16的研究

利用ZnO光催化氧化技术对气相n-C7H16进行了降解研究，考察了氧气、水燕气体积分数等因素对n-C7H16光催化氧化的影响，利用气相色谱－质谱联用仪和气相色谱仪对气相光催化反应过程中的气体组成进行了定性分析，并对主要中间产物丙醛进行了定量分析，结果发现，ZnO超微粒子光催化氧化n-C7H16的降解率较高，n-C7H16绝大部分被完全氧化成CO2，探讨了n-C7H16光催化氧化反尖的动力学行为及机理。     

A Feasible and Quantitative Encoding Method for Microbeads with Multicolor Quantum Dots

Multicolor encoded beads were achieved by incorporating two color core-shell quantum dots (QDs) (CdSe/ZnS) to commercial polystyrene (PS) beads. By controlling the concentration ratios of the two quantum dots (QDs) in doping solutions, a series of codes with different intensity ratios were obtained. Based on the multiple encoded carboxylic modified polystyrene beads, fluorescent dyes labeled antibodies were distinguished successfully on the beads’ surface. It suggests that the encoded beads from this method have the practicability in biological applications and chemical analysis. Hai-Qiao Wang and Zhen-Li Huang authors contribute equally to this work     

超高效液相色谱-串联质谱法测定水稻基质中阿维菌素残留量

建立了超高效液相色谱-串联质谱法(UPLC-MS/MS)测定水稻基质中阿维菌素残留量,考察了基质效应,并对实际样品进行了检测.稻田土、稻壳、糙米和稻杆经乙腈振荡提取,稻田水经乙酸乙酯液液分配提取后,用C18固相萃取小柱或弗罗里硅土柱净化,采用UPLC-MS/MS正离子扫描测定残留的阿维菌素.稻田土、稻田水和糙米的3种添加浓度(1.0,10.0和100 μg/kg或μg/L)的平均回收率为84％～107％,相对标准偏差为4.7％～13.6％.稻壳和稻杆的2档添加浓度(10.0和100 μg/kg)的平均回收率为90％和103％,相对标准偏差为8.4％～12.9％.本方法在稻田水、糙米和稻田土中的检出限为0.3μg/kg在稻壳和稻杆中检出限为3.0 μg/kg,低于欧盟和日本在稻米中制定的阿维菌素最大残留限量值.阿维菌素在2.0～100 μg/L范围内线性关系良好( r＞ 0.999).     

极性晶体膜中束缚磁极化子的声子平均数与回旋共振频率的关系

采用改进的线性组合算符法和幺正变换方法,研究极性晶体膜中束缚磁极化子的声子平均数与回旋共振频率ωc的变化关系.得出束缚磁极化子的声子平均数由两部分组成:第一部分是由于电子一体LO声子相互作用所引起的;第二部分则是电子-SO声子相互作用引起的.而且当λ＜20× 1012s-1时,声子平均数随着回旋共振频率ωc的增加而迅速增加,这主要是由于磁场的加入使电子声子的相互作用增强而引起的.     

Improved synthesis of diethyl 2,6-dimethyl-4-aryl-4H-pyran-3,5-dicarboxylate under ultrasound irradiation

Diethyl 2,6-dimethyl-4-aryl-4H-pyran-3,5-dicarboxylates (1) have been synthesized by the reaction of aryl aldehyde and 1,3-diketone catalyzed by ZnCl₂ under ultrasound irradiation. The effects of changes in the ultrasonic power, temperature, and reaction time are discussed. With the optimized reaction conditions, various aryl aldehydes were used to synthesize 4H-pyrans (1) under the influence of ultrasound irradiation. Compared with the conventional thermal methods, the remarkable advantages of this method are the simple experimental procedure, shorter reaction time and high yield of product.     

Influence of quantum dot's quantum yield to chemiluminescent resonance energy transfer

The resonance energy transfer between chemiluminescence donor (luminol-H₂O₂ system) and quantum dots (QDs, emission at 593 nm) acceptors (CRET) was investigated. The resonance energy transfer efficiencies were compared while the oil soluble QDs, water soluble QDs (modified with thioglycolate) and QD-HRP conjugates were used as acceptor. The fluorescence of QD can be observed in the three cases, indicating that the CRET occurs while QD acceptor in different status was used. The highest CRET efficiency (10.7%) was obtained in the case of oil soluble QDs, and the lowest CRET efficiency (2.7%) was observed in the QD-HRP conjugates case. This result is coincident with the quantum yields of the acceptors (18.3% and 0.4%). The same result was observed in another similar set of experiment, in which the amphiphilic polymer modified QDs (emission at 675 nm) were used. It suggests that the quantum yield of the QD in different status is the crucial factor to the CRET efficiency. Furthermore, the multiplexed CRET between luminol donor and three different sizes QD acceptors was observed simultaneously. This work will offer useful support for improving the CRET studies based on quantum dots.     

Diffraction Pattern for a Class of One-Dimensional Quasicrystals

We study the diffraction pattern and indexing problems for a class of 1D quasiperiodic lattices, for which the substitution rules are B ⇒ BA and A ⇒ BAB. The similarity property of diffraction pattern has been found. The numerical calculation is performed to prove the theoretical results.     

交叉色关联噪声驱动的单模激光系统统计性质研究

采用交叉色关联的加性色噪声和乘性色噪声驱动的单模激光立方模型,通过诺维科夫理论和福克斯近似以及斯特拉托诺维奇近似,得到反映激光统计性质的强度关联函数C的表达式;研究关联时间τ、净增益系数a₀和交叉关联强度λ对强度关联函数C的影响.数值模拟发现,在阈值以上（a₀>0）时,关联函数C随关联时间τ的增大而增大;在阈值以下（a₀<0）时,关联函数C随关联时间τ的增大而减小.无论在阈值以上还是阈值以下,关联函数C均随交叉关联强度λ的增大而减小.在C-a₀曲线上存在单峰. 关键词： 单模激光 交叉关联 强度涨落 强度关联函数     

A flow cytometric assay technology based on quantum dots-encoded beads

A flow cytometric detecting technology based on quantum dots (QDs)-encoded beads has been described. Using this technology, several QDs-encoded beads with different code were identified effectively, and the target molecule (DNA sequence) in solution was also detected accurately by coupling to its complementary sequence probed on QDs-encoded beads through DNA hybridization assay. The resolution of this technology for encoded beads is resulted from two longer wavelength fluorescence identification signals (yellow and red fluorescent signals of QDs), and the third shorter wavelength fluorescence signal (green reporting signal of fluorescein isothiocyanate (FITC)) for the determination of reaction between probe and target. In experiment, because of QDs’ unique optical character, only one excitation light source was needed to excite the QDs and probe dye FITC synchronously comparing with other flow cytometric assay technology. The results show that this technology has present excellent repeatability and good accuracy. It will become a promising multiple assay platform in various application fields after further improvement.