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We report a simple approach to the production of carbon fiber‐based amperometric microbiosensors for selective detection of hydrogen peroxide (H2O2), which was achieved by electrometallization of carbon fiber microelectrodes (CFMs) by electrodeposition of Pt nanoparticles. The Pt‐carbon hybrid sensing interface provided a sensitivity of 7711±587 μA ? mM?1 ? cm?2, a detection limit of 0.53±0.16 μM (S/N=3), a linear range of 0.8 μM–8.6 mM, and a response time of <2 sec. The morphologies of the Pt nanoparticle‐modified CFMs were characterized by scanning electron microscopy. To achieve selectivity, permseletive layers, polyphenylenediamine (PPD) and Nafion, were deposited resulting in exclusion of the anionic and cationic interferents, ascorbic acid and dopamine, respectively, at their physiologically relevant concentrations. The resultant sensors displayed a sensitivity to hydrogen peroxide of 1381±72 μA ? mM?1 ? cm?2, and a detection limit of 0.86±0.19 μM (S/N=3). This simple and rapid metallization method converts carbon fiber microelectrodes, which are readily accessible, to microscale Pt electrodes in 2 min, providing a platform for oxidase‐based amperometric biosensors with improved spatial resolution over more commonly used platinum electrode array microprobes. 相似文献
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Two-photon fluorescence (TPF) is one of the most important discoveries for biological imaging. Although a cw laser is known to excite TPF, its application in TPF imaging has been very limited due to the perceived low efficiency of excitation. Here we directly excited fluorophores with an IR cw laser used for optical trapping and achieved single-molecule fluorescence sensitivity: discrete stepwise photobleaching of enhanced green fluorescent proteins was observed. The single-molecule fluorescence intensity analysis and on-time distribution strongly indicate that a cw laser can generate TPF detectable at the single-molecule level, and thus opens the door to single-molecule TPF imaging using cw lasers. 相似文献
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In this paper, Bi2O3 and rare earth (La, Ce)‐doped Bi2O3 visible‐light‐driven photocatalysts were prepared in a Triton X‐100/n‐hexanol/cyclohexane/water reverse microemulsion. The resulting materials were characterized by X‐ray powder diffraction (XRD), transmission electron microscopy (TEM), Brunauer–Emmett–Teller (BET) surface area, photoluminescence spectra (PLS) and UV–Vis diffuse reflectance spectroscopy. The XRD patterns of the as‐prepared catalysts calcined at 500°C exhibited only the characteristic peaks of monoclinic α‐Bi2O3. PLS analysis implied that the separation efficiency for electron‐hole has been enhanced when Bi2O3 was doped with rare earth. UV–Vis diffuse reflectance spectroscopy measurements presented an extension of light absorption into the visible region. The photocatalytic activity of the samples was evaluated by degradation of methyl orange (MO) and 2,4‐dichlorophenol (2,4‐DCP). The results displayed that the photocatalytic activity of rare earth‐doped Bi2O3 was higher than that of dopant‐free Bi2O3. The optimal dopant amount of La or Ce was 1.0 mol%. And the mechanisms of influence on the photocatalytic activity of the catalysts were discussed. 相似文献
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Liu Ximiao Wang Yanli Zhan Liang Qiao Wenming Liang Xiaoyi Ling Licheng 《Journal of Solid State Electrochemistry》2011,15(2):413-419
The surface chemistry of activated carbon was treated with sulfuric acid and hydrogen to analyze the oxygen-containing functional
groups on the impedance behavior of electric double-layer capacitors. Based on the electrochemical impedance spectrum (EIS),
an equivalent circuit model was proposed considering the kinetic and charge transfer characteristics, and Marquardt fit procedure
was applied to the EIS data. The simulated results indicate that the oxidation treatment made the ionic resistance within
the pore of carbon electrode decrease, and the ion diffusion coefficients significantly increase, which leads to improvement
of power capability of the carbon electrode. 相似文献
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Zhang LiuJianzhang Fang Ximiao ZhuJinhui Chu Baojian Li 《Applied Surface Science》2012,258(8):3771-3778
Reverse microemulsions, consisting of n-hexanol, Triton X-100, Cyclohexane and aqueous salt solutions, were used to synthesize BiOI, TiO2 and BiOI/TiO2 hybrid nanoparticles at room temperature. The particles had been characterized by X-ray powder diffraction, FT-IR spectra, TG-DSC analysis, nitrogen sorption, electron microscopy, and UV-vis diffuse reflectance spectroscopy. The photocatalytic properties of those particles were evaluated by degradation of methyl orange under visible light irradiation. The BiOI/TiO2 composites showed about 5 times higher photocatalytic performances than BiOI when the mole ratio of BiOI to TiO2 was 75%. The remarkable enhancement in the visible light photocatalytic activities of the BiOI/TiO2 heterostructures could be first attributed to the effective electron-hole separations at the interfaces of the two semiconductors, which facilitated the transfer of the photoinduced carriers. Meanwhile, the heterojunction formed between BiOI and TiO2 would further retard the recombination of photoinduced carriers. In addition, high degree of crystallization, bimodal porous structure, relative large specific surface area, and appropriate energy band gap have great contribution to the enhancement of photocatalytic performance. 相似文献
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