全文获取类型
收费全文 | 2730篇 |
免费 | 458篇 |
国内免费 | 317篇 |
专业分类
化学 | 1893篇 |
晶体学 | 34篇 |
力学 | 244篇 |
综合类 | 13篇 |
数学 | 368篇 |
物理学 | 953篇 |
出版年
2024年 | 17篇 |
2023年 | 63篇 |
2022年 | 101篇 |
2021年 | 106篇 |
2020年 | 136篇 |
2019年 | 101篇 |
2018年 | 118篇 |
2017年 | 100篇 |
2016年 | 143篇 |
2015年 | 167篇 |
2014年 | 182篇 |
2013年 | 208篇 |
2012年 | 231篇 |
2011年 | 228篇 |
2010年 | 160篇 |
2009年 | 148篇 |
2008年 | 153篇 |
2007年 | 161篇 |
2006年 | 130篇 |
2005年 | 102篇 |
2004年 | 81篇 |
2003年 | 65篇 |
2002年 | 81篇 |
2001年 | 78篇 |
2000年 | 61篇 |
1999年 | 58篇 |
1998年 | 53篇 |
1997年 | 42篇 |
1996年 | 40篇 |
1995年 | 27篇 |
1994年 | 22篇 |
1993年 | 23篇 |
1992年 | 26篇 |
1991年 | 20篇 |
1990年 | 16篇 |
1989年 | 5篇 |
1988年 | 5篇 |
1987年 | 4篇 |
1986年 | 7篇 |
1985年 | 7篇 |
1984年 | 7篇 |
1983年 | 3篇 |
1982年 | 3篇 |
1981年 | 3篇 |
1979年 | 2篇 |
1974年 | 2篇 |
1973年 | 2篇 |
1964年 | 1篇 |
1957年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有3505条查询结果,搜索用时 15 毫秒
1.
Rong Yin Jihui Zhang Xudong Shang 《Mathematical Methods in the Applied Sciences》2020,43(15):8736-8752
This paper is dedicated to studying the following Schrödinger–Poisson system Under some different assumptions on functions V(x), K(x), a(x) and f(u), by using the variational approach, we establish the existence of positive ground state solutions. 相似文献
2.
Yimei Wang Yi Qiao Xiaomin Xu Xiaohong Ding Weiwei Li Bo Yuan Haiyan Xu 《Biomedical chromatography : BMC》2019,33(8)
A sensitive and reliable LC–MS/MS method was developed and validated for simultaneous quantification of the major components of Huangqi–Honghua extact in rat plasma, including hydroxysafflor yellow A (HSYA), astragaloside IV (ASIV), calycosin‐7‐O‐β‐d ‐glucoside (CAG), calycosin, calycosin‐3′‐O‐glucuronide (C‐3′‐G) and calycosin‐3′‐O‐sulfate (C‐3′‐S). After extraction by protein precipitation with acetonitrile and methanol from plasma, the analytes were separated on a Hypersil BDS C18 column by gradient elution with acetonitrile and 5 mM ammonium acetate. The detection was carried out on a triple quadrupole tandem mass spectrometer equipped with electrospray ionization source switched between negative and positive modes. HSYA was monitored in negative ionization mode from 0 to 4.9 min, and ASIV, CAG, calycosin, C‐3′‐G and C‐3′‐S were determined in positive ionization mode from 4.9 to 10 min. The lower limits of quantification of the analytes were 6.25 ng/mL for HSYA, 0.781 ng/mL for CAG and 1.56 ng/mL for ASIV and calycosin. The intra‐ and inter‐assay precision (RSD) values were within 13.43%, and accuracy (RE) ranged from ?8.75 to 9.92%. The validated method was then applied to the pharmacokinetic study of HSYA, ASIV, CAG, calycosin, C‐3′‐G and C‐3′‐S in rat after an oral administration of Huangqi–Honghua extract. 相似文献
3.
Anti-BZ-Structure in Effect Algebras 总被引:1,自引:0,他引:1
The definitions of sharply approximating effect algebras, anti-BZ-effect algebras, central approximating effect algebras, and S-anti-BZ-effect algebras are given, the relationships between sharply approximating effect algebras and anti-BZ-effect algebras, between central approximating effect algebras and anti-BZ-effect algebras are established, and the set of anti-BZ-sharp elements in S-anti-BZ-effect algebras is proved to be an orthomodular lattice. 相似文献
4.
P. Santhana Gopala Krishnan Chaobin He Christine Tay Shang Shang 《Journal of polymer science. Part A, Polymer chemistry》2004,42(16):4036-4046
Two ladder‐like polysilsesquioxanes (LPS) containing side‐chain maleimide groups have been synthesized successfully by reacting N‐(4‐hydroxyphenyl)maleimide (HPM) with LPS containing 100 mol % of chloropropyl groups (Ladder A ) and 50 mol % of each methyl and chloropropyl group (Ladder B ). HPM was synthesized by reacting maleic anhydride with 4‐aminophenol, and the resulting amic acid was imidized using p‐toluenesulfonic acid as a catalyst (Scheme 1 ). The LPSs were characterized by Fourier transform infrared (FTIR), 1H nuclear magnetic resonance (NMR), proton‐decoupled 13C NMR, 29Si NMR, wide‐angle X‐ray diffraction (WAXD), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). Characterization indicated that these polymers had ordered ladder‐like structures with possible defects. These polymers were soluble in common solvents at ambient temperature, which suggested that they were not crosslinked. Both the polymers and the HPM were cured, and their kinetics were followed by dynamic DSC. The Ozawa and Kissinger methods were used to calculate activation energies for curing. Curing increased the temperature at which both 5% weight loss and maximum rate of weight loss were observed. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4036–4046, 2004 相似文献
5.
YAN Xiaomin ZHAO Lin SHAO Jianhui TAN Xin SONG Zhengxiao School of Chemical Engineering Technology Tianjin University Tianjin China Slichem Liquid Material Co. Ltd. Shijiazhuang China 《Chinese Journal of Reactive Polymers》2004,(Z1)
1. INTRODUCTION Methionine, namely 2-amido-4-thiomethyl butyric acid with a structure of CH3SCH2CH2CHCOOH, is one of the essential amino acids and has two natural enantionmers, D and L-methionine. The mixture of L- and D-isomers can be used as analeptics or nutritive additives to maintain the equilibrium of amino acids of feed [1,2]. L-methionine can release active methyl and accelerate the synthesis of choline, which further speeds up the conversion of the lipid accumulated in liv… 相似文献
6.
三种群食物链交错扩散模型的整体 总被引:1,自引:0,他引:1
本文应用能量估计方法和Gagliardo-Nirenberg型不等式证明了一类强耦合反应扩散系统整体解的存在性和一致有界性,该系统是带自扩散和交错扩散项的三种群Lotka-Volterra食物链模型.通过构造Lyapunov函数给出了该模型正平衡点全局渐近稳定的充分条件. 相似文献
7.
用FDTD方法计算了二维正方晶胞各向异性碲圆柱光子晶体的点缺陷模.为了得到TE,TM模式在完全禁带中具有相同共振频率的缺陷模,对中心点缺陷半径Rd以及中心附近对称位置的点缺陷半径Rn做了一系列微调.计算表明,TM模对于Rn的变化不敏感,而TE模随着Rn的改变出现了明显的规则的移动趋势.通过计算分析,发现对应于f=0.4的背景(R=0.3568a),当Rd=0.55a,Rn=0.26a时在完全禁带中TE和TM的缺陷模具有相同的共振频率ω0=0.2466ωe(其中ωe=2πca,a为晶格常数)
关键词:
时域有限差分法
光子晶体
缺陷模
各向异性 相似文献
8.
A simple and accurate algorithm (phase scanning method) is proposed for 3D surface contouring and dynamic response determination of a vibrating object. A sinusoidal fringe pattern is projected onto a low-frequency vibrating object by a programmable liquid crystal display projector. The fringe patterns are captured by a high-speed CCD camera with a telecentric gauging lens. Phase values are evaluated point by point using phase scanning method. From the phase values of each point on the object, the contour of the specimen at different instants of vibration can be retrieved. In this paper, a small vibrating coin is used to demonstrate the validity of the method and the experimental results are compared with test results on a stationary coin using four-step phase shifting and fast Fourier transform methods. The technique is especially useful in applications where the vibrating object has a complicated shape. 相似文献
9.
10.
多目标半定规划的互补弱鞍点和G-鞍点最优性条件 总被引:1,自引:0,他引:1
对于含矩阵函数半定约束和多个目标函数的多目标半定规划问题,给出Lagrange函数在弱有效意义下的互补弱鞍点和Geofrrion恰当有效意义下的G-鞍点的定义及其等价定义.然后,在较弱的凸性条件下,利用含矩阵和向量约束的择一性定理,建立多目标半定规划的互补弱鞍点和G-鞍点充分必要条件. 相似文献