全文获取类型
收费全文 | 3753篇 |
免费 | 710篇 |
国内免费 | 517篇 |
专业分类
化学 | 2873篇 |
晶体学 | 21篇 |
力学 | 184篇 |
综合类 | 34篇 |
数学 | 319篇 |
物理学 | 1549篇 |
出版年
2024年 | 7篇 |
2023年 | 88篇 |
2022年 | 128篇 |
2021年 | 95篇 |
2020年 | 142篇 |
2019年 | 142篇 |
2018年 | 121篇 |
2017年 | 112篇 |
2016年 | 167篇 |
2015年 | 162篇 |
2014年 | 213篇 |
2013年 | 296篇 |
2012年 | 375篇 |
2011年 | 403篇 |
2010年 | 268篇 |
2009年 | 235篇 |
2008年 | 288篇 |
2007年 | 251篇 |
2006年 | 235篇 |
2005年 | 187篇 |
2004年 | 134篇 |
2003年 | 110篇 |
2002年 | 92篇 |
2001年 | 86篇 |
2000年 | 62篇 |
1999年 | 67篇 |
1998年 | 61篇 |
1997年 | 61篇 |
1996年 | 70篇 |
1995年 | 74篇 |
1994年 | 39篇 |
1993年 | 27篇 |
1992年 | 39篇 |
1991年 | 31篇 |
1990年 | 19篇 |
1989年 | 19篇 |
1988年 | 18篇 |
1987年 | 7篇 |
1986年 | 8篇 |
1985年 | 10篇 |
1984年 | 6篇 |
1983年 | 3篇 |
1982年 | 6篇 |
1981年 | 7篇 |
1980年 | 1篇 |
1979年 | 4篇 |
1974年 | 1篇 |
1940年 | 1篇 |
1902年 | 1篇 |
1898年 | 1篇 |
排序方式: 共有4980条查询结果,搜索用时 31 毫秒
1.
Guo-Xing Li Xiao-Wei Qu Lu-Wei Hao Qing Li Su Chen 《Journal of polymer science. Part A, Polymer chemistry》2022,60(11):1710-1717
From the implementation point of view, the printable magnetic Janus colloidal photonic crystals (CPCs) microspheres are highly desirable. Herein, we developed a dispensing-printing strategy for magnetic Janus CPCs display via a microfluidics-automatic printing system. Monodisperse core/shell colloidal particles and magnetic Fe3O4 nanoparticles precursor serve as inks. Based on the equilibrium of three-phase interfacial tensions, Janus structure is successfully formed, followed by UV irradiation and self-assembly of colloid particle to generate magnetic Janus CPCs microspheres. Notably, this method shows distinct superiority with highly uniform Janus CPCs structure, where the TMPTA/Fe3O4 hemisphere is in the bottom side while CPCs hemisphere is in the top side. Thus, by using Janus CPCs microspheres with two different structural colors as pixel points, a pattern with red flower and green leaf is achieved. Moreover, 1D linear Janus CPCs pattern encapsulated by hydrogel is also fabricated. Both the color and the shape can be changed under the traction of magnets, showing great potentials in flexible smart displays. We believe this work not only offers a new feasible pathway to construct magnetic Janus CPCs patterns by a dispensing-printable fashion, but also provides new opportunities for flexible and smart displays. 相似文献
2.
Qin Yin Shou-Guo Wang Xiao-Wei Liang De-Wei Gao Jun Zheng Shu-Li You 《Chemical science》2015,6(7):4179-4183
An organocatalytic asymmetric chlorinative dearomatization of naphthols was realized for the first time, providing chiral naphthalenones with a Cl-containing all-substituted stereocenter in excellent yields and enantioselectivity (up to 97% yield and 96% ee). The reaction features mild reaction conditions, good tolerance of diverse functional groups and simple reaction operation. 相似文献
3.
运用群论及原子分子反应静力学方法,推导了XY(H,Li,Na)分子基态的电子态及相应的离解极限.并采用密度泛函方法(B3LYP)和二次组态相互作用方法(QCISD)优化计算了XY(H,Li,Na)分子基态的平衡结构、振动频率和离解能.使用QCISD/6-311++G(3df,3pd)方法,对XY(H,Li,Na)分子基态进行了单点能扫描计算,采用最小二乘法拟合Murrell-Sorbie函数得到了相应的势能函数和与该基态相对应的光谱常数(Be,αe,ωe和ωexe),计算结果与实验数据符合得相当好. 相似文献
4.
5.
A new family of photonucleases, naphthalimide-thiazoles was synthesized and evaluated. These compounds intercalated into DNA efficiently and damaged DNA photochemically at concentrations as low as 5 μM. Mechanistic experiment suggests that a novel naphthalimide-thiazole radical produced via an excited triple state might be involved in the DNA photodamage. Different activity may arise from the impact of substituents at 2-phenyl ring of thiazole on the electron population of excited triple state according to AM1 semi-empirical calculation. 相似文献
6.
7.
1载流圆环在匀强磁场中的受力情况 半径为r0,通以电流I的弹性圆环,放在光滑的水平面上,磁感强度为B0的匀强磁场垂直穿过圆环,如图1所示. 相似文献
8.
9.
Y. Qu J.X. Zhang A. Uddin C.Y. Liu S. Yuan M.C.Y. Chan B. Bo G. Liu H. Jiang 《Applied Physics A: Materials Science & Processing》2006,82(2):305-308
Ridge-waveguide InGaAsN triple-quantum-well strain-compensated lasers grown by metal organic chemical vapor deposition were fabricated with pulsed anodic oxidation. The laser’s output power reached 145 mW in continuous-wave mode at room temperature for a 4-?m -stripe-width laser. Continuous-wave single longitudinal mode operation was maintained at a high injection current level with a wavelength of 1287.3 nm at room temperature. Single longitudinal mode operation at 1317.2 nm was achieved at twice the threshold current at 100 °C. The band gap of InGaAsN in the quantum wells at different temperatures was calculated and compared to the measured temperature-dependent laser wavelength. 相似文献
10.