不同重力环境下辐射加热材料表面着火特性分析

研究外界辐射加热下，不同重力环境中热薄燃料的着火特性．探讨了重力、环境氧浓度、环境压力及外界辐射强度对着火的影响．结果表明，随着重力的变化，存在不同的着火机制．在微重力和在高的环境氧浓度中，材料的着火延迟时间变短．压力减小，着火延迟时间增大．随着辐射强度的增大，着火延迟时间变小．     

基于突变论的林火蔓延分析

在对森林火灾进行能量和质量守恒分析的基础上,把尖点突变模型应用于森林火灾蔓延的预测,使突变理论在 森林火灾的模型中从理论上有了初步的应用。文中计算了林火发生突变时的一些分歧点,分析了林火突变的特点和变化规 律。     

正庚烷在超稳Y沸石(USY)负载超强酸催化剂上加氢异构化

The Pt-bearing SO₄^2-/ZrO₂ superacid catalysts supported on ultra stable Y (USY) zeolite were prepared by impregnation and characterized by X-ray diffraction, nitrogen adsorption and Hammett indicators. Their catalytic activities were evaluated in the hydroisomerization of n-heptane with an atmospheric fixed-bed reactor. The catalysts possessed a high surface area, superacidity and well maintained pore structure of USY support. The supported catalysts with a suitable SO₄^2-/ZrO₂ loading exhibited a higher catalytic activity and selectivity than the unsupported SO₄^2-/ZrO₂ catalyst or the Pt supported on USY catalyst without superacid. At the reaction temperature of 220 ℃, over the catalyst with a Pt loading of 0.8wt% and ZrO₂ loading of 10wt%, the conversion of n-heptane could be as high as 35.2% with a selectivity of 87.9% for isomerization products.     

Facile One-Pot Method for the Synthesis of Polysubstituted Phthalide Derivatives

A new three-component cyclization method is described involving two starting materials, ethyl 4-chloroacetoacetate and aldehydes, catalyzed by piperidine, acid, and iodine. Ten corresponding polysubstituted phthalides are formed with good yields (44–78%). A mechanism of the reaction is also proposed.     

Cationic Nonporous Macrocyclic Organic Compounds for Multimedia Iodine Capture

Over the past two decades, progress in chemistry has generated various types of porous materials for removing iodine (¹²⁹I or ¹³¹I) that can be formed during nuclear energy generation or nuclear waste storage. However, most studies for iodine capture are based on the weak host-guest interactions of the porous materials. Here, we present two cationic nonporous macrocyclic organic compounds, namely, MOC-1 and MOC-2 , in which 6I^- and 8I⁻ were as counter anions, for highly efficient iodine capture. MOC-1 and MOC-2 were formed by reacting 1,1′-diamino-4,4′-bipyridylium di-iodide with 1,2-diformylbenzene or 1,3-diformylbenzene, respectively. The presence of a large number of I⁻ anions results in high I₂ affinity with uptake capacities up to 2.15 g ⋅ g⁻¹ for MOC-1 and 2.25 g ⋅ g⁻¹ for MOC-2 .     

Influence of cesium on the stability of a GaAs photocathode

The stability of a reflection-mode GaAs photocathode has been investigated by monitoring the photocurrent and the spectral response at room temperature.We observe the photocurrent of the cathode decaying with time in the vacuum system under the action of Cs current,and find that the Cs atoms residing in the vacuum system are helpful in prolonging the life of the cathode.We examine the evolution and analyse the influence of the barrier on the spectral response of the cathode.Our results support the double dipolar model for the explanation of the negative electron affinity effect.     

厄尔尼诺和南方涛动海气耦合模型中参数估计的变分方法

提出一种基于变分原理估计厄尔尼诺和南方涛动海气耦合模型中未知参数的方法. 首先将所研究的非线性海气耦合动力方程引入到目标泛函中; 接着利用变分方法导出伴随方程和待辨识参数泛函梯度的公式; 然后设计了估计未知参数的算法.数值试验结果表明变分方法是一 种能有效估计海气耦合非线性系统未知参数的方法.     

Anti-apoptotic and neuroprotective effects of Tetramethylpyrazine following spinal cord ischemia in rabbits

Background  

Tetramethylpyrazine (TMP) is one of the most important active ingredients of a Chinese herb Ligusticum wallichii Franchat, which is widely used in many ischemia disorders treatments. However, the exact mechanism by which TMP protects the spinal cord ischemia/reperfusion (I/R) injury is still unknown. For this purpose, rabbits were randomly divided into sham group, control group and TMP group. After the evaluation of neurologic function, the spinal cords were immediately removed for biochemical and histopathological analysis. Apoptosis was measured quantitatively by the terminal transferase UTP nick end-labeling (TUNEL) method and confirmed by electron microscopic examination, the expression of Bax and Bcl-2 was immunohistochemically evaluated and quantified by Western blot analysis.     

曲波域统计量自适应阈值探地雷达数据去噪技术

非线性、非平稳探地雷达数据常掺杂各种复杂噪声源,其对精确提取弱反射波信号、识别绕射波双曲线同相轴特征具有严重影响,忽略噪声影响给探地雷达探测数据全波形偏移成像及后续解译造成较大误差.采用传统阈值函数的曲波变换去噪需要根据数据噪声水平人为确定合理阈值控制系数.对此,本文开展自适应阈值函数的曲波变换去噪算法研究.引入块状复数域阈值函数算法,分析传统阈值函数曲波变换去噪的效果随阈值控制系数变化的规律;利用高阶统计量理论,对曲波变换系数在尺度、方向上进行相关性叠加,通过相关性统计量自适应确定有效信号在曲波变换系数分布尺度、旋转方向,由此确定清除噪声成分阈值范围,构建统计量自适应阈值函数曲波变换去噪算法.针对包含随机噪声、相关噪声合成探地雷达数据及实测探地雷达数据,采用传统阈值函数曲波变换去噪与本文提出去噪算法处理结果对比分析,检验了本文算法的有效性及可行性.研究成果对复杂探地雷达数据精确推断解译具有指导意义.     

A facile and efficient method for synthesis of xanthone derivatives catalyzed by HBF4/SiO2 under solvent-free conditions

Abstract  

HBF₄/SiO₂ was used as an efficient, green, and inexpensive catalytic system for synthesis of 12-aryl or 12-alkyl-8,9,10,12-tetrahydro-11H-benzo[a]xanthen-11-one derivatives via a one-pot three-component reaction of aldehydes, 2-naphthol, and cyclic 1,3-dicarbonyl compounds. The reactions proceeded rapidly at 80 °C under solvent-free conditions and the desired products were obtained in good to excellent yields.