一类酶反应底物的光化学荧光研究

研究了对位取代酚类酶反应底物的光化学荧光反应机理，指出光子不仅可以取代过氧化物酶，而且可以取代氧化剂（Ｈ_２Ｏ_２）。用于测定多种酶反应底物，结果满意。     

光化学-荧光分析法研究——Ⅲ.片剂及注射液中安定的测定

本文提出了测定安定的光化学—荧光分析新方法。安定在含有十二烷基硫酸钠的稀硫酸介质中,经紫外光照射后,产物能发射荧光(=368nm,=476nm)。安定浓度在0～2.5μg/ml范围内,荧光强度与浓度成良好的线性关系。方法的相对标准偏差为1.5％,检出限为0.044μg/ml,可用于片剂及注射液中安定含量的测定。     

Adsorption of 1,10-phenanthroline within a dodecanethiol monolayer: an approach to a switchable electrode surface

A simple method was used to prepare a "switchable" electrode surface by using self-assembled monolayers of dodecanethiol on a gold electrode. The dodecane-modified electrode was electrochemically inactive until the monolayer was soaked in solutions of 1,10-phenanthroline or 2,2'-bipyridine. The electroactive form of the electrode could be reverted back to the nonelectroactive form by rinsing the electrode. Surface IR results showed that both dodecanethiol and 1,10-phenanthroline exist in the mixed monolayer.     

Studies on pharmacokinetics,body distribution,plasma protein binding rate,and excretion of 1-methyl hydantoin in rats in vivo

In this paper, plasma concentration, plasma protein binding rate, body distribution, and excretion of both oral and intravenous administration of rats were determined by high performance liquid chromatography (HPLC) combining with UV detector. The blood drug concentration of oral and intravenous administration was summarized. The bioavailability of T_1/2 was approximately 0.75?hr. At the meanwhile, the bioavailability was about 18.84?±?2.21%. The plasma protein binding rate of 1-methyl hydantoin was about 24.36?±?0.93%, belonging to low protein binding drug. The result shows that 1-methyl hydantoin can be rapidly distributed in various organs and tissues and quickly eliminated within 6?hr without accumulation in the organs. Its discharge from the urine and feces was 16.58?±?4.48% and 3.37?±?0.71%, respectively. All of the results showed that the recovery rate, liner relationship, specificity, stability, and precision of the method were good. The study also proved that 1-methyl hydantoin has been eliminated quite faster in rats.     

Vasiek利率模型下住房抵押贷款保证险的鞅定价

利用期权定价理论和鞅方法 ,分析了 Vasic∨ ek利率模型下住房抵押贷款保证险的定价问题 ,得到了全额担保和部分担保两类住房抵押贷款保证险的无套利定价公式 ,其中房价服从一般的扩散过程 .     

过渡金属大环配合物的研究Ⅲ 4-硝基-苯并15冠-5与钴(Ⅱ)、铜(Ⅱ)和银(Ⅰ)配合物的合成及性质

有关冠醚配体与碱金属,碱土金属和稀土离子形成配合物的特性研究,国内外均有报导,但冠醚与d-过渡金属离子配合物的研究工作,则开展较晚,文献报导亦甚少。本文为探讨4-硝基-苯并15冠-5(No_2·B15C15)与过渡金属离子的配位能力,合成了Co(Ⅱ),Cu(Ⅱ),和Ag(Ⅰ)与4-硝基-苯并15冠-5配合物。并进行了元素分析,X-射线衍射,红外光谱,摩尔电导,激光拉曼光谱及差热-热失重分析的研究。     

气缸垫对机体受力和缸套变形影响的实验研究

某四缸柴油机在试制中出现机体裂纹现象，为保证内燃机正常工作，机体裂纹问题急待处理．应用力学理论对此进行分析，得出机体裂纹是由机体受力不均匀引起的结论．同时采用实验应力分析方法，对两种四缸柴油机机体进行了对比实验研究，在实验中发现了缸垫对机体受力和缸套变形的影响，从而提出了一种有效的改进方法，使机体的应力有明显下降，并不再出现裂纹，也未出现漏油、漏气和活塞拉缸等不良现象，大大提高了产品可靠性．     

可激发气体分子声弛豫过程振动模式能量转移速率计算

研究可激发气体中振动模式能量转移速率和声弛豫过程形成的关系,将单一气体Tanczos弛豫方程理论[J.Chem.Phys.25,439(1956)]扩展应用于混合气体中振动模式的振动-振动(V-V)和振动-平动(V-T)能量转移速率的计算。在室温下CO₂,CH₄,CL₂,N₂和O₂组成的多种混合气体中,振动模式能量转移速率的计算结果表明:对于多个振动模式所形成的声复合弛豫过程,各振动模式的声激发能可由V-V能量转移相互耦合后传递给具有最快V-T转移速率的最低振动频率振动模式,再通过该振动模式的V-T转移退激发形成主弛豫过程。这种选择最快转移路径的声激发量弛豫方式,造成了大多数可激发气体中声弛豫吸收谱的实测数据只存在一个吸收峰的现象。从而提供了一个可通过计算微观振动能量转移速率分析混合气体声弛豫过程形成机理的理论模型。