High electro-catalytic graphite felt/MnO<Subscript>2</Subscript> composite electrodes for vanadium redox flow batteries

A mild and simple synthesis process for large-scale vanadium redox flow batteries (VRFBs) energy storage systems is desirable. A graphite felt/MnO₂ (GF-MNO) composite electrode with excellent electrocatalytic activity towards VO²⁺/VO₂⁺ redox couples in a VRFB was synthesized by a one-step hydrothermal process. The resulting GF-MNO electrodes possess improved electrochemical kinetic reversibility of the vanadium redox reactions compared to pristine GF electrodes, and the corresponding energy efficiency and discharge capacity at 150 mA cm^?2 are increased by 12.5% and 40%, respectively. The discharge capacity is maintained at 4.8 A h L^?1 at the ultrahigh current density of 250 mA cm^?2. Above all, 80% of the energy efficiency of the GFMNO composite electrodes is retained after 120 charge-discharge cycles at 150 mA cm^?2. Furthermore, these electrodes demonstrated that more evenly distributed catalytic active sites were obtained from the MnO₂ particles under acidic conditions. The proposed synthetic route is facile, and the raw materials are low cost and environmentally friendly. Therefore, these novel GFMNO electrodes hold great promise in large-scale vanadium redox flow battery energy storage systems.     

三维数值仿真研究锗硅异质结双极晶体管总剂量效应

为探索锗硅异质结双极晶体管(SiGe HBT)总剂量效应的损伤机理,采用半导体器件三维模拟工具(TCAD),建立电离辐照总剂量效应损伤模型,分析比较电离辐射在SiGe HBT不同氧化层结构的不同位置引入陷阱电荷缺陷后,器件正向Gummel特性和反向Gummel特性的退化特征,获得SiGe HBT总剂量效应损伤规律,并与⁶⁰Coγ辐照实验进行对比.结果表明:总剂量辐照在SiGe HBT器件中引入的氧化物陷阱正电荷主要在pn结附近的Si/SiO₂界面处产生影响,引起pn结耗尽区的变化,带来载流子复合增加,最终导致基极电流增大、增益下降;其中EB Spacer氧化层中产生的陷阱电荷主要影响正向Gummel特性,而LOCOS隔离氧化层中的陷阱电荷则是造成反向Gummel特性退化的主要因素.通过数值模拟分析获得的SiGe HBT总剂量效应损伤规律与不同偏置下⁶⁰Coγ辐照实验的结论符合得较好.     

Enabling a Durable Electrochemical Interface via an Artificial Amorphous Cathode Electrolyte Interphase for Hybrid Solid/Liquid Lithium-Metal Batteries

A hybrid solid/liquid electrolyte with superior security facilitates the implementation of high-energy-density storage devices, but it suffers from inferior chemical compatibility with cathodes. Herein, an optimal lithium difluoro(oxalato)borate salt was introduced to build in situ an amorphous cathode electrolyte interphase (CEI) between Ni-rich cathodes and hybrid electrolyte. The CEI preserves the surface structure with high compatibility, leading to enhanced interfacial stability. Meanwhile, the space-charge layer can be prominently mitigated at the solid/solid interface via harmonized chemical potentials, acquiring promoted interfacial dynamics as revealed by COMSOL simulation. Consequently, the amorphous CEI integrates the bifunctionality to provide an excellent cycling stability, high Coulombic efficiency, and favorable rate capability in high-voltage Li-metal batteries, innovating the design philosophy of functional CEI strategy for future high-energy-density batteries.     

Parallel FEM LES with one-equation subgrid-scale model for incompressible flows

This article develops a parallel large-eddy simulation (LES) with a one-equation subgrid-scale (SGS) model based on the Galerkin finite element method and three-dimensional (3D) brick elements. The governing filtered Navier–Stokes equations were solved by a second-order accurate fractional-step method, which decomposed the implicit velocity–pressure coupling in incompressible flow and segregated the solution to the advection and diffusion terms. The transport equation for the SGS turbulent kinetic energy was solved to calculate the SGS processes. This FEM LES model was applied to study the turbulence of the benchmark open channel flow at a Reynolds number Re_τ = 180 (based on the friction velocity and channel height) using different model constants and grid resolutions. By comparing the turbulence statistics calculated by the current model with those obtained from direct numerical simulation (DNS) and experiments in literature, an optimum set of model constants for the current FEM LES model was established. The budgets of turbulent kinetic energy and vertical Reynolds stress were then analysed for the open channel flow. Finally, the flow structures were visualised to further reveal some important characteristics. It was demonstrated that the current model with the optimum model constants can predict well the organised structure near the wall and free surface, and can be further applied to other fundamental and engineering applications.     

CdX(X=Se,Te,Te/ZnS)量子点脂质体的制备及毒性比较

在水相中以巯基乙酸(mercaptoacetic acid, MA)为稳定剂合成了CdSe、CdTe、CdTe/ZnS量子点及谷胱甘肽(glutathione, GSH)为稳定剂合成了CdTe量子点,然后通过卵磷脂和胆固醇修饰制得相应的量子点脂质体。溶血实验证实GSH修饰量子点的溶血率低于MA修饰的量子点45%;脂质体修饰后,量子点的溶血率＜5%,达到生物医用材料要求。不同表面修饰的量子点对小鼠毒性存在明显差异,荧光显微镜观察组织切片证实量子点在小鼠体内主要分布在肺、肾、胸腺等组织中,而脂质体量子点在脑组     

翻转课堂与传统课堂在高三化学教学中的对比研究

利用对比实验法,在2个平行班开展关于翻转课堂和传统课堂的对比研究。通过研究,发现翻转课堂教学模式能够激发学生的学习兴趣,提高学生的学习积极性;翻转课堂教学模式能够帮助教师发挥教学的主导作用,凸显学生学习的主体地位,能够帮助教师更好地掌握学生的学习进程;翻转课堂教学模式能有效提高学生的学习成绩。     

金属钠与盐酸反应的实验研究

目前关于金属钠与盐酸或水反应速率的快慢问题,不同学者提出了不同的观点。基于此,开展了“钠与盐酸反应”的实验研究,实验中观察到白色沉淀,定性分析了白色沉淀的成分并提供了理论依据。     

制取银氨溶液异常实验现象的探究

将市售硝酸银试剂配成溶液,滴入氨水,反应液始终保持澄清,初步认为这种异常实验现象是由硝酸银试剂中含有少量硝酸铵杂质引起的。测定了向硝酸银溶液中加入氨水生成氧化银沉淀的质量,指出制取银氨溶液时只有少部分硝酸银与氨水反应生成中间产物氧化银,大部分硝酸银与氨水反应直接生成银氨络合物。探析了向硝酸银溶液中滴入氨水,反应液始终澄清或生成白色沉淀的异常实验现象。     

Raising the capacity of lithium vanadium phosphate via anion and cation co-substitution

The pursuit for batteries with high specific energy provokes the research of high-voltage/capacity cathode materials with superior stability and safety as the alternative for lithium iron phosphate.Herein,using the sol-gel method,a lithium vanadium phosphate with higher average discharge voltage(3.8 V,vs.Li+/Li) was obtained from a single source for Mg2+ and Cl-co-substitution and uniform carbon coating,and a nearly theoretical capacity(130.1 mA h g^-1) and outstanding rate performance(25 C) are acquired together with splendid capacity retention(80%) after 650 cycles.This work reveals that the well-sized anion and cation substitution and uniform carbon coating are of both importance to accelerate kinetic performance in the context of nearly undisturbed crystal structure for other analogue materials.It is anticipated that the electrochemistry comprehension will shed light on preparing cathode materials with high energy density in the future.     

基于“证据推理与模型认知”的有机化合物结构探究*——以“葡萄糖分子结构探究”为例

基于元素分析仪、质谱仪、红外光谱仪等现代分析仪图谱,提出葡萄糖分子结构的可能假设,通过实验加以证实,再结合1H-NMR图谱佐证葡萄糖分子结构,从而建立葡萄糖分子结构的探究模型,为有机化合物分子结构探究提供范式。