全文获取类型
收费全文 | 122篇 |
免费 | 7篇 |
国内免费 | 40篇 |
专业分类
化学 | 159篇 |
晶体学 | 1篇 |
数学 | 1篇 |
物理学 | 8篇 |
出版年
2021年 | 2篇 |
2020年 | 3篇 |
2019年 | 1篇 |
2016年 | 8篇 |
2015年 | 1篇 |
2014年 | 8篇 |
2013年 | 4篇 |
2012年 | 6篇 |
2011年 | 10篇 |
2010年 | 3篇 |
2009年 | 13篇 |
2008年 | 16篇 |
2007年 | 16篇 |
2006年 | 6篇 |
2005年 | 5篇 |
2004年 | 6篇 |
2003年 | 1篇 |
2002年 | 6篇 |
2001年 | 1篇 |
2000年 | 2篇 |
1999年 | 2篇 |
1998年 | 6篇 |
1997年 | 11篇 |
1996年 | 3篇 |
1995年 | 6篇 |
1994年 | 4篇 |
1993年 | 3篇 |
1992年 | 1篇 |
1989年 | 2篇 |
1988年 | 3篇 |
1987年 | 6篇 |
1986年 | 2篇 |
1984年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有169条查询结果,搜索用时 0 毫秒
1.
Hongchao Li Yufeng Hu Yanguang Zhang Dongge Ma Lixiang Wang Xiabin Jing Fosong Wang 《Journal of polymer science. Part A, Polymer chemistry》2004,42(16):3947-3953
A conjugated poly(p‐CN‐phenylenevinylene) (PCNPV) containing both electron‐donating triphenylamine units and electron‐withdrawing cyano groups was prepared via Knoevenagel condensation in a good yield. Gel permeation chromatography suggested that the soluble polymer had a very high weight‐average molecular weight of 309,000. A bright and saturated red emission was observed under UV excitation in solution and film. Cyclic voltammetry showed that the polymer presented quasi‐reversible oxidation with a relatively low potential because of the triphenylamine unit. A single‐layer indium tin oxide/PCNPV/Mg–Ag device emitted a bright red light (633 nm). © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3947–3953, 2004 相似文献
2.
Peng Ping Wenshou Wang Xuesi Chen Xiabin Jing 《Journal of Polymer Science.Polymer Physics》2007,45(5):557-570
Poly(ε‐caprolactone)‐based segmented polyurethanes (PCLUs) were prepared from poly(ε‐caprolactone) diol, diisocyanates (DI), and 1,4‐butanediol. The DIs used were 4,4′‐diphenylmethane diisocyanate (MDI), 2,4‐toluenediisocyanate (TDI), isophorone diisocyanate (IPDI), and hexamethylene diisocyanate (HDI). Differential scanning calorimetry, small‐angle X‐ray scattering, and dynamic mechanical analysis were employed to characterize the two‐phase structures of all PCLUs. It was found that HDI‐ and MDI‐based PCLUs had higher degree of microphase separation than did IPDI‐ and TDI‐based PCLUs, which was primarily due to the crystallization of HDI‐ and MDI‐based hard‐segments. As a result, the HDI‐based PCLU exhibited the highest recovery force up to 6 MPa and slowest stress relaxation with increasing temperature. Besides, it was found that the partial damage in hard‐segment domains during the sample deformation was responsible for the incomplete shape‐recovery of PCLUs after the first deformation, but the damage did not develop during the subsequent deformation. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 557–570, 2007 相似文献
3.
Phenylene vinylene‐based electroluminescent polymers with electron transport block in the main chain
Honghao Sun Chongyu Mei Quanguo Zhou Ze Liu Dongge Ma Lixiang Wang Xiabin Jing Fosong Wang 《Journal of polymer science. Part A, Polymer chemistry》2006,44(11):3469-3478
We report a new route for the design of soluble phenylene vinylene (PV) based electroluminescent polymers bearing electron‐deficient oxadizole (OXD) and triazole (TZ) moieties in the main chains with the aryloxy linkage. Both series of the PV‐based polymers were prepared by Wittig reaction. By properly adjusting the OXD and/or TZ content through copolymerization, we can achieve an enhanced balance of hole‐ and electron injections, such that the device efficiency is significantly improved. Light‐emitting diodes fabricated from P1, P2, P3, P4, P5, P6, and P7 with the configuration of Indium–Tin Oxide (ITO)/Poly (styrene sulfonic acid) doped poly (ethylenedioxythiophene) (PEDOT)/polymer/Ca/Al, emit bright green light with the maximum peak around 500 nm. For the device using the optimal polymer (P4) as emitting layer, a maximum brightness of 1300 cd/m2 at 20 V and a maximum luminance efficiency of 0.325 cd/A can be obtained. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3469–3478, 2006 相似文献
4.
聚乙烯单晶的退火效应 总被引:1,自引:1,他引:1
用混合晶红外光谱法和SAXS、DSC和LAM等方法研究了聚乙烯单晶在75℃、90℃和105℃退火前后的结构变化,发现在90℃以下和105℃以上退火,遵循不同的退火机制 相似文献
5.
6.
凝胶型聚合物电解质的电导率与温度的关系孙晓光,林云青,齐力,景遐斌,王佛松(中国科学院长春应用化学研究所长春130022)关键词凝胶电解质,离子电导率,活化能无定形聚合物电解质电导与温度的依赖关系一般可用Vogel-Tamman-Fulcherc(V... 相似文献
7.
8.
9.
聚合物作为一种有机发光材料,由于在平板显示和光电子器件中的良好应用前景而受到广泛研究[1~2].近年来,一个重要进展是在聚合物中观测到了受激发射(简称Poly-mer激光)现象[3~6].Polymer激光最早是在溶液中实现的[3~4].作为一种新型... 相似文献
10.
Xueyu Qiu Yadong Han Xiuli Zhuang Xuesi Chen Yuesheng Li Xiabin Jing 《Journal of nanoparticle research》2007,9(5):901-908
Nano-hydroxyapatite (HA)/poly(l-lactide) (PLLA) composite microspheres with relatively uniform size distribution were prepared by a solid-in-oil-in-water
(s/o/w) emusion solvent evaporation method. The encapsulation of the HA nanopaticles in microshperes was significantly improved
by grafting PLLA on the surface of the HA nanoparticles (p-HA) during emulsion process. This procedure gave a possibility
to obtain p-HA/PLLA composite microspheres with uniform morphology and the encapsulated p-HA nanoparticle loading reached
up to 40 wt% (33 wt% of pure HA) in the p-HA/PLLA composite microspheres. The microstructure of composite microspheres from
core-shell to single phase changed with the variation of p-HA to PLLA ratios. p-HA/PLLA composite microspheres with the diameter
range of 2–3 μm were obtained. The entrapment efficiency of p-HA in microspheres could high up to 90 wt% and that of HA was
only 13 wt%. Surface and bulk characterizations of the composite microspheres were performed by measurements such as wide
angle X-ray diffraction (WAXD), thermal gravimetric analysis (TGA), environmental scanning electron microscope (ESEM) and
transmission electron microscopy (TEM). 相似文献