Photo-electrochemically Synergetic Effect in the Catalytic Degradation of Reactive Dyes

The dye wastewater has a high potential environmental impact principally due to the wastewater containing high organic charge and strong coloration. As far as back the 1980s, the totals of synthesized dyes have been more than 800 thousand tons every year in the whole would. However, in the all of dyes, reactive dyes represent an important fraction of the commercialized synthetic pigments used. The major environmental problem associated with the use of the reactive dyes is their loss in the dyeing processes with general low fixation efficiency, large mount of dye-containing wastewater was inevitably discharged into water supply. So, the treatment of wastewater containing reactive dyes is very urgent for our health.     

地球变化磁场Z分量的混沌动力学特性分析

对地球变化磁场进行了混沌动力学特性分析,主要进行了以下两个方面的工作:1)运用多种方法对多个地磁台站同一时段变化磁场分量数据(分为磁扰较小和磁扰较大时段)进行了混沌特性分析,主要是为了以更充分的判据来验证地球变化磁场是否具有混沌特性;2)同一地磁台站不同时段变化磁场分量数据的混沌特性分析,主要是验证地球变化磁场是否具有变参数混沌特性.分析结果表明:1)变化磁场时间序列确实具有混沌特性;2)从混沌时间序列相空间重构的角度可初步认为模拟地球变化磁场动力学系统所必须的独立变量应该为6左右;3)变化磁场时间序列不仅具有混沌特性而且其参数也是在缓慢变化着的,具有变参数混沌系统的特性.     

An approach to the structure and spectra of copper barbiturate trihydrate

In the neutral title complex [Cu(C₄N₂H₃)₂(H₂O)₃] or [Cu(BBR)₂(H₂O)₃] (BBR^– = Barbiturate), the Cu^II ion, in the slightly distorted square-pyramidal geometry, is coordinated by two O atoms of the two monodentate barbiturates and three O atoms of three water ligands. The average bond length of Cu—O (BBR^–) is 1.981(5) Å and the average bond length of Cu—O (H₂O) at the basal sites is 1.94(5) Å, i.e. much shorter than that of Cu—O (H₂O) [2.175(11) Å]. The crystal structure is characterized by an extensive network of hydrogen bonds in which each [Cu(BBR)₂(H₂O)₃] entity links to six adjacent [Cu(BBR)₂(H₂O)₃] by O(C=O) ··· H—O(H₂O) bonds. Tautomerism in the coordination process for BBR^– was found from the crystal structure and i.r. spectral analysis. The interaction of Cu^II and BBR^– in aqueous solution was also investigated by electronic spectra and electrochemical method. It was observed that the copper ion could not only form the [Cu(BBR)₂(H₂O)₃] complex in aqueous but also catalyze the decomposition of BBR^– at pH 1.1.     

Solvent Sublation for Surface-Active Substances from Aqueous Solution,Comparison with Solvent-Extraction

The solvent sublation technique, a non-foaming technique, is originated by Sebba^[1] as an option for ion flotation, in which the surface active solute in water is adsorbed on the surface of ascending bubbles and then collected in an immiciable solvent As we know that there are a number of features that make the technique more advantageous than that of the solvent extraction:the possibility of easy handling of large volumes of aqueous sample; the equilibrium state established not in the bulk of system but only at the aqueous-organic interface and the recovery of trace elements eventually reaching 100%; no emulsion formation^[2-3]. Furthermore, the effluent water from a sublation column doesn't require further treatment to remove residual solvent. The handles are single and expenses are cheap, so the solvent sublation has the potential in the environmental treatment and the separation and preconcentration process^[4-6]. The aim of this paper is to investigate the experimental possibilities of the solvent sublation and its intercomparison with conventional liquid-liquid extraction, in order to get more information on widely applications in the near future.     

Fe3O4和Zn2+掺杂型Zn1-xFe2+xO4纳米晶的溶剂热合成和电磁性能

利用溶剂热法, 在醋酸钠静电保护剂的辅助下, 成功制备出Fe₃O₄和Zn²⁺掺杂型Zn_0.07Fe_2.93O₄纳米晶. 利用X射线衍射仪和扫描电子显微镜等对样品的晶体结构、粒径、形貌和化学组成进行了分析. 结果表明, 所得纳米晶的粒径均匀, 形貌为球形, 分散度好; Zn_0.07Fe_2.93O₄纳米晶的平均粒径(70 nm)明显小于Fe₃O₄(170 nm). 磁性能测量结果表明, 室温下Zn_0.07Fe_2.93O₄的饱和磁化强度(54.2 A·m²·kg^-1)小于Fe₃O₄ (81.6 A·m²·kg^-1). 利用矢量网络分析仪对样品的电磁性能和吸波性能进行了研究. 结果表明, Zn²⁺掺杂型Zn_0.07Fe_2.93O₄纳米晶的吸波性能优于Fe₃O₄, 前者的最大吸收峰(-19.3 dB)大于后者(-9.8 dB), 且吸收峰低于-10 dB的峰宽达2.5 GHz.