首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   7649篇
  免费   1393篇
  国内免费   1751篇
化学   6407篇
晶体学   97篇
力学   417篇
综合类   158篇
数学   1092篇
物理学   2622篇
  2024年   20篇
  2023年   112篇
  2022年   184篇
  2021年   253篇
  2020年   271篇
  2019年   322篇
  2018年   222篇
  2017年   266篇
  2016年   340篇
  2015年   360篇
  2014年   387篇
  2013年   572篇
  2012年   599篇
  2011年   656篇
  2010年   524篇
  2009年   492篇
  2008年   565篇
  2007年   488篇
  2006年   454篇
  2005年   438篇
  2004年   358篇
  2003年   348篇
  2002年   444篇
  2001年   395篇
  2000年   284篇
  1999年   227篇
  1998年   164篇
  1997年   141篇
  1996年   106篇
  1995年   111篇
  1994年   99篇
  1993年   90篇
  1992年   99篇
  1991年   89篇
  1990年   51篇
  1989年   54篇
  1988年   55篇
  1987年   21篇
  1986年   32篇
  1985年   24篇
  1984年   22篇
  1983年   13篇
  1982年   12篇
  1981年   12篇
  1980年   5篇
  1979年   3篇
  1978年   2篇
  1977年   3篇
  1957年   2篇
  1943年   1篇
排序方式: 共有10000条查询结果,搜索用时 468 毫秒
1.
Journal of Optimization Theory and Applications - We distinguish two kinds of piecewise linear functions and provide an interesting representation for a piecewise linear function between two normed...  相似文献   
2.

We study the Bell nonlocality of high dimensional quantum systems based on quantum entanglement. A quantitative relationship between the maximal expectation value B of Bell operators and the quantum entanglement concurrence C is obtained for even dimension pure states, with the upper and lower bounds of B governed by C.

  相似文献   
3.
Redox-based post-translational modification of protein thiols has become an attractive strategy in cellular homeostasis and cell signaling.Due to the reductive end of the redox buffer network,the vicinal dithiol-containing proteins(VDPs)maintains an appropriate oxidation-reduction state of proteins through the reversible transformation from vicinal dithiols to disulfide,which is responsible for a variety of  相似文献   
4.
5.
Yin  Pengpeng  Liu  Chang  Wang  Ying  Guan  Lei  Chen  Xian  Xiong  Xuejia  Jin  Hongzhe 《Russian Journal of General Chemistry》2021,91(5):897-903
Russian Journal of General Chemistry - A dinuclear Tb complex, Tb2(H2L)3(phen)2 (1), and two similar N-donor coordination complexes, Fe(phen)3·HL (2), Fe(bipy)3·HL·5H2O (3) (Na2H2L =...  相似文献   
6.
Because of its unpredictable side effects and efficacy, the anticancer drug docetaxel (DTX) requires improved characterisation of its pharmacokinetic profiles through population pharmacokinetic studies. A sensitive and rugged LC–MS/MS method for the detection of DTX in human plasma was developed and optimised using paclitaxel as an internal standard (IS). The plasma samples underwent rapid extraction using hybrid solid-phase extraction-protein precipitation. The analyte and IS were separated with an isocratic system on a Zorbax Eclipse Plus C18 column using water containing 0.05% acetic acid along with 20 μM of sodium acetate and methanol (30/70, v/v) as the mobile phase. Quantification was performed using a triple quadrupole mass spectrometer through multiple reaction monitoring in positive mode, using the m/z 830.3 → 548.8 and m/z 876.3 → 307.7 transitions for DTX and paclitaxel, respectively. The range of the calibration curve was 1–500 ng/mL for DTX, and the linear correlation coefficient was >0.99. The accuracies ranged from −4.6 to 4.2%, and the precision was no higher than 7.0% for the analytes. No significant matrix effect was observed. Both DTX and the IS showed considerable recovery. This method was finally applied to the establishment of a population pharmacokinetic model to optimise the clinical use of DTX.  相似文献   
7.
In this Letter,a novel system for adaptively correcting the phase of a dynamic multimode beam is proposed.While using merely one spatial light modulator,the phase measurement of the first-order diffraction pattern and the correction of the zeroth diffraction order are simultaneously realized.The real-time experimental result is obtained at a control rate of 10 Hz.The power-in-the-bucket value is improved from 38.5%to 61.8%,even with fundamental mode content that is consistently below 30%.To the best of our knowledge,this is the first implementation of real-time adaptive correction of the entire multimode beam.  相似文献   
8.
The modulation of electron density is an effective option for efficient alternative electrocatalysts. Here, p‐n junctions are constructed in 3D free‐standing FeNi‐LDH/CoP/carbon cloth (CC) electrode (LDH=layered double hydroxide). The positively charged FeNi‐LDH in the space‐charge region can significantly boost oxygen evolution reaction. Therefore, the j at 1.485 V (vs. RHE) of FeNi‐LDH/CoP/CC achieves ca. 10‐fold and ca. 100‐fold increases compared to those of FeNi‐LDH/CC and CoP/CC, respectively. Density functional theory calculation reveals OH? has a stronger trend to adsorb on the surface of FeNi‐LDH side in the p‐n junction compared to individual FeNi‐LDH further verifying the synergistic effect in the p‐n junction. Additionally, it represents excellent activity toward water splitting. The utilization of heterojunctions would open up an entirely new possibility to purposefully regulate the electronic structure of active sites and promote their catalytic activities.  相似文献   
9.
关于绝对半素环和绝对半素根   总被引:3,自引:0,他引:3  
本文了绝对半素环的概念,研究了绝对半素与与半素环及素环之间的关系,讨论了由全体绝对半素环类决定的上根--绝对半半素根及其性质。  相似文献   
10.
A new type of THz waveguides, which employs a solid polyethylene rod as the core and polyethylene tubes in a periodic array of square lattice as the cladding, is proposed. Optical properties of this new THz waveguide, especially in dispersion, confinement loss and single mode property, are investigated in detail with the plane wave expansion method and the beam propagation method. Numerical results demonstrate that the new THz waveguide can reach not only low dispersion but also low confinement loss at single mode propagation. Therefore, the square lattice structure is a better candidate as THz waveguides than the triangular ones.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号