Cumulant functions in optical coherence theory

Cumulant functions are introduced to describe the statistical state of a radiation field. These functions are simply related to the optical coherence functions but have some interesting features. It is shown that if the cumulant functions of all orders greater than some numberN ₀ vanish then they also vanish for all orders greater than 2. Thermal field is the only field having this property. This property holds whether the field is described by a classical stochastic process or by a quantum density operator. Further the particular operator ordering used in defining these cumulant functions for the quantized field affects only the second order cumulant function. To describe the statistical state of a vector field such as partially polarized or unpolarized radiation, one would need to introduce cumulant tensors.     

Gas phase activation energy for unimolecular dissociation of biomolecular ions determined by focused RAdiation for gaseous multiphoton ENergy transfer (FRAGMENT)

We present a novel approach for the determination of activation energy for the unimolecular dissociation of a large (>50 atoms) ion, based on measurement of the unimolecular dissociation rate constant as a function of continuous-wave CO(2) laser intensity. Following a short ( approximately 1 s) induction period, CO(2) laser irradiation produces an essentially blackbody internal energy distribution, whose 'temperature' varies inversely with laser intensity. The only currently available method for measuring such activation energies is blackbody infrared radiative dissociation (BIRD). Compared with BIRD, FRAGMENT: (a) eliminates the need to heat the surrounding ion trap and vacuum chamber to each of several temperatures (each requiring hours for temperature equilibration); (b) offers a three-fold wider range of effective blackbody temperature; and (c) extends the range of applications to include initially cold ions (e.g., gas-phase H/D exchange). Our FRAGMENT-determined activation energy for dissociation of protonated bradykinin, 1.2 +/- 0.1 eV, agrees within experimental error to the value, 1.3 +/- 0.1 eV, previously reported by Williams et al. from BIRD experiments. Copyright 1999 John Wiley & Sons, Ltd.     

A new high-spin isomer in 145Sm

A new high-spin isomer in ¹⁴⁵Sm was observed by in-beam γ-ray spectroscopy with the reaction ¹²²Sn(²⁷Al,3np) at 127 MeV performed at the Nordball multi-detector array in Roskilde. The excitation energy of the isomer was determined to be E _x= 11147 keV, and using the generalized centroid-shift method its half-life was found to be T _1/2= (7.4 ± 1.0) ns. Received: 23 October 1998     

Systematics of related high-spin isomers in 144Sm and other N = 82 nuclei

An in-beam experiment with the reaction ¹²²Sn(²⁷Al,4np) at 127 MeV was performed at the Nordball multi-detector array in Roskilde. It provided evidence for a new high-spin isomer in ¹⁴⁴Sm. This isomer with T _1/2= (2.6 ± 0.5) ns at an excitation energy E _x= 9232 keV seems to belong to a family of isomers of similar configuration in neighbouring N= 82 nuclei. Received: 16 November 1997     

The lifetime of the 266 keV level in 206Tl

The lifetime of the ²⁰⁶Tl 2^? state at 266 keV has been measured by the delayed coincidence technique. The state was populated via the γ-decay of high-lying states excited in the ²⁰⁵Tl (d, p)²⁰⁶Tl reaction at E_d = 9.0 MeV. Delayed coincidences between a Si surface-barrier detector and a Ge(Li) detector resulted in a mean life for the 266 keV level of τ = 3.3(2) ns. The deduced B(E2) value of 171 (11) e² · fm⁴ indicates strong configuration mixing of two-hole states in this level.     

New isomeric states in the stable nucleus 185Re

High-spin states in ¹⁸⁵Re have been studied using the ¹⁷⁶Yb(¹³C,p3n) reaction at 65 MeV. Levels up to spin (37/2) h? at E _x = 4.799 MeV have been identified. Among them two levels were observed with half-lives of 6 ± 2 ns and 123 ± 23 ns.     

Single‐beam coherent anti‐Stokes Raman scattering (CARS) spectroscopy of gas‐phase CO2 via phase and polarization shaping of a broadband continuum

Coherent anti‐Stokes Raman scattering (CARS) spectroscopy of gas‐phase CO₂ is demonstrated using a single femtosecond (fs) laser beam. A shaped ultrashort laser pulse with a transform‐limited temporal width of ∼7 fs and spectral bandwidth of ∼225 nm (∼3500 cm⁻¹) is employed for simultaneous excitation of the CO₂ Fermi dyads at ∼1285 and ∼1388 cm⁻¹. CARS signal intensities for the two Raman transitions and their ratio as a function of pressure are presented. The signal‐to‐noise ratio of the single beam–generated CO₂ CARS signal is sufficient to perform concentration measurements at a rate of 1 kHz. The implications of these experiments for measuring CO₂ concentrations and rapid pressure fluctuations in hypersonic and detonation‐based chemically reacting flows are also discussed. Copyright © 2010 John Wiley & Sons, Ltd.     

A new high-spin isomer in 145Eu

In ¹⁴⁵Eu a high-spin isomer with E _level = 8528 keV and T _1/2 = (3.7 ± 0.4) ns has been observed. The data were obtained by in-beam γ-ray spectroscopy using the reaction ¹²²Sn(²⁷Al,4n)¹⁴⁵Eu at 127 MeV performed at the NORD-BALL spectrometer in Roskilde.     

Multistep rotational energy correlations probed by high fold $γ$ coincidence data

The number of discrete rotational bands in the nucleus ¹⁶⁸Yb is obtained by a fluctuation analysis of the rotational ridge structure in double and triple γ coincidence matrices. The data are compared with cranked shell model calculations including a surface delta interaction. It is found that the number of calculated bands strongly depends on the interaction strength V₀, and agreement between data and calculations supports the standard value V₀= 27.5/A MeV. Received: 11 January 1999     

铌酸锶钡薄膜的微结构与电光性能的研究

本文叙述了使用溶胶凝胶法在MgO(0 0 1)的衬底上制备铌酸锶钡薄膜的过程 ,膜层厚度可达 5 μm。通过X射线衍射、摇摆曲线、扫描、拉曼散射光谱等方法研究了薄膜的微结构性能 ,实验发现 ,铌酸锶钡薄膜具有了较好的 (0 0 1)方向的优先取向性能 ,并且随着薄膜厚度的增加 ,其晶体取向性也会随之不断改进。熔石英的透明衬底上生长的SBN薄膜具有较大的电致双折射效应 ,其有效电光系数能够高达 6 6 2× 10 -11m/V。