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1.
P. Schuurmans J. Wouters P. De Moor N. Severijns W. Vanderpoorten J. Vanhaverbeke L. Vanneste 《Hyperfine Interactions》1992,75(1-4):423-430
Anisotropic α-emission from nuclei in the decay chain from223Ra to207Tl has been observed using low temperature nuclear orientation in combination with high resolution α-detection at 4.2 K. Information
on partial wave amplitudes as well as hyperfine interactions has been extracted. 相似文献
2.
E. Van Walle D. Vandeplassche J. Wouters N. Severijns L. Vanneste 《Hyperfine Interactions》1987,34(1-4):105-109
Since the previous conference we extended our series of on-line -anisotropy measurements in the Z=50 and Z=82 region leading a.o. to the identification of the phase transition in the Au isotopes. Besides conventional on-line low temperature nuclear orientation, we introduced the first on-line applications of NMR/ON, on-line -anisotropy measurements and -decay asymmetry experiments. The intriguing information from these new developments both in the field of nuclear structure and solid state physics is briefly discussed. 相似文献
3.
4.
Applications of the laser microprobe mass analyzer for characterizing the surface of chemically modified minerals (crown ether/montmorillonite and organosilane/sepiolite) and for detecting micro-crystallites at the surface of an inorganic matrix (brucite surface layer of chrysotile fibers) were investigated using laser desorption conditions. The laser microprobe is shown to be a versatile tool for these applications. 相似文献
5.
Michael Woolman Jimmy Qiu Claudia M. Kuzan-Fischer Isabelle Ferry Delaram Dara Lauren Katz Fowad Daud Megan Wu Manuela Ventura Nicholas Bernards Harley Chan Inga Fricke Mark Zaidi Brad G. Wouters James T. Rutka Sunit Das Jonathan Irish Robert Weersink Howard J. Ginsberg David A. Jaffray Arash Zarrine-Afsar 《Chemical science》2020,11(33):8723
Integration between a hand-held mass spectrometry desorption probe based on picosecond infrared laser technology (PIRL-MS) and an optical surgical tracking system demonstrates in situ tissue pathology from point-sampled mass spectrometry data. Spatially encoded pathology classifications are displayed at the site of laser sampling as color-coded pixels in an augmented reality video feed of the surgical field of view. This is enabled by two-way communication between surgical navigation and mass spectrometry data analysis platforms through a custom-built interface. Performance of the system was evaluated using murine models of human cancers sampled in situ in the presence of body fluids with a technical pixel error of 1.0 ± 0.2 mm, suggesting a 84% or 92% (excluding one outlier) cancer type classification rate across different molecular models that distinguish cell-lines of each class of breast, brain, head and neck murine models. Further, through end-point immunohistochemical staining for DNA damage, cell death and neuronal viability, spatially encoded PIRL-MS sampling is shown to produce classifiable mass spectral data from living murine brain tissue, with levels of neuronal damage that are comparable to those induced by a surgical scalpel. This highlights the potential of spatially encoded PIRL-MS analysis for in vivo use during neurosurgical applications of cancer type determination or point-sampling in vivo tissue during tumor bed examination to assess cancer removal. The interface developed herein for the analysis and the display of spatially encoded PIRL-MS data can be adapted to other hand-held mass spectrometry analysis probes currently available.Integration between a hand-held mass spectrometry desorption probe based on picosecond infrared laser technology (PIRL-MS) and an optical surgical tracking system demonstrates in situ tissue pathology from point-sampled mass spectrometry data. 相似文献
6.
Johan Wouters Bernadette Norberg Salvatore Guccione 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(2):o69-o71
The crystal structures of 4‐methyl‐2‐[N‐(3,4‐methylenedioxybenzylidene)hydrazino]thiazole, C12H11N3O2S, and its reduction product 4‐methyl‐2‐[N‐(3,4‐methylenedioxybenzylidene)hydrazono]‐4,5‐dihydrothiazole, C12H13N3O2S, have been determined and compared. In the reduction product, the tautomer observed bears an H atom on the exocyclic N atom. Both compounds form hydrogen‐bonded dimers over centers of inversion. 相似文献
7.
Ibtissam Elaaraj Safae ER. Raouan Asmae Nakkabi Bouchra Es-sounni Ibnsouda Koraichi Noureddine El moualij Mohammed Fahim 《印度化学会志》2022,99(5):100404
New metal complexes of (Zn(II), Co(II), Ni(II) and Cu(II)) based on the ligand 2-(thiophen-2-yl)-1-(thiophen-2-ylmethyl)-1H-benzo[d]imidazole] were synthesized, whose structures were determined with the different spectroscopic techniques 1H NMR,13C NMR, FT-IR, UV–Visible and by mass spectrometry. The thermal analysis was performed by TG-DTA. The antioxidant activity of the ligand and its complexes was evaluated by DPPH (2,2-diphenyl-1-picrylhydrazyl) method, in comparison with the synthetic antioxidant, ascorbic acid. The results obtained showed that the antioxidant activity of the ligand and its complexes is moderate and that the copper complex has a high activity that exceeds that of ascorbic acid. Antimicrobial activity of the ligand and its metal complexes was studied against two Gram-positive bacteria: Bacillus subtilis ILP1428B, Staphylococcus aureus CIP543154 and two Gram-negative bacteria: Pseudomonas aeruginosa ATCC27653, Escherichia coli CIP5412 (American Type Culture Collection)the activity data show that the metal complexes are more potent than the free ligand. 相似文献
8.
Reglucosylation of the Benzoxazinoid DIMBOA with Inversion of Stereochemical Configuration is a Detoxification Strategy in Lepidopteran Herbivores 总被引:1,自引:0,他引:1 下载免费PDF全文
Felipe C. Wouters Dr. Michael Reichelt Dr. Gaétan Glauser Eugen Bauer Dr. Matthias Erb Prof. Jonathan Gershenzon Dr. Daniel G. Vassão 《Angewandte Chemie (International ed. in English)》2014,53(42):11320-11324
Benzoxazinoids are chemical defenses against herbivores and are produced by many members of the grass family. These compounds are stored as stable glucosides in plant cells and require the activity of glucosidases to release the corresponding toxic aglucones. In maize leaves, the most abundant benzoxazinoid is (2R)‐DIMBOA‐Glc, which is converted into the toxic DIMBOA upon herbivory. The ways in which three Spodoptera species metabolize this toxin were investigated. (2S)‐DIMBOA‐Glc, an epimer of the initial plant compound, was observed in the insect frass, and the associated glucosyltransferase activity was detected in the insect gut tissue. The epimeric glucoside produced by the insect was found to be no longer reactive towards plant glucosidases and thus cannot be converted into a toxin. Stereoselective reglucosylation thus represents a detoxification strategy in Spodoptera species that might help to explain their success as agricultural pests on benzoxazinoid‐containing crops. 相似文献
9.
Dr. Aurélien Chardon Arnaud Osi Damien Mahaut Dr. Thu-Hong Doan Dr. Nikolay Tumanov Prof. Johan Wouters Dr. Luca Fusaro Prof. Benoît Champagne Prof. Guillaume Berionni 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(30):12502-12506
A highly bent triarylborane, 9-boratriptycene, was generated in solution by selective protodeboronation of the corresponding tetra-aryl boron ate complex with the strong Brønsted acid HNTf2. The iptycene core confers enhanced Lewis acidity to 9-boratriptycene, making it unique in terms of structure and reactivity. We studied the stereoelectronic properties of 9-boratriptycene by quantifying its association with small N- and O-centered Lewis bases, as well as with sterically hindered phosphines. The resultant Lewis adducts exhibited unique structural, spectroscopic, and photophysical properties. Beyond the high pyramidalization of the 9-boratriptycene scaffold and its low reorganization energy upon Lewis base coordination, quantum chemical calculations revealed that the absence of π donation from the triptycene aryl rings to the boron vacant pz orbital is one of the main reasons for its high Lewis acidity. 相似文献
10.
Kalina Mambourg Laurie Bodart Nikolay Tumanov Steve Lanners Johan Wouters 《Acta Crystallographica. Section C, Structural Chemistry》2020,76(3):205-211
The condensation reaction of 2‐mercapto‐3‐methoxybenzaldehyde with 3‐aminopyridine afforded an unexpected N‐alkylated [1,5]dithiocine instead of the N‐salicylideneaniline. The proposed mechanism for this condensation involves a strong intramolecular hydrogen bond between the thiol and the amine groups, leading to a second condensation. The corresponding product, i.e. 4,10‐dimethoxy‐13‐(pyridin‐3‐yl)‐6H,12H‐6,12‐epiminodibenzo[b,f][1,5]dithiocine methanol 0.463‐solvate, C21H18N2O2S2·0.463CH3OH, was characterized by single‐crystal X‐ray diffraction analysis. The supramolecular structure shows π–π stacking and S…S interactions in the crystal packing. Within the asymmetric unit, two geometries of the N atom are observed. Although a planar geometry should be expected, a pyramidal one is observed due to the crystal packing. The presence of the two geometries was further supported by density functional theory (DFT) calculations that show an electronic energy difference of less than 2 kJ mol?1 between the two conformers. 相似文献