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Kou Hui-Zhong Gao Dong-Zhao Bu Wie-Ming Fan Yu-Guo Liao Dai-Zheng Cheng Peng Jiang Zong-Hui Yan Shi-Ping Wang Geng-Lin Li Tian-Jian Tang Jin-Kui 《Transition Metal Chemistry》2001,26(4-5):457-460
Two CrIII–FeIII complexes, K2[Cr(salen)(H2O)][Fe(CN)6]·H2O (1) and [trans-Cr(tn)2Cl2]3[Fe(CN)6]·6H2O (2), have been prepared. Crystal structure determination shows that complex (2) possesses an ionic salt structure. General physical measurements and magnetic studies indicate that (1) assumes a cyanide-bridged dinuclear structure, and that the CrIII–FeIII magnetic coupling through the cyanide bridge is antiferromagnetic, which can be rationalized by the overlap of magnetic orbitals of the same symmetry. 相似文献
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