The O-H distance in ice

The thermodynamic properties of normal and para-hydrogen are computed from multiple time-step path integral hybrid Monte Carlo (PIHMC) simulations. Four different isotropic pair potentials are evaluated by comparing simulation results with experimental data. The Silvera–Goldman potential is found to be the most accurate of the potentials tested for computing the density and internal energy of fluid hydrogen. Using the Silvera–Goldman potential, simulation and experimental data are compared on isobars ranging from 0.1 to 100 MPa and for temperatures from 18 to 300 K. The Gibbs free energy is calculated from the PIHMC simulations by an adaptation of Widom's particle insertion technique to a path integral fluid. A new method is developed for computing phase equilibria for quantum fluids directly by combining PIHMC with the Gibbs ensemble technique. This Gibbs–PIHMC method is used to calculate the vapour–liquid phase diagram of hydrogen from simulations. Agreement with experimental data is good.     

Air-water two-phase flow in a helically coiled tube

Air-water flow has been studied in a helically coiled tube. The flow pattern transition between stratified and annular flow was examined, and a series of measurements were then taken in the annular flow regime. Local values of the liquid film thickness and liquid film flowrate around the tube periphery were obtained. The variations of these values around the periphery was similar. For most of the cases studied the liquid film flow rate was greatest on the inside of tbe bend, but in some results a subsidiary peak at the outside position was also obtained. There was little net entrained flow because of the centrifugal forces tending to deposit drops very quickly. Attempts to use correlations developed in vertical annular flow at a local position on the tube periphery were not very successful.     

Simultaneous evaluation of electroactive membranes on a four-function isfet by a constant dilution method

Multifunctional ISFETs are used in testing the performance of several nitrate-sensitive polymeric membranes simultaneously. By mounting the ISFET in a miniature flow-through cell, a continuous dilution technique can be used to obtain calibration curves and selectivity coefficient data for several membranes under identical conditions.