全文获取类型
收费全文 | 153篇 |
免费 | 0篇 |
国内免费 | 2篇 |
专业分类
化学 | 73篇 |
力学 | 16篇 |
数学 | 18篇 |
物理学 | 48篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2021年 | 3篇 |
2020年 | 2篇 |
2019年 | 1篇 |
2015年 | 1篇 |
2014年 | 1篇 |
2013年 | 17篇 |
2012年 | 7篇 |
2011年 | 8篇 |
2010年 | 2篇 |
2009年 | 5篇 |
2008年 | 4篇 |
2007年 | 4篇 |
2006年 | 3篇 |
2005年 | 3篇 |
2004年 | 3篇 |
2003年 | 1篇 |
2002年 | 4篇 |
2001年 | 3篇 |
2000年 | 6篇 |
1999年 | 6篇 |
1998年 | 2篇 |
1996年 | 7篇 |
1995年 | 1篇 |
1994年 | 6篇 |
1993年 | 4篇 |
1992年 | 5篇 |
1991年 | 2篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1988年 | 3篇 |
1987年 | 5篇 |
1986年 | 1篇 |
1985年 | 4篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1979年 | 3篇 |
1978年 | 4篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1973年 | 4篇 |
1972年 | 1篇 |
1934年 | 1篇 |
排序方式: 共有155条查询结果,搜索用时 0 毫秒
1.
The anaerobic photochemistry of a number of plausible lignin model compounds (i.e. I: 3,4-Dimethoxy-α-(2-methoxyphenoxy)-β-hydroxypropiophenone;II: 1-(3,4-Dimethoxyphenyl)-2-(2-methoxyphenoxy)-propan-1,3-diol;Pol A: Poly(4-methoxyacrylophenone);Pol B: Poly(3,4-dimethoxyacrylophenone);St 1: 3,5-Dimethoxy-4-hydroxystilbene; andSt 2: 3,5,3′,5′-Tetramethoxy-4-hydroxystilbene) was studied, thin films of these materials being exposed to long-wave (λ≥300 nm) radiation under high vacuum conditions (10?6 torr). In all cases, the only low molecular weight products formed were methane and ethane, and quantum yields were estimated for these reactions. All materials underwent colouration (yellow) and a number of changes were also observed in both the absorbing and emitting characteristics. The colouration was attributed to the presence ofo-quinones which were formed (by further photolysis) from the phenoxy radicals, which were, in turn, produced by O?CH3 fission, the resulting methyl radicals being the precursors of methane and ethane. The stilbenes were in all cases much more reactive (by a factor of about 100); however, they also absorbed higher intensities of radiation in the 300<λ<350 nm region on account of the greater extent of red-shifting of the longest-wave π-π′ aromatic transitions. Gel permeation data indicate the formation of products of cyclization and isomerization of stilbenes and the dimerization of phenoxy radicals while new absorbances in the infrared and13C NMR confirm the presence ofo-quinones in all the models. 相似文献
2.
Four commonly used trapping agents for scintillation counting of14CO2 (Hyamine, Primene, ethanolamine and β-phenylethylamine) were assessed under identical conditions, the progress of trapping being measured directly by pressure changes and by liquid scintillation counting. It was found that quantitative absorption required considerably longer periods of time than those previously reported and that absorption at low14CO2 pressures was very slow. The effects of pressure and stirring rate were also studied. 相似文献
3.
The dipole moments μab of some forty complexes between substituted phenols and substituted pyridines were determined, using the Onsager relation. The dipole increment Δμ, vector difference between μab and the dipole moments μa and μb of the components, show a coherent evolution with the pKa of the donor and of the acceptor and with the complexation enthalpy, when such orientations of the molecules which correspond to a hydrogen bond between the O-H group of the phenol and the lone pair of electrons of the nitrogen atom of the base are chosen. This evolution with respect to the ΔpKa is given by a unique curve for all the complexes. This shows that the difference in pKa between the donor and the acceptor is the main factor determining Δμ for these complexes. This curve presents a sigmoidal aspect in agreement with a model assuming a tautomeric equilibrium between two forms of the hydrogen bond: A-H·B ? A?·H+-B. The corresponding equilibrium constant Ks was computed for the complexes lying in the transition region and obeys the linear relation, log Ks = 0.7pKa-2.25. The data also permit the evaluation of the angle θa between the O-H direction and the dipole moment of the 3,4-dinitrophenol. This angle is of the order of magnitude of 70°, showing the presence of appreciable amounts of different rotamers around the C-O direction in the complexes composed of this acid with pyridines. 相似文献
4.
N. A. Weir 《辐射效应与固体损伤》2013,168(1):23-27
The effect of self-irradiation of β-tritiated polystyrene under high vacuum at 25°C was studied, and simultaneous random chain scission and cross-linking were observed. Analyses of the gaseous products and the colored polymer residue showed that hydrogen was the only volatile product, while spectroscopic measurements indicated that the coloration was associated with the presence of main-chain double bonds. G values for hydrogen formation GH2, cross-linking, G XL and chain scission, G CS were obtained as follows: GH2=0.031; G CS=0.044; G XL=0.061. Possible mechanisms of radiation damage are discussed. 相似文献
5.
N.?F.?Brady J.?M.?Montgomery G.?Tsoi T.?Gebre S.?T.?Weir Y.?K.?Vohra D.?J.?HiltonEmail author 《The European Physical Journal B - Condensed Matter and Complex Systems》2013,86(7):334
We have used X-ray diffraction to study the structural phase of CeCoIn5 in external pressure. Using high-pressure X-ray diffraction, we find that the crystalline phase is stable in the P4/mmm phase for pressures ≤51.2 GPa. From our measured equation of state, we find a bulk modulus given by B 0 = 72.8 ± 2.9 GPa and a first pressure derivative of B ′ = 5.1 ± 0.3. Measurement of the electrical resistivity of CeCoIn5 to pressures as high as 34.4 GPa shows the existence of a peak in resistivity at p ? = 8.2 ± 0.2 GPa. 相似文献
6.
Chelsea Weir Michelle L. Pantoya Gautham Ramachandran Tim Dallas Daniel Prentice Michael Daniels 《Journal of Electrostatics》2013,71(1):77-83
Composite energetic material response to electrical stimuli was investigated and a correlation between electrical conductivity and ignition sensitivity was examined. The composites consisted of micrometer particle aluminum combined with another metal, metal oxide, or fluoropolymer. Of the nine tested mixtures, aluminum (Al) with copper oxide (CuO) was the only mixture to ignite by electrostatic discharge. Under the loose powder conditions of these experiments, the Al–CuO minimum ignition energy (MIE) is 25 mJ and exhibited an electrical conductivity two orders of magnitude higher than the next composite. This study showed a similar trend in MIE for ignition triggered by a discharged spark compared with a thermal hot wire source. 相似文献
7.
Douglas McHugh Sherry SJ Hu Neta Rimmerman Ana Juknat Zvi Vogel J Michael Walker Heather B Bradshaw 《BMC neuroscience》2010,11(1):44
Background
Microglia provide continuous immune surveillance of the CNS and upon activation rapidly change phenotype to express receptors that respond to chemoattractants during CNS damage or infection. These activated microglia undergo directed migration towards affected tissue. Importantly, the molecular species of chemoattractant encountered determines if microglia respond with pro- or anti-inflammatory behaviour, yet the signaling molecules that trigger migration remain poorly understood. The endogenous cannabinoid system regulates microglial migration via CB2 receptors and an as yet unidentified GPCR termed the 'abnormal cannabidiol' (Abn-CBD) receptor. Abn-CBD is a synthetic isomer of the phytocannabinoid cannabidiol (CBD) and is inactive at CB1 or CB2 receptors, but functions as a selective agonist at this Gi/o-coupled GPCR. N-arachidonoyl glycine (NAGly) is an endogenous metabolite of the endocannabinoid anandamide and acts as an efficacious agonist at GPR18. Here, we investigate the relationship between NAGly, Abn-CBD, the unidentified 'Abn-CBD' receptor, GPR18, and BV-2 microglial migration. 相似文献8.
9.
Ong RA Weir AJ Abrams GS Amidei D Baden AR Barklow T Boyarski AM Boyer J Burchat PR Burke DL Butler F Dorfan JM Feldman GJ Gidal G Gladney L Gold MS Goldhaber G Golding L Haggerty J Hanson G Hayes K Herrup D Hollebeek RJ Innes WR Jaros JA Juricic I Kadyk JA Karlen D Klein SR Lankford AJ Larsen RR LeClaire BW Levi M Lockyer NS Lüth V Nelson ME Perl ML Petersen A Richter B Riles K Rowson PC Schaad T Schellman H Schmidke WB Sheldon PD Trilling GH Wood DR Yelton JM 《Physical review letters》1988,60(25):2587-2590
10.
van Enk SJ 《Physical review letters》2000,84(4):789; author reply 790