DeNOx催化剂FeZSM-5/Raney Fe的制备

用原位晶化法合成了FeZSM-5/RFe(RFeRaney Fe)催化剂. 合成液的组成为5Na2O*100SiO2*10TPABr*7 000H2O,pH＞11.5. 合成液中不含Al,ZSM-5分子筛的骨架Al只来源于Raney Fe的表面. 此法提高了ZSM-5分子筛中骨架Al的稳定性和分子筛上Fe离子的负载量. FeZSM-5/RFe用作DeNOx催化剂时具有较高的活性和水热稳定性.     

Trace metal speciation measurements in waters by the liquid binding phase DGT device

The speciation measurements of trace metals by the diffusive gradients in thin-films technique (DGT) using a poly(4-styrenesulfonate) (PSS) aqueous solution as a binding phase and a cellulose dialysis membrane (CDM) as a diffusive layer, CDM-PSS DGT, were investigated and showed good agreement with computer modelling calculations. The diffusion coefficients of ethylenediaminetetraacetic acid (EDTA) complexes with Cd²⁺ and Cu²⁺ were measured and compared with those of the inorganic metal ions. CDM-PSS DGT device was tested for speciation measurement in sample solutions containing EDTA, tannic acid (TA), glucose (GL), dodecylbenzenesulfonic acid (DBS) and humic acid (HA) as complexing ligands forming organic complexes with varying stability constants. Lower percentages of DGT labile copper concentrations over total filterable copper concentrations obtained from the deployments in freshwater sites indicated that copper complexes with organic matter were basically not measured by the devices.     

Metal speciation measurement by diffusive gradients in thin films technique with different binding phases

Since its invention in the mid-1990s, the diffusive gradients in thin films (DGT) technique has rapidly become one of the most promising in situ sampling techniques for trace metal measurement in natural waters. We investigated here the possibility of using DGT devices with different binding phases to determine different DGT labile fractions of Cd and Cu in laboratory solutions and in natural waters. Several binding phases were studied, including conventional Chelex 100 resin imbedded polyacrylamide hydrogel (Chelex) and several recently developed binding phases, poly(acrylamide-co-acrylic acid) (PAM-PAA) gel, poly(acrylamidoglycolic acid-co-acrylamide) (PAAG-PAM) gel, Whatman P81 cellulose phosphate ion-exchange membrane (P81), and poly(4-styrenesulfonate) (PSS) aqueous solution. Laboratory testing in metal solutions spiked with EDTA or humic acid suggested that all the DGT devices measured only free metal ions and inorganic metal complexes. Upon field testing at both freshwater and seawater sites it was found that the DGT labile metal concentrations measured by different binding phases can be significantly different, suggesting that the DGT labile metal fractions were dependent on binding strength of the binding phase. By designing binding phases that can compete with different natural water complexing ligands to varying extents, it is possible to use these different DGT devices to measure metal speciation in natural waters.     

有机碳材料在光电催化系统中的作用

有机碳材料因电荷传导效率高、结构可调、无污染等特点被广泛应用于光电催化领域。将含有机碳材料的催化剂作为电极材料已成为光电催化领域的研究热点之一。本文介绍了几种常见的有机碳材料的结构、特点、制备方法及其研究方向,并将含有机碳材料的电极进行分类。主要总结并论述了有机碳材料在光电催化系统中的五种作用:(1)作为催化剂;(2)作为光敏剂(3)作为电子介质;(4)作为催化剂载体;(5)作为光电极的稳定剂,最后阐述了有机碳材料在光电催化系统中的研究现状及难点问题。     

Surface resonant-states-enhanced acoustic wave tunneling in two-dimensional phononic crystals

We show that by placing a metal plate next to a two-dimensional phononic crystal, acoustic waves can tunnel through the combined structure at a specific frequency that lies inside the band gap of the phononic crystal. The enhanced transmission is attributed to the coupling of the input waves with the acoustically resonant states created between the metal plate and the phononic crystal. Experiments are in excellent agreement with the theoretical predictions.     

Ruthenium nanoclusters anchored on cobalt phosphide hollow microspheres by green phosphating process for full water splitting in acidic electrolyte

Transition metal phosphide(TMP) based electrocatalysts possessing special crystal and electronic structures attract broad attention in the field of electrocatalysis.Immense effort is made to optimize TMP catalysts aiming to satisfy the electrochemical catalysis performance.In this work,an environmentally friendly in situ green phosphating strategy and spatial limiting effect of the RuCo precursor is employed to fabricate the ruthenium nanoclusters anchored on cobalt phosphide hollow microspheres(Ru NCs/Co₂P HMs).The obtained Ru NCs/Co₂P HMs electrocatalysts exhibit high hydrogen evolution reaction(HER) activity at wide pH ranges,which require an overpotential of 77 mV to achieve the current density of 10 mA/cm² in 0.5 mol/L H₂SO₄ and 118 mV in 1.0 mol/L KOH.Besides,the multifunctional Ru NCs/Co₂P HMs exhibit good oxygen evolution reaction(OER) activity with an overpotential of 197 mV to reach the current density of 10 mA/cm² in 0.5 mol/L H₂SO₄,which is below that of the commercial RuO₂ electrocatalyst(248 mV).A two-electrode electrolyzer is assembled as well,in acid electrolyte,it achieves a current density of 10 mA/cm² at a voltage of 1.53 V,which is superior to that of the benchmark of precious metal-based electrolyzer(1.58 V).     

多体系统动力学微分／代数方程组数值方法

多体系统动力学微分／代数混合方程组又称Ｅｕｌｅｒ－ｌａｇｒａｎｇｅ方程,是近十年来动力学和计算数学领域研究的热点之一．本文介绍这两个领域中引入的传统的数值积分方法与新的理论．      

A fixed-parameter-tractable algorithm for set packing

1. IntroductionIt is a useful and challenging task to find efficient algorithms for many computationalhard problems. Recently, the research on Fixed-Parameter nactable Theory arouses muchinterest. FOr example, different fixed- p ax amet er- t rac t ab le- algori t hms for many well- knowndecisio11 pruble11ls illc1udi11g 3-dimellsio11al IIlatchiIlg: a11d vertex--cover Problen1 have beenPrese11ted in [1 8]. Jia11er Chen, DoIlald K. FYiesen al1d Weijia Jia proPosed a coll1pletelynew appro…     

准相位匹配PPKTP晶体连续倍频13 mW绿光输出

采用高压脉冲电场极化,通过电光效应实时监控、倍频通光二维监控等手段的应用,制备出周期为9μm、长为8 mm、宽为3 mm、厚为1 mm的周期极化KTiOPO4晶体(PPKTP);倍频通光实验中,当波长1064 nm的基频光功率为1 W时,得到了功率为13.5 mW的532 nm连续倍频绿光输出,单通倍频转换效率为1.35%,归一化转换效率为1.69%/(W.cm),接近理论最大值。