全文获取类型
收费全文 | 1475篇 |
免费 | 287篇 |
国内免费 | 129篇 |
专业分类
化学 | 940篇 |
晶体学 | 42篇 |
力学 | 69篇 |
综合类 | 19篇 |
数学 | 147篇 |
物理学 | 674篇 |
出版年
2024年 | 1篇 |
2023年 | 33篇 |
2022年 | 32篇 |
2021年 | 45篇 |
2020年 | 67篇 |
2019年 | 66篇 |
2018年 | 45篇 |
2017年 | 61篇 |
2016年 | 71篇 |
2015年 | 85篇 |
2014年 | 94篇 |
2013年 | 104篇 |
2012年 | 136篇 |
2011年 | 127篇 |
2010年 | 105篇 |
2009年 | 96篇 |
2008年 | 116篇 |
2007年 | 106篇 |
2006年 | 83篇 |
2005年 | 63篇 |
2004年 | 53篇 |
2003年 | 40篇 |
2002年 | 35篇 |
2001年 | 28篇 |
2000年 | 31篇 |
1999年 | 22篇 |
1998年 | 17篇 |
1997年 | 22篇 |
1996年 | 17篇 |
1995年 | 8篇 |
1994年 | 11篇 |
1993年 | 14篇 |
1992年 | 14篇 |
1991年 | 7篇 |
1990年 | 7篇 |
1989年 | 8篇 |
1988年 | 1篇 |
1987年 | 4篇 |
1984年 | 1篇 |
1982年 | 2篇 |
1980年 | 2篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1969年 | 1篇 |
1966年 | 1篇 |
1955年 | 1篇 |
排序方式: 共有1891条查询结果,搜索用时 15 毫秒
1.
A nanomaterials-based novel molecular beacon has attracted growing attentions in fluorescent assays as many nanomaterials possess excellent quenching efficiency. In this work, a gold-based nanobeacon probe was established to detect organophosphorus pesticides for the first time. The constructed gold-based nanobeacon acted as a signal indicator and could display the decreasing of the intensity in the presence of targets, which competitively bound to single strand DNA. To achieve a high sensitive probe, some parameters including solution pH, temperature and reaction time were investigated and optimized. The gold-based nanobeacon probe assay was proved to be rapid and sensitive to achieve a detection limit of 0.035 μM for isocarbophos, 0.134 μM for profenofos, 0.384 μM for phorate and 2.35 μM for omethoate, respectively. The prepared nanobeacon effectively reduced the background and improved the detection sensitivity and selectivity. The probe is stable, easy to operate and does not need sophisticated instruments. These features makes the probe feasible for screening trace organophosphorus pesticides in real samples. 相似文献
2.
Yaping Chen Dr. Kun Rui Prof. Jixin Zhu Prof. Shi Xue Dou Dr. Wenping Sun 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(3):703-713
Developing clean and sustainable energies as alternatives to fossil fuels is in strong demand within modern society. The oxygen evolution reaction (OER) is the efficiency-limiting process in plenty of key renewable energy systems, such as electrochemical water splitting and rechargeable metal–air batteries. In this regard, ongoing efforts have been devoted to seeking high-performance electrocatalysts for enhanced energy conversion efficiency. Apart from traditional precious-metal-based catalysts, nickel-based compounds are the most promising earth-abundant OER catalysts, attracting ever-increasing interest due to high activity and stability. In this review, the recent progress on nickel-based oxide and (oxy)hydroxide composites for water oxidation catalysis in terms of materials design/synthesis and electrochemical performance is summarized. Some underlying mechanisms to profoundly understand the catalytic active sites are also highlighted. In addition, the future research trends and perspectives on the development of Ni-based OER electrocatalysts are discussed. 相似文献
3.
研究了Fe(acac)3-Al(i-Bu)3-8-羟基喹啉(acac=乙酰丙酮)催化体系催化丙烯酸丁酯(BA)聚合,考察了聚合规律,用凝胶渗透色谱研究了聚合物分子量和分子量分布.动力学研究表明聚合反应对单体浓度呈一级关系,表观活化能为13.9kJ/mol. 相似文献
4.
研究了不同衬底-阴极距离、直流电压和H2流量对a-CH薄膜沉积速率的影响。结果表明:衬底-阴极距离必须大于0.5cm,随着该距离的增加,薄膜的沉积速率减少;直流电压达550V时沉积速率最大;随着H2含量的增加,CH4含量相对减少,沉积速率随之降低。用AFM观察了以该方法制得的448.4nm CH薄膜的表面形貌,表面粗糙度约为10nm。最后测出了不同条件下CH薄膜的UV-VIS谱,由此可以计算得到薄膜的禁带宽度及折射率。 相似文献
5.
关于局部对称空间中2-调和子流形 总被引:6,自引:0,他引:6
本文研究局部对称完备黎曼流形中的紧致2-调和子流形,得到了这类流形第二基本模式长平方的Pinching定理及推广的J.Simons型积分不等式。 相似文献
6.
7.
D. Liu Y. Li R. An Y. Dou H. Yang Q. Gong 《Applied Physics A: Materials Science & Processing》2006,84(3):257-260
We studied the influence of focusing depth on the index change threshold and damage threshold of silica glass irradiated by a focused 120 fs laser beam. Both thresholds increased with the focusing depth. The aspect ratio of the waveguide cross section can be selected by changing the focusing depth. A 5 mm long waveguide was written at the depth of 2100 μm, which was single mode at 632.8 nm and exhibited propagation loss of 0.56 dB/cm. The refractive index change was calculated to be ∼2.47×10-3. The influence of the focusing depth should be considered in multi-layer devices as shown in the fabrication of a 3×3 waveguide array. PACS 42.62.-b; 42.82.Et; 81.05.Kf 相似文献
8.
9.
Solution rheology of 2‐vinyl pyridine and N‐methyl‐2‐vinyl pyridinium chloride random copolymers in ethylene glycol was studied over wide ranges of concentration and effective charge. The fraction of quaternized monomers α and the fraction of monomers bearing an effective charge f of these copolymers were measured using counterion titration and dielectric spectroscopy, respectively. Ethylene glycol is a good solvent for neutral poly(2‐vinyl pyridine), with very few ionic impurities. The viscosity η and relaxation time τ of dilute and semidilute unentangled solutions exhibit the scaling with concentration and effective charge expected by the Dobrynin model. Reduced viscosity data are independent of concentration in dilute solution, giving an intrinsic viscosity that depends on effective charge, and the experimental data obey the Fuoss law in the semidilute unentangled regime. Scaling concentration with the overlap concentration (c/c*) reduces these data to common curves, and c* ~ f ?12/7 as predicted by the Dobrynin model, where f is the fraction of monomers bearing an effective charge. While the overlap concentration depends strongly on effective charge until counterion condensation occurs, the entanglement concentration ce is surprisingly insensitive to effective charge, indicating that entanglement effects are not understood using the Dobrynin model. The terminal modulus G = η/τ depends only on the number density of chains G = ckT/N for c* < c < ce, and G ~ c3/2 for c > ce independent of the effective charge. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2001–2013, 2006 相似文献
10.