Microscale heat transfer in an evaporating moving extended meniscus

The evaporative heat flux distribution in the leading edge region of a moving evaporating thin liquid film of pentane on quartz was obtained by analyzing the measured thickness profile for thicknesses, δ < 2 μm. The profiles in a constrained vapor bubble were obtained using image analyzing interferometry. Although the evaporating meniscus appeared to be benign (i.e., without additional observed motion beyond creeping), high heat fluxes were obtained. Significantly higher heat fluxes are possible. The interfacial slope, curvature, interfacial shear stress, and liquid pressure profiles were also obtained. Results obtained using a continuum model were consistent with those obtained using a control volume model. The measured pressure field profile of the isothermal extended meniscus agreed with the constant pressure field predicted by the augmented Young–Laplace model. For the non-isothermal case, measured thickness gradients lead to disjoining pressure and curvature gradients for fluid flow and evaporation. The experimental results demonstrate that disjoining pressure at the contact line controls fluid flow within an evaporating completely wetting thin curved film and is, therefore, a useful boundary condition. However, in small interfacial systems, non-idealities can have a dramatic effect.     

Studies on photoinduced effects in pulse-electrodeposited Ag/Hg-1212/CdSe hetero-nanostructures

Metal/superconductor/semiconductor (Ag/Hg-1212/CdSe) hetero-nanostructures have been fabricated using pulse-electrodeposition technique and are characterized by X-ray diffraction (XRD), full-width at half-maximum (FWHM) and scanning electron microscopy (SEM) studies. The junction capacitance of Ag/Hg-1212, Hg-1212/CdSe and Ag/Hg-1212/CdSe heterojunctions is measured in dark and under laser irradiation at room temperature. The nature of the junction formed and built-in-junction potentials were determined. The increase in carrier concentration across the junction due to photo-irradiation has been observed.     

Effect of laser irradiation of C-V characteristics of electrodeposited Ag/Tl-2223/CdSe hetero-nanostructures

One of the innovative technological directions for the high-temperature superconductors has been persued by fabricating the heteroepitaxial multilayer structures such as superconductor-semiconductor heterostructures. In the present investigation, metal/superconductor/semiconductor (Ag/Tl-2223/CdSe) hetero-nanostructures have successfully been fabricated using dc electrodeposition technique and were characterized by X-ray diffraction (XRD), full-width at half-maximum (FWHM) and scanning electron microscopy (SEM) studies. The measurement of junction capacitance as a function of biasing voltage was used for the estimation of junction built-in-potential (V _D) and to study the charge distribution in a heterojunction. The Mott-Schottky plots were measured for each junction in dark and under the photo-irradiation. The effect of laser irradiation on C-V characteristics of hetero-nanostructure has been studied.     

Functionalization of Si(111) surfaces with alkyl chains terminated by electrochemically polymerizable thienyl units

A Si(111) surface has been derivatized with a thiophene-terminated alkyl monolayer which was subsequently photoanodically oxidized in the presence of thiophene to yield a strongly adherent and smooth conducting film.     

Unsaturated spiro-γ-lactone formation by the dissociative reduction of bromoacetates

Unsaturated spiro-γ butyrolactones can be prepared in good yields from bromoacetate precursors by a simple route that requires only 2-propanol as solvent and free radical initiation.     

Organic based reducing agents. Prediction of oxidation potentials of Election rich radicals from the Analysis of AM1 charge density Distributions [1]

Electrochemical oxidation potentials ofmethoxy substituted benzyl, l-naphthylmethyl, phenethyl, diphenylmethyl and cumyl radicals, substituted at the α-, 2-, 3-, or 4-position have been measured by photomodulation voltammetry. These data are compared to ionization potentials calculated using the AM1 molecular orbital method. Although a plot of the oxidation potentials versus the AM1 ionization potentials is quite scattered, an essentially linear relationship is found for a plot of the relative oxidation potential (i.e. compared to that of the unsubstituted parent radical) and the fraction of charge in the 2p_z orbital of the parent cation. The relationship is remarkable considering the potentials span a range of ca. 1 eV (23 kcal mol ^-1) and the fractional charges span a range of ca. 0.5 of a unit charge. The utility of such a relationship as a predictive tool in the design of simple organic based reducing agents is discussed.     

Disjoining pressure and capillarity in the constrained vapor bubble heat transfer system

Using the disjoining pressure concept in a seminal paper, Derjaguin, Nerpin and Churaev demonstrated that isothermal liquid flow in a very thin film on the walls of a capillary tube enhances the rate of evaporation of moisture by several times. The objective of this review is to present the evolution of the use of Churaev's seminal research in the development of the Constrained Vapor Bubble (CVB) heat transfer system. In this non-isothermal "wickless heat pipe", liquid and vapor flow results from gradients in the intermolecular force field, which depend on the disjoining pressure, capillarity and temperature. A Kelvin-Clapeyron model allowed the use of the disjoining pressure to be expanded to describe non-isothermal heat, mass and momentum transport processes. The intermolecular force field described by the convenient disjoining pressure model is the boundary condition for "suction" and stability at the leading edge of the evaporating curved flow field. As demonstrated by the non-isothermal results, applications that depend on the characteristics of the evaporating meniscus are legion.     

Formation, characterization, and chemistry of undecanoic acid-terminated silicon surfaces: patterning and immobilization of DNA

This paper describes a simple strategy for DNA immobilization on chemically modified and patterned silicon surfaces. The photochemical modification of hydrogen-terminated Si(111) with undecylenic acid leads to the formation of an organic monolayer covalently attached to the surface through Si-C bonds without detectable reaction of the carboxylic acid group, providing indirect support of a free radical mechanism. Chemical activation of the acid function was achieved by a simple chemical route using N-hydroxysuccinimide (NHS) in the presence of N-ethyl-N'-(3-dimethylaminopropyl) carbodiimide hydrochloride. Single strand DNA with a 5'-dodecylamine group was then coupled to the NHS-activated surface by amide bond formation. Using a previously reported chemical patterning approach, we have shown that DNA can be immobilized on silicon surfaces in spatially well-resolved domains. Methoxytetraethyleneglycolamine was used to inhibit nonspecific adsorption. The resulting DNA-modified surfaces have shown good specificity and chemical and thermal stability under hybridization conditions. The sequential reactions on the surface were monitored by ATR-FTIR, X-ray Photoelectron Spectroscopy, and fluorescence spectroscopy.