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1.
Wadysaw Charmas Wawrzyniec Podkocielny Joachim Brunn 《Journal of polymer science. Part A, Polymer chemistry》1989,27(7):2397-2415
The process of oxirane ring opening of thioether glycidyl resins under various temperatures has been described. Reaction rate constants (k) and the activaton parameters (Eα, ΔH*, ΔS*) for epoxy group loss of 1,2-epoxy-3-(phenylthio)propane, 1,2-epoxy-3-(p-tolythio)propane, and 1,2-epoxy-3-(p-chloro-phenylthio)propane using classical kinetic methods were determined. The reaction products were separated and analyzed by means of chromatography and the structure of the compounds was determined by means of the spectral analyses: IR, 1H-NMR, and 13C-NMR 相似文献
2.
Wawrzyniec Podkocielny Danuta Wdowicka 《Journal of polymer science. Part A, Polymer chemistry》1983,21(10):2961-2972
New polythioesters by interfacial polycondensation of bis/4-mercaptophenyl/ether with oxalyl, succinyl, adipoyl, suberoyl, or sebacoyl chlorides were obtained. To define the optimal conditions of the process, the polythioesters of dithiol and adipoyl or sebacoyl chlorides were chosen as a model system. Yield for all reaction products and reduced viscosity were found. The following factors were studied: organic phase, contribution of catalyst, concentration and molar ratio of reagents, rate of addition of acid chloride, temperature of reaction, contribution of emulsifier, and concentration of hydrochloride acceptor. The structure of all polythioesters was determined by elementary analysis, infrared spectra, and x-ray. Initial decomposition and initial intensive decomposition temperature were defined by the curves of thermogravimetric analysis. Some mechanical and electrical properties of polythioesters from dithiol and adipoyl or sebacoyl chlorides were studied. The molecular weights for these polymers were also determined by gel-chromatography. 相似文献
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Fila Karolina Grochowicz Marta Podkościelna Beata 《Journal of Thermal Analysis and Calorimetry》2018,133(1):489-497
Journal of Thermal Analysis and Calorimetry - The paper presents the synthesis, structure and polymerization of S-phenyl 2-methylprop-2-enethioate (PSM). This compound was prepared in the reaction... 相似文献
5.
Synthesis and characterization of the new styrene microspheres with pendant methylenethiol groups are presented. At the first stage, the polymeric matrices were obtained by the suspension–emulsion polymerization of monomers: styrene (St) with 2,3‐(2‐hydroxy‐3‐methacryloyloxypropoxy)naphthalene (NAF.DM) or (bis[4(2‐hydroxy‐3‐methacryloyloxypropoxy)phenyl]sulfide (BES.DM) or divinylbenzene (DVB). At the second stage, the modification of the sythesized matrices was performed as follows: the matrices were reacted with paraformaldehyde in the presence of hydrochloric acid forming chloromethyl derivatives. Next, by reaction with thiourea, a thiouronium salt was obtained, and then the hydrolysis with NaOH solution and acidification with HCl were carried out. Finally, microspheres with –CH2SH groups on their surface were obtained. The –SH group content (elemental analysis), thermal properties (thermogravimetric analysis), Fourier transform infrared as well as the swelling characteristics of the functional microspheres were examined. The surface texture was also visualized by the atomic force microscopy (AFM) method. The obtained polymers were screened towards sorption of Cu(II) ions. It was found that a better correlation between the experimental Cu(II) uptake and the theoretical curves predicted by the Langmuir or Freundlich models is obtained in the case of the DVB–St–SH polymer. In the case of the BES.DM–St–SH and 2,3‐NAF–St–SH ones, the Freundlich model corresponded quite well to the experimental data. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
6.
Beata Podkościelna 《Journal of Thermal Analysis and Calorimetry》2013,111(2):1553-1560
Structure and characterization of the sulfur-containing monomers bis[4(2-hydroxy-3-methacryloyloxypropoxy)phenyl]sulfide (S·DM), bis[4(2-hydroxy-3-methacryloyloxypropoxy)phenyl]sulfinyl (SO·DM), bis[4(2-hydroxy-3-methacryloyloxypropoxy)phenyl]sulfonyl (SO2·DM), and their photopolymerization with N-vinyl-2-pyrrolidone (NVP) are presented. The monomers were obtained in the reaction of derivatives of aromatic diols with 2-(chloromethyl)oxirane in the two-phase liquid/liquid system, including organic and aqueous phases. Next, esterification of the obtained diglycidyl ether was carried out with the use of methacrylic acid. Photopolymerization of the compositions (S·DM, SO·DM, SO2·DM and NVP) and the initiator (Irgacure 651) was carried out. The influence of oxidation number of sulfur on the properties of the obtained copolymers was studied. The following properties were determined: density, glass transition temperature, Young’s modulus, hardness and tensile strength. Additionally, dynamic-mechanical and thermal properties were investigated. Thermal properties of copolymers under different conditions (in air, in nitrogen and in helium) were tested. 相似文献
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Dr. Wawrzyniec Kaszub Andrea Marino Dr. Maciej Lorenc Prof. Eric Collet Prof. Elena G. Bagryanskaya Prof. Evgeny V. Tretyakov Prof. Victor I. Ovcharenko Prof. Matvey V. Fedin 《Angewandte Chemie (International ed. in English)》2014,53(40):10636-10640
Molecular compounds with photoswitchable magnetic properties have been intensively investigated over the last decades due to their prospective applications in nanoelectronics, sensing and magnetic data storage. The family of copper‐nitroxide‐based molecular magnets represents a new promising type of photoswitchable compounds. We report the first study of these appealing systems using femtosecond optical spectroscopy. We unveil the mechanism of ultrafast (<50 fs) spin state photoswitching and establish its principal differences compared to other photoswitchable magnets. On this basis, we propose potential advantages of copper‐nitroxide‐based molecular magnets for the future design of ultrafast magnetic materials. 相似文献
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Surface heterogeneity of activated carbons is usually characterized by adsorption energy distribution (AED) functions which can be estimated from the experimental adsorption isotherms by inverting integral equation. The experimental data of phenol adsorption from aqueous solution on activated carbons prepared from polyacrylonitrile (PAN) and polyethylene terephthalate (PET) have been taken from literature. AED functions for phenol adsorption, generated by application of regularization method have been verified. The Grand Canonical Monte Carlo (GCMC) simulation technique has been used as verification tool. The definitive stage of verification was comparison of experimental adsorption data and those obtained by utilization GCMC simulations. Necessary information for performing of simulations has been provided by parameters of AED functions calculated by regularization method. 相似文献
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Beata Podkościelna 《Journal of Thermal Analysis and Calorimetry》2011,104(2):725-730
The thermal stability of the ionic liquids (ILs) 1-n-butyl-3-methylimidazolium bromide, [BMIM]Br, and 1-n-octyl-3-methylimidazolium bromide, [OMIM]Br, was evaluated through thermogravimetry (TG). Long-term isothermal TG studies
revealed that both of these ILs exhibit appreciable decomposition even at temperatures significantly lower than the onset
decomposition temperature, previously determined from fast scan TG experiments. The long-term TG studies of both the ILs showed
linear mass loss as a function of time at each temperature of 10 °C interval in the range 533–573 K over a period of 10 h.
The kinetics of isothermal decomposition of ILs was analyzed using pseudo-zero-order rate expression. The activation energies
for the isothermal decomposition of [BMIM]Br and [OMIM]Br under nitrogen atmosphere are 219.86 and 212.50 kJ mol−1, respectively. The moisture absorption kinetics of these ILs at 25 °C and 30% relative humidity (RH) and at 85 °C and 85%
RH were also studied. Water uptake of ILs exposed at 25 °C/30%RH follows a simple saturation behavior in agreement with Weibull
model while that at 85 °C/85%RH fortuitously fit into the Henderson–Pabis model. 相似文献
10.
Anna Kultys Wawrzyniec Podkocielny Stanisaw Pikus 《Journal of polymer science. Part A, Polymer chemistry》1998,36(13):2359-2369
Two series of new linear polyesters containing sulfur in the main chain were obtained by melt polycondensation of naphthalene-1,4-bis(methylthioacetic acid) (N-1,4-BMTAA) or naphthalene-1,5-bis(methylthioacetic acid) (N-1,5-BMTAA) with some aliphatic diols using a 0.05 molar excess of diol. Softening temperatures ranging from 55 to 130°C, reduced viscosities in the range of 0.15–0.39 dL/g, and low-molecular weights were their characteristic. The structure and thermal properties of all polyesters were examined by using elemental analysis, FT-IR and 1H-NMR spectroscopy, X-ray diffraction analysis, differential thermal analysis (DTA), thermogravimetric analysis (TGA), and differential scanning calorymetry (DSC). The kinetics of polyester formation by uncatalyzed melt polycondensation was studied in a model system: N-1,4-BMTAA or N-1,5-BMTAA and 2,2′-oxydiethanol (ODE) at 150, 160, and 170°C. Reaction rate constants (k3) and activation parameters (ΔG‡, ΔH‡, ΔS‡) from carboxyl group loss were determined using classical kinetic methods. Hydroxyl-terminated polyesters derived from 1,4-butanediol, 1,5-pentanediol, and 1,6-hexanediol were used for preparation of the polyurethanes by melt polyaddition with hexamethylene diisocyanate (HDI). They were characterized by reduced viscosity, FT-IR spectroscopy, X-ray diffraction analysis, TGA, DSC, polarizing microscope observation, and hardness and tensile properties. The resulting polyurethanes behave like high-elasticity thermoplastic elastomers, except the one derived from N-1,5-BMTAA and 1,6-hexanediol-based polyester. © 1998 John Wiley & Sons, Inc. J. Polym. Sci. A Polym. Chem. 36: 2359–2369, 1998 相似文献