A geometric representation of spectral and temporal vowel features: quantification of vowel overlap in three linguistic varieties

A geometrical method for computing overlap between vowel distributions, the spectral overlap assessment metric (SOAM), is applied to an investigation of spectral (F1, F2) and temporal (duration) relations in three different types of systems: one claimed to exhibit primary quality (American English), one primary quantity (Jamaican Creole), and one about which no claims have been made (Jamaican English). Shapes, orientations, and proximities of pairs of vowel distributions involved in phonological oppositions are modeled using best-fit ellipses (in F1 x F2 space) and ellipsoids (F1 x F2 x duration). Overlap fractions computed for each pair suggest that spectral and temporal features interact differently in the three varieties and oppositions. Under a two-dimensional analysis, two of three American English oppositions show no overlap; the third shows partial overlap. All Jamaican Creole oppositions exhibit complete overlap when F1 and F2 alone are modeled, but no or partial overlap with incorporation of a factor for duration. Jamaican English three-dimensional overlap fractions resemble two-dimensional results for American English. A multidimensional analysis tool such as SOAM appears to provide a more objective basis for simultaneously investigating spectral and temporal relations within vowel systems. Normalization methods and the SOAM method are described in an extended appendix.     

Reduction Mechanism of Tellurium Species from Copper Electrowinning Solutions

The presence of tellurium in copper–nickel sulfide ores results in downstream contamination of leach solutions and electrolytes. Tellurium must be removed from leach solutions before electrowinning to prevent contamination of copper cathodes. Cuprous ion is industrially used as a reductant to remove tellurium ions. However, the reduction kinetics of tellurium ions with cuprous is not well known. In this study, the slow Te^VI reduction step with cuprous was identified and a plausible Te^VI reduction mechanism was suggested. The rate‐determining step was investigated by studying the kinetics of the coupled reaction of Te^VI and Te^IV with cuprous. The rate law suggested for the reduction of Te^IV with cuprous and the coupled kinetics equation for consecutive reduction reactions of Te^IV and Te^VI were derived. It was shown that the rate constant of the coupled reaction is very close to the rate constant calculated based on the assumption that Te^VI reduction is a rate‐determining step.     

Imaging cytoplasmic cAMP in mouse brainstem neurons

Background  

cAMP is an ubiquitous second messenger mediating various neuronal functions, often as a consequence of increased intracellular Ca²⁺ levels. While imaging of calcium is commonly used in neuroscience applications, probing for cAMP levels has not yet been performed in living vertebrate neuronal tissue before.     

Stable isotopic studies of earthworm feeding ecology in tropical ecosystems of Puerto Rico

Feeding strategies of earthworms and their influence on soil processes are often inferred from morphological, behavioral and physiological traits. We used (13)C and (15)N natural abundance in earthworms, soils and plants to explore patterns of resource utilization by different species of earthworms in three tropical ecosystems in Puerto Rico. In a high altitude dwarf forest, native earthworms Trigaster longissimus and Estherella sp. showed less (15)N enrichment ((15)N = 3-6 per thousand) than exotic Pontoscolex corethrurus ((15)N =7-9 per thousand) indicating different food sources or stronger isotopic discrimination by the latter. Conversely, in a lower altitude tabonuco forest, Estherella sp. and P. corethrurus overlapped completely in (15)N enrichment ((15)N = 6-9 per thousand), suggesting the potential for interspecific competition for N resources. A tabonuco forest converted to pasture contained only P. corethrurus which were less enriched in (15)N than those in the forest sites, but more highly enriched in (13)C suggesting assimilation of C from the predominant C(4) grass. These results support the utility of stable isotopes to delineate resource partitioning and potential competitive interactions among earthworm species. Copyright 1999 John Wiley & Sons, Ltd.     

Effect of surfactants on wetting of super-hydrophobic surfaces

The effect of surfactants on wetting behavior of super-hydrophobic surfaces was investigated. Super-hydrophobic surfaces were prepared of alkylketene dimer (AKD) by casting the AKD melt in a specially designed mold. Time-dependent studies were carried out, using the axisymmetric drop shape analysis method for contact angle measurement of pure water on AKD surfaces. The results show that both advancing and receding contact angles of water on the AKD surfaces increase over time ( approximately 3 days) and reach the values of about 164 and 147 degrees , respectively. The increase of contact angles is due to the development of a prickly structure on the surface (verified by scanning electron microscopy), which is responsible for its super-hydrophobicity. Aqueous solutions of sodium acetate, sodium dodecyl sulfate, hexadecyltrimethylammonium bromide, and n-decanoyl-n-methylglucamine were used to investigate the wetting of AKD surfaces. Advancing and receding contact angles for various concentrations of different surfactant solutions were measured. The contact angle results were compared to those of a number of pure liquids with surface tensions similar to those of surfactant solutions. It was found that although the surface tensions of pure liquids and surfactant solutions at high concentrations are similar, the contact angles are very different. Furthermore, the usual behavior of super-hydrophobic surfaces that turn super-hydrophilic when the intrinsic contact angle of liquid on a smooth surface (of identical material) is below 90 degrees was not observed in the presence of surfactants. The difference in the results for pure liquids and surfactant solutions is explained using an adsorption hypothesis.     

Wide-bore glass capillary columns for gas chromatography. Their preparation and application

Summary Methods for the preparation of wide-bore glass capillary columns for gas chromatography are presented. The pretreatment of the columns (etching, carbonization, deactivation and/or surface-coating with porous materials), and the coating of them with polar or apolar phases (preferably by the static method) is described. The performance of the columns prepared is evaluated and a number of applications are given, such as analysis of volatile compounds, pesticides, lipids and GC/MS analysis. In some respects, the wide-bore glass capillaries have advantages over the narrow-bore types. They can be installed very easily in GC-instruments, and permit the analysis of larger samples. A system of collecting separated sub-g fractions in glass capillary traps, which makes direc re-injection from these traps possible, completes the methods presented.