Semistar ascending chain conditions over polynomial rings

Ricerche di Matematica - Let D be an integral domain. G. Picozza associated to a stable semistar operation $$\star $$ on D,  a semistar operation $$\star _1$$ on the polynomial ring D[X]....     

Schwingungsspektren und Kraftkonstanten der Übergangsreihen OP(OCH3)3?OPCl3 und SP(OCH3)3?SPCl3

The IR- and RAMAN -spectra are reported from OP(OCH₃)₂Cl, OP(OCH₃)Cl₂, SP(OCH₃)Cl, SP(OCH₃)Cl₂. The assignement to the fundamental vibration is given and all Valence-force-constants are calculated. With increasing number of chlorine atoms decrease f P? OCH₃ and f P? Cl. In the contrary, f O? P and f S? P increase. Here the influence of decreasing electro negativity is compensated by the change from an element of the first period of eight elements to an element of the second period.     

Conjugated Polymers-Based Ternary Hybrid toward Unique Photophysical Properties

The improvement of optical and optoelectronic properties of the individual poly [2-methoxy-5- (2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV), poly[2-methoxy-5-(3,7-dimethyl-octyloxy)-1,4-phenylenevinylene]–End capped with Dimethyl phenyl (OC1C10–PPV–DMP), and poly (9,9′-di- n -octylfluorenyl-2,7-diyl) (F8) was revealed by blending them in ternary hybrid with optimal ratio (F8/2 wt.% MEH-PPV/2 wt.% OC1C10–PPV–DMP). All individual and optimal ternary solutions were prepared via the solution-blending method followed by depositing them onto glass and ITO substrates using spin-coating technique. The semi-crystalline phase of the ternary hybrid and the strong mixing between the conjugated polymers were evidenced by observing the X-ray diffraction patterns that related to F8 into the hybrid diffractogram. The optical and optoelectronic properties of all prepared thin films were investigated in terms of absorption and emission spectra, Commission International d′Eclairage (CIE) coordinates, and current–voltage (I-V) characterizations. Emission peaks at the entire range of visible spectrum can be revealed from the ternary hybrid of the three individual conjugated polymers, producing white emission as evidenced from the emission spectrum and CIE coordinates of the hybrid. Among all fabricated organic light-emitting diodes (OLEDs) devices, the ternary hybrid-based-OLED revealed the best performance in terms of current and turn-on voltage.     

Antibacterial Activity of Dental Composite with Ciprofloxacin Loaded Silver Nanoparticles

Resin composites have been widely used in dental restoration. However, polymerization shrinkage and resultant bacterial microleakage are major limitations that may lead to secondary caries. To overcome this, a new type of antibacterial resin composite containing ciprofloxacin-loaded silver nanoparticles (CIP-AgNPs) were synthesized. The chemical reduction approach successfully produced CIP-AgNPs, as demonstrated by FTIR, zeta potential, scanning electron microscopy, and ultraviolet-visible (UV-vis) spectroscopy. CIP-AgNPs were added to resin composites and the antibacterial activity of the dental composite discs were realized against Enterococcus faecalis, Streptococcus mutans, and the Saliva microcosm. The biocompatibility of modified resin composites was assessed and mechanical testing of modified dental composites was also performed. The results indicated that the antibacterial activity and compressive strength of resin composites containing CIP-AgNPs were enhanced compared to the control group. They were also biocompatible when compared to resin composites containing AgNPs. In short, these results established strong ground application for CIP-AgNP-modified dental composite resins.     

Supply chain optimization of petroleum organization under uncertainty in market demands and prices

A multi-period stochastic planning model has been developed and implemented for a supply chain network of a petroleum organization operating in an oil producing country under uncertain market conditions. The proposed supply chain network consists of all activities related to crude oil production, processing and distribution. Uncertainties were introduced in market demands and prices. A deterministic optimization model was first developed and tested. The impact of uncertainty on the supply chain was studied by performing a sensitivity analysis in which ±20% deviations were introduced in market demands and prices of different commodities. A stochastic formulation was then proposed, which is based on the two-stage problem with finite number of realizations. The proposed stochastic programming approach proved to be quite effective in developing resilient production plans in light of high degree of uncertainty in market conditions. The anticipated production plans have a considerably lower expected value of perfect information (EVPI). The main conclusion of this study is that for an oil producing country with oil processing capabilities, the impact of economic uncertainties may be tolerated by an appropriate balance between crude exports and processing capacities.     

Identification of the Physical Parameters Used in the Thermo-Hygro-Mechanical Model

This paper describes different methods used to identify a large number of physical parameters of the thermo-hygro-mechanical coupling model. This model is developed on the basis of mechanics of porous media and deals with the prediction of response of a structure submitted to thermal, hygrometric and mechanical loading. The aim of this work is mainly to propose some experimental methods for the determination of physical parameters used previously in the model such as hygrometric parameters (liquid Biot's coefficient b _l , vapour and liquid permeability _v, _l and tangent capillary modulus N _ll). Thermal parameters such as thermal conductivity (), specific heat (C) and the thermo-hydrous expansion coefficient ( _i ^p ) have been identified using some works published previously. The different physical parameters were identified in the case of cement mortar without taking into account the influence of hysteresis.     

Structure and insertion properties of disordered and ordered LiNi0.5Mn1.5O4 spinels prepared by wet chemistry

We present the synthesis, characterization, and electrode behavior of LiNi_0.5Mn_1.5O₄ spinels prepared by the wet-chemical method via citrate precursors. The phase evolution was studied as a function of nickel substitution and upon intercalation and deintercalation of Li ions. Characterization methods include X-ray diffraction, SEM, Raman, Fourier transform infrared, superconducting quantum interference device, and electron spin resonance. The crystal chemistry of LiNi_0.5Mn_1.5O₄ appears to be strongly dependent on the growth conditions. Both normal-like cubic spinel [Fd3m space group (SG)] and ordered spinel (P4 ₁ 32 SG) structures have been formed using different synthesis routes. Raman scattering and infrared features indicate that the vibrational mode frequencies and relative intensities of the bands are sensitive to the covalency of the (Ni, Mn)-O bonds. Scanning electron microscopy (SEM) micrographs show that the particle size of the LiNi_0.5Mn_1.5O₄ powders ranges in the submicronic domain with a narrow grain-size distribution. The substitution of the 3d⁸ metal for Mn in LiNi_0.5Mn_1.5O₄ oxides is beneficial for its charge–discharge cycling performance. For a cut-off voltage of 3.5–4.9 V, the electrochemical capacity of the Li//LiNi_0.5Mn_1.5O₄ cell is ca. 133 mAh/g during the first discharge. Differences and similarities between LiMn₂O₄ and LiNi_0.5Mn_1.5O₄ oxides are discussed.