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1.
Natalia Sh. Lebedeva Anatoly I. Vyugin Natalia A. Pavlycheva Elena V. Parfenyuk Olga I. Davidova 《Thermochimica Acta》2002,390(1-2):179-186
The heats of interactions of zinc(II)tetraphenylporphyrine with 30 types of neutral molecules in benzene and carbon tetrachloride were measured using the calorimetric titration method. The thermodynamic characteristics of complex formation were calculated. The satisfactory multiparameter correlation of thermodynamic stability of the molecular complexes formed with physicochemical properties of the neutral molecules (electron pair donor ability, volume, electronic and orientational polarization) was obtained. 相似文献
2.
Muyakshin S. I. Didenkulov I. N. Vyugin P. N. Chernov V. V. Denisov D. M. 《Acoustical Physics》2021,67(3):268-272
Acoustical Physics - The paper presents the results from a study of the interaction of Lamb waves with inhomogeneities in composite plates. It was found that waves of this type are diffracted by... 相似文献
3.
Gurbatov S. N. Vyugin P. N. Deryabin M. S. Kasyanov D. A. Kurin V. V. Tyurina A. V. Bakhtin V. K. 《Acoustical Physics》2021,67(3):237-244
Acoustical Physics - The paper presents the experimental and theoretical studies of diffraction effects in intense acoustic beams diffracted by a narrow circular aperture in a screen. The... 相似文献
4.
E. V. Balantseva E. V. Antina M. B. Berezin A. I. Vyugin 《Journal of Thermal Analysis and Calorimetry》2008,92(3):671-675
The crystal solvates of complexes MP (P is the dianion of tetrakis(3,5-di-t-butylphenyl)porphin, M=Ni(II), Zn(II)) and (Ac)MnP with pyridine have been obtained by isothermal evaporation of corresponding solutions at 35°C.
The formation and the decomposition temperatures of crystal solvates and enthalpies of evaporation pyridine molecules from
those crystal solvates were received using thermogravimetric method. In addition to that, an influence of the type of metal
on the compositions, the energetic and thermal stabilities of the received complexes were analyzed. 相似文献
5.
Guseva G. B. Rumyantsev E. V. Antina E. V. Berezin M. B. Vyugin A. I. 《Russian Journal of Coordination Chemistry》2004,30(5):371-374
The kinetics of deprotonation of 1,3,7,13,17,19-hexamethyl-2,8,12,18-tetrabutylbiladiene-a,c dyhydrobromide on treatment with nucleophilic reagents (pyridine, dimethylformamide, dimethyl sulfoxide) in carbon tetrachloride was measured by electron absorption spectroscopy in the temperature range of 293.15–303.15 K. The effects of the reactant concentrations, the temperature, and the electron-donor properties of the nucleophilic reagent on the kinetics of deprotonation of biladiene-a,c as the salt with HBr are discussed. 相似文献
6.
Natalia A. Dudina Elena V. Antina Galina B. Guseva Anatoly I. Vyugin 《Journal of fluorescence》2014,24(1):13-17
A fluorescent chemosensor based on the 3,3′-bis(dipyrrin) bearing two chromophoric dipyrrin units was synthesized, which showed a strongly enhanced fluorescent intensity in the presence of Zn2+ ions and a high selectivity toward Zn2+ ions over a wide range of tested metal ions in organic solvents. 相似文献
7.
Nataliya Sh. Lebedeva Elena A. Malkova Elena V. Parfenyuk Anatoliy I. Vyugin 《Journal of inclusion phenomena and macrocyclic chemistry》2007,59(1-2):71-80
Spectral and thermochemical studies of complexes of zinc(II)tetra-tertbutylphthalocyanine (Zn(t-Bu)4Pc) with some amines have been carried out. Spectral effects of the complex formation of the metallophthalocyanine with amines
have been established. It has been found that an ability of Zn(t-Bu)4Pc to coordinate amines depends on both their nature and conditions of preparation. Similarity of the crystal structures of
biligand and monoligand of Zn(t-Bu)4Pc complexes to individual β- and α-polymorphs of Zn(t-Bu)4Pc, respectively is proved by IR spectroscopy and X-ray diffraction method. 相似文献
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9.
Natalia A. Bumagina Elena V. Antina Anna Yu. Nikonova Mikhail B. Berezin Alexander A. Ksenofontov Anatoly I. Vyugin 《Journal of fluorescence》2016,26(6):1967-1974
3,3′,5,5′-Tetraphenyl-2,2′-dipyrromethene was described as a highly sensitive and selective Off-on fluorescent colorimetric chemosensor for Zn2+ based on the chelation-enhanced fluorescence (CHEF) effect. The reaction of dipyrromethene ligand with Zn2+ induces the formation of the [ZnL2] complex, which exhibits the increasing fluorescence in 120 fold compared with ligand in the propanol-1/cyclohexane (1:30) binary mixture. The Zn2+ detection limit was 1.4 × 10?7 М. The UV-Vis and fluorescence spectroscopic studies demonstrated that the dipyrromethene sensor was highly selective toward Zn2+ cations over other metal ions (Na+, Mg2+, Co2+, Ni2+, Fe3+, Cu2+, Mn2+, Cd2+ and Pb2+), excluding Hg2+. 相似文献
10.
N. Sh. Lebedeva Yu. A. Gubarev E. S. Yurina A. I. Vyugin I. M. Lipatova 《Russian Journal of General Chemistry》2017,87(10):2327-2331
The interaction of chitosan with copper(II) and cobalt(II) tetrasulfophthalocyanines is studied by spectral methods. The main parameters of binding of chitosan to anionic metal phthalocyanines are determined by Scatchard analysis. It is found that the formation of the polymer complex is considerably contributed by donor?acceptor interactions between the coordinately unsaturated metal phthalocyanine and chitosan amino groups. Сhitosan reacts with a monomeric cobalt(II) tetrasulfophthalocyanine, whereas copper(II) tetrasulfophthalocyanine in its complex with chitosan remains in the dimeric state. The reaction centers responsible for the Cu(SO3H)4Pc)2–chitosan and Co(SO3H)4Pc–chitosan complexes are revealed by means of IR spectroscopy. 相似文献