全文获取类型
收费全文 | 411篇 |
免费 | 0篇 |
专业分类
化学 | 302篇 |
晶体学 | 4篇 |
力学 | 7篇 |
数学 | 5篇 |
物理学 | 93篇 |
出版年
2021年 | 4篇 |
2020年 | 7篇 |
2019年 | 4篇 |
2018年 | 12篇 |
2017年 | 9篇 |
2016年 | 10篇 |
2015年 | 4篇 |
2014年 | 13篇 |
2013年 | 19篇 |
2012年 | 16篇 |
2011年 | 25篇 |
2010年 | 19篇 |
2009年 | 19篇 |
2008年 | 19篇 |
2007年 | 17篇 |
2006年 | 18篇 |
2005年 | 10篇 |
2004年 | 13篇 |
2003年 | 6篇 |
2002年 | 9篇 |
2001年 | 9篇 |
2000年 | 3篇 |
1997年 | 2篇 |
1995年 | 2篇 |
1992年 | 2篇 |
1991年 | 4篇 |
1990年 | 3篇 |
1988年 | 2篇 |
1987年 | 4篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 4篇 |
1983年 | 4篇 |
1982年 | 3篇 |
1981年 | 3篇 |
1980年 | 4篇 |
1979年 | 5篇 |
1978年 | 7篇 |
1977年 | 11篇 |
1976年 | 13篇 |
1975年 | 9篇 |
1974年 | 9篇 |
1973年 | 9篇 |
1972年 | 6篇 |
1971年 | 12篇 |
1970年 | 5篇 |
1969年 | 2篇 |
1968年 | 3篇 |
1967年 | 2篇 |
1954年 | 2篇 |
排序方式: 共有411条查询结果,搜索用时 15 毫秒
1.
M. G. Voronkov N. N. Vlasova S. A. Bolshakova S. V. Kirpichenko 《Journal of organometallic chemistry》1980,190(4):335-341
The hydrosilylation of mono- and di-alkenyl sulphides of the type RS(CH2)nCH=CH2 (R = C2H5, CH2=CH, CH2=CHCH2, C3H7, n = 0, 1 and 4) by triethyl- and triethoxy-silane, catalyzed by H2PtCl6·6 H2O, (Ph3P)3RhCl and (PhCN)2PdCl2·Ph3P, has been studied. The addition of hydrosilane to the double bond of alkenyl sulphide leads to a mixture of two isomeric monoadducts. The hydrosilane can cleave the C---S bond of the initial sulphides giving the corresponding derivatives of thiosilanes, X3SiS(CH2)nCH=CH2 (X = C2H5, C2H5O). Hydrosilylation of alkenyl sulphides is accompanied by some side reactions such as dehydrocondensation, reduction and polymerization. The effect of the catalyst nature, the structure of hydrosilane and alkenyl sulphide on the reaction route has been investigated. 相似文献
2.
E. M. Peresleni M. Ya. Uritskaya V. A. Azimov V. A. Loginova T. F. Vlasova Yu. N. Sheinker L. N. Yakhontov 《Chemistry of Heterocyclic Compounds》1974,10(3):340-344
It was shown by means of IR, UV, and PMR spectra that -(3-nitro-2-pyridyl)pyruvic acid esters are practically completely enolized in the crystal state and in solution; ethyl -(3-nitro-4-pyridyl)pyruvate has an enol structure in the crystalline state and in pyridine solution but exists as a mixture of keto and enol forms in low-polarity solvents.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 389–393, March, 1974. 相似文献
3.
. . .
. , L
p[0, l], 1 >p <, . 相似文献
4.
M. V. Solovskii M. Yu. Eropkin E. M. Eropkina A. V. Slita M. Yu. Smirnova E. N. Vlasova E. B. Tarabukina A. I. Amirova 《Russian Journal of Applied Chemistry》2007,80(10):1703-1707
Nontoxic water-soluble low-molecular-weight (MW 14 000–36 000 Da) copolymers of acrylamide with 2-acrylamido-2-methylpropanesulfonic
acid, containing from 17.3 to 37.6 mol % sulfonate-containing monomeric units, were synthesized by heterophase radical polymerization
in isopropanol or ethanol at 50°C with azobis(isobutyronitrile) as an initiator.
Original Russian Text M.V. Solovskii, M.Yu. Eropkin, E.M. Eropkina, A.V. Slita, M.Yu. Smirnova, E.N. Vlasova, E.B. Tarabukina,
A.I. Amirova, 2007, published in Zhurnal Prikladnoi Khimii, 2007, Vol. 80, No. 10, pp. 1674–1678. 相似文献
5.
6.
V. E. Schneider E. E. Tornau A. A. Vlasova A. A. Gurskas 《Journal of inclusion phenomena and macrocyclic chemistry》1985,3(3):235-242
Clathrate thermodynamic stability conditions and the phase transitions associated with either the orientational ordering of the guest molecules or with the condensation of the guest molecules in the host lattice are investigated by means of the common microscopic model. The theory proposed describes the thermodynamic properties of -hydroquinone (Q
) clathrates. The dielectric constant (T) was measured experimentally inQ
·CH3OH andQ
·SO2 in the temperature range from 4.2 to 300 K and the phase transitions were found. It is shown that the theory qualitatively explains the experimental data obtained.Dedicated to Professor H. M. Powell. 相似文献
7.
The condensation of 2-amino- and 2-methylthio-4, 6-dihydroxypyrimidines and barbituric and thiobarbituric acids with -diketones in strong acids leads to pyrylia[2,3-d]pyrimidine salts, which on treatment with ammonia or aniline are converted to pyrido[2,3-d]pyrimidines or to 8-phenylpyrido[2,3-d]pyrimidinium salts, respectively.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1484–1486, November, 1977. 相似文献
8.
N. N. Vlasova O. Yu. Grigor’eva M. G. Voronkov 《Russian Journal of General Chemistry》2005,75(6):860-861
N,N′-Bis(trimethylsilylmethyl)-λ6-thiocarbamide S,S-dioxide was synthesized by oxidation of N,N′-bis(trimethylsilylmethyl)thiocarbamide with hydrogen peroxide. The synthesized dioxide is a less active reducing agent than previously studied S,S-dioxides of organosilicon thiocarbamides in which the silicon atom is separated from the thiocarbamide fragment by a -CH2CH2CH2- bridge.__________Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 6, 2005, pp. 912–914.Original Russian Text Copyright © 2005 by Vlasova, Grigor’eva, Voronkov. 相似文献
9.
N. N. Vlasova O. Yu. Grigor’eva E. N. Oborina Yu. N. Pozhidaev L. I. Larina M. G. Voronkov 《Russian Journal of General Chemistry》2006,76(7):1081-1084
The reaction of triethoxysilylpropylamine (AGM-9) with dicyanodiamide was studied. The condensation of AGM-9 with dicyanodiamide occurs in the presence of a catalytic amount of CuCl2 at 125–145°C within 5–24 h; it involves both the amino group of AGM-9 and ethoxy substituents at the Si atoms, with an unusual exchange of a Si-O bond for a Si-N bond. The final reaction product is 1-N-(3-triethoxysilylpropyl)-2-N-[3-aminopropylsilyl(diethoxy)]biguanidine. Its hydrolytic polycondensation yields an organosilicon polymer, a polycondensate of AGM-9 with 1-N-(3-triethoxysilylpropyl)biguanidine, which is a highly efficient sorbent for Ag(I) (static sorption capacity 544 mg g?1). 相似文献
10.
R. R. Shakirov L. I. Vlasova D. V. Shishkin N. N. Yarmukhamedov N. Z. Baybulatova D. G. Semesko V. A. Dokichev Yu. V. Tomilov 《Russian Chemical Bulletin》2005,54(7):1737-1743
5-Nitropentan-2-one reacts with methylamine and formaldehyde according to the Mannich reaction pattern to give 5-hexahydropyrimidinylcarbonyl-substituted
1-nitro-3,7-diazabicyclo[3.3.1]nonane in one experimental stage. When methyl 3-R-4-nitrobutanoates are used, the reaction
stops after the formation of substituted 5-nitrohexahydropyrimidines in 40–98% yields.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1687–1693, July, 2005. 相似文献