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排序方式: 共有168条查询结果,搜索用时 15 毫秒
1.
A commercially available on-line energy dispersive x-ray fluorescence (EDXRF) system has been modified for glove box operations and installed on the Advanced Testing Line for Actinide Separations (ATLAS) at Los Alamos. The goal is to quantitatively monitor actinides and metal impurities in an anion-exchange effluent to obtain near-real-time chemical information. Because of recent compliance issues, metals listed in the Resource Conservation and Recovery Act (RCRA) and other low level radioactive components are also being analyzed. Initial experiments on how pre concentration techniques can be applied to on-line EDXRF measurements for improved detection limits have also been conducted. An overview of these developments is presented in this paper. 相似文献
2.
Seghezzo L Trupiano AP Liberal V Todd PG Figueroa ME Gutiérrez MA Da Silva Wilches AC Iribarnegaray M Guerra RG Arena A Cuevas CM Zeeman G Lettinga G 《Applied biochemistry and biotechnology》2003,109(1-3):167-180
A pilot-scale sewage treatment system consisting of two upflow anaerobic sludge bed (UASB) reactors followed by five waste stabilization ponds (WSPs) in series was studied under subtropical conditions. The first UASB reactor started up in only 1 mo (stable operation, high chemical oxygen demand [COD] removal efficiency, low volatile fatty acids concentration in the effluent, alkalinity ratio above 0.7, biogas production above 0.1 Nm3/kg of CODremoved). Removal efficiencies up to 90% were obtained in the anaerobic steps at a hydraulic retention time of 6 + 4 h (80% removal in the first step). Fecal coliform removal in the whole system was 99.9999% (99.94% in anaerobic steps and 99.98% in WSPs). COD balances over UASB reactors are provided. A minimum set of data necessary to build COD balances is proposed. Intermittent sludge washout was detected in the reactors with the COD balances. Sludge washout from single-step UASB reactors should be monitored and minimized in order to ensure constant compliance with discharge standards, especially when no posttreatment is provided. The system combined high COD and fecal coliform removal efficiency with an extremely low effluent concentration, complying with discharge standards, and making it an attractive option for sewage treatment in subtropical regions. 相似文献
3.
An experimental and computational investigation of the effects of local fluid shear rate on the aggregation and breakage of approximately 10 microm latex spheres suspended in an aqueous solution undergoing laminar Taylor-Couette flow was carried out according to the following program. First, computational fluid dynamics (CFD) simulations were performed and the flow field predictions were validated with data from particle image velocimetry experiments. Subsequently, the quadrature method of moments (QMOM) was implemented into the CFD code to obtain predictions for mean particle size that account for the effects of local shear rate on the aggregation and breakage. These predictions were then compared with experimental data for latex sphere aggregates (using an in situ optical imaging method) and with predictions using spatial average shear rates. The mean particle size evolution predicted by CFD and QMOM using appropriate kinetic expressions that incorporate information concerning the particle morphology (fractal dimension) and the local fluid viscous effects on aggregation collision efficiency match well with the experimental data. 相似文献
4.
Anthony Fratiello Vicki Kubo-Anderson Soheil Azimi Thomas Flores Eric Marinez Dennis Matejka Richard Perrigan Michael Vigil 《Journal of solution chemistry》1990,19(8):811-829
A coordination study of Lu(III) has been carried out for the nitrate and perchlorate salts in aqueous mixtures of acetone-d6 and Freon-12 by1H,15N and35Cl NMR spectroscopy. At temperatures lower than –90°C, proton and ligand exchange are slow enough to permit the direct observation of1H resonance signals for coordinated and free water molecules, leading to an accurate measure of the Lu(III) hydration number. In perchlorate solution, in the absence of inner-shell ion-pairing, Lu(III) exhibits a maximum coordination number of six over the allowable concentration range of study, contrasting markedly with the report of values of six to nine or greater as determined by a similar NMR method. The absence of contact ion-pairing was confirmed by35Cl NMR chemical shift and linewidth measurements. Extensive ion-pairing was observed in the nitrate solutions as reflected by the lower Lu(III) hydration numbers of two to three in these systems, the observation of two coordinated water signals, and15N NMR signals for two complexes. The1H and15N NMR spectra and the hydration number could be accounted for by the presence of (H2O)4Lu(NO3)2+ and (H2O)2Lu(NO3)
2
1+
. 相似文献
5.
Viviana Solferino Marco Squassina 《Journal of Fixed Point Theory and Applications》2012,11(1):137-157
For quasi-linear elliptic equations we detect relevant properties which remain invariant under the action of a suitable class of diffeomorphisms. This yields a connection between existence theories for equations with degenerate and nondegenerate coerciveness. 相似文献
6.
Viviana De Luca Paolo Digiamberardino Giovanna Di Pasquale Salvatore Graziani Antonino Pollicino Elena Umana Maria Gabriella Xibilia 《Journal of Polymer Science.Polymer Physics》2013,51(9):699-734
Smart systems adapt to the surrounding environments in a number of ways. They are capable to scavenge energy from available sources, sense and elaborate external stimuli and adequately react. Electro Active Polymers are playing a main role in the realization of smart systems for applications if fields such as bio inspired and autonomous robotics, medicine, and aerospace. This paper focus on the possibility to use Ionic Polymer Metal Composites as a class of materials relevant to the realization of post silicon smart systems. The three main aspects of this new technology, i.e., fabrication methods, modeling, and applications are described with emphasis to most recent results. Attention is given to main challenges and shortcomings to be solved for technology, modelling, and control of IPMC based devices that need to be solved before this new technology can be fully exploited in real world applications. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2013 相似文献
7.
Viviana Heguaburu Hugo do Carmo Florencia Parpal María Eugenia Amorós Andrés González 《Tetrahedron letters》2017,58(18):1738-1741
The synthesis of 3-hydroxy-2-hexanone and 2,3-hexanediol, two components of the aggregation pheromone of several cerambycid species, is disclosed in here. Starting from 2-hexanone, through an α-hydroxylation using (diacetoxyiodo)benzene, 3-hydroxy-2-hexanone is obtained in good yield. Further reduction of this compound, gives 2,3-hexanediol in excellent yield. A study of the α-hydroxylation reaction of several alkylketones using an hypervalent iodine reagent is also disclosed in here. The synthesis of optically active compounds (R)- and (S)-3-hydroxy-2-hexanone was achieved starting from 2-hexanone with nitrosobenzene and l- and d-proline respectively, in several reaction media. 相似文献
8.
Luisa Pieroni Federica Iavarone Alessandra Olianas Viviana Greco Claudia Desiderio Claudia Martelli Barbara Manconi Maria Teresa Sanna Irene Messana Massimo Castagnola Tiziana Cabras 《Journal of separation science》2020,43(1):313-336
More than 300 different protein post‐translational modifications are currently known, but only a few have been extensively investigated because modified proteoforms are commonly present in sub‐stoichiometry amount. For this reason, improvement of specific enrichment techniques is particularly useful for the proteomic characterization of post‐translationally modified proteins. Enrichment proteomic strategies could help the researcher in the challenging issue to decipher the complex molecular cross‐talk existing between the different factors influencing the cellular pathways. In this review the state of art of the platforms applied for the enrichment of specific and most common post‐translational modifications, such as glycosylation and glycation, phosphorylation, sulfation, redox modifications (i.e. sulfydration and nitrosylation), methylation, acetylation, and ubiquitinylation, are described. Enrichments strategies applied to characterize less studied post‐translational modifications are also briefly discussed. 相似文献
9.
Giulia Festa Claudia Scatigno Francesco Armetta Maria Luisa Saladino Veronica Ciaramitaro Viviana Mollica Nardo Rosina Celeste Ponterio 《Molecules (Basel, Switzerland)》2022,27(1)
Spectral preprocessing data and chemometric tools are analytical methods widely applied in several scientific contexts i.e., in archaeometric applications. A systematic classification of natural powdered pigments of organic and inorganic nature through Principal Component Analysis with a multi-instruments spectroscopic study is presented here. The methodology allows the access to elementary and molecular unique benchmarks to guide and speed up the identification of an unknown pigment and its recipe. This study is conducted on a set of 48 powdered pigments and tested on a real-case sample from the wall painting in S. Maria Delle Palate di Tusa (Messina, Italy). Four spectroscopic techniques (X-ray Fluorescence, Raman, Attenuated Total Reflectance and Total Reflectance Infrared Spectroscopies) and six different spectrometers are tested to evaluate the impact of different setups. The novelty of the work is to use a systematic approach on this initial dataset using the entire spectroscopic energy range without any windows selection to solve problems linked with the manipulation of large analytes/materials to find an indistinct property of one or more spectral bands opening new frontiers in the dataset spectroscopic analyses. 相似文献
10.
Marina Quartu Maria Pina Serra Marianna Boi Viviana Ibba Tiziana Melis Marina Del Fiacco 《BMC neuroscience》2008,9(1):108