全文获取类型
收费全文 | 592篇 |
免费 | 10篇 |
专业分类
化学 | 325篇 |
晶体学 | 4篇 |
力学 | 40篇 |
数学 | 96篇 |
物理学 | 137篇 |
出版年
2022年 | 5篇 |
2021年 | 18篇 |
2020年 | 10篇 |
2019年 | 8篇 |
2018年 | 12篇 |
2017年 | 5篇 |
2016年 | 16篇 |
2015年 | 9篇 |
2014年 | 6篇 |
2013年 | 22篇 |
2012年 | 29篇 |
2011年 | 23篇 |
2010年 | 15篇 |
2009年 | 17篇 |
2008年 | 33篇 |
2007年 | 26篇 |
2006年 | 36篇 |
2005年 | 21篇 |
2004年 | 17篇 |
2003年 | 18篇 |
2002年 | 18篇 |
2001年 | 7篇 |
2000年 | 10篇 |
1999年 | 3篇 |
1998年 | 10篇 |
1997年 | 12篇 |
1996年 | 14篇 |
1995年 | 11篇 |
1994年 | 11篇 |
1992年 | 7篇 |
1991年 | 9篇 |
1990年 | 11篇 |
1989年 | 6篇 |
1988年 | 4篇 |
1987年 | 5篇 |
1986年 | 6篇 |
1985年 | 5篇 |
1984年 | 13篇 |
1982年 | 5篇 |
1981年 | 8篇 |
1980年 | 9篇 |
1979年 | 7篇 |
1978年 | 8篇 |
1977年 | 9篇 |
1976年 | 5篇 |
1975年 | 4篇 |
1971年 | 4篇 |
1966年 | 3篇 |
1919年 | 2篇 |
1906年 | 2篇 |
排序方式: 共有602条查询结果,搜索用时 15 毫秒
1.
This paper describes the performance and simulation of a compact integrated optical processor for the real-time reconstruction of two-dimensional images in airborne stripmap synthetic aperture radar applications. The functional behavior of the processor is explained in some detail. The design criteria are briefly given. The simulation step allowed the main processor characteristics and properties to be identified. A number of comparisons were obtained in airborne SAR mission scenarios between the predictions of the optical device and those achieved by the modern electronic digital approach, based on the wavefront reconstruction method by matched filtering. 相似文献
2.
A. Wajid C. Gogol C. Hurd M. Hetzel A. Spina R. Lum M. McDonald R. J. Capik 《Journal of Crystal Growth》1997,170(1-4):237-241
We describe a continuous wave resonant acoustic sensor that has been optimized as a very sensitive in-line monitor for measuring the composition of precursor gases used in MOCVD processes. The precursor/carrier gas mixtures flow through a compact stainless steel acoustic chamber that is isolated from the acoustic transducers by a set of metallic diaphragms. The sensor has been successfully operated at supply line pressures from atmosphere down to 50 Torr with gas flow rates of up to 1600 sccm. The accuracy of the speed of sound measurement for hydrogen gas is better than 0.005%, even in a high noise and low pressure environment. Hydrogen, as well as nitrogen or argon carrier gases, are accommodated within the instrument's 1–5 kHz working frequency range. The instrument's sensitivity and stability are demonstrated with the laboratory data. Measurements of the dynamic response characteristics of the metalorganic bubbler lines at low pressure are also be presented. Application of the cell is general, encompassing any of the metalorganic and hydride materials typically used in MOCVD processes. 相似文献
3.
L. Cianchi F. Del Giallo F. Pieralli M. Mancini S. Sciortino G. Spina 《Hyperfine Interactions》1991,66(1-4):387-391
Mössbauer parameters of151Eu in Eu1+x Ba2?x Cu3O7+δ have been studied as a function of temperature, forx=0.15 andx=0.25. The areas of the absorption spectra for the two samples are almost equal. This could mean that thef-Mössbauer factor for151Eu at the barium sites is much smaller than that for151Eu at the rare earth sites, i.e. we only observe the spectra of the latter sites. According to this, the fits of the spectra with a single quadrupolar pattern and with two quadrupolar patterns have given equivalent χ2 values. 相似文献
4.
Marko D. Mihovilovic Bernhard Müller Markus Spina Arjumand I. Durrani Peter Stanetty Georg Dazinger Karl Kirchner 《Monatshefte für Chemie / Chemical Monthly》2006,137(6):785-794
Summary. Recombinant Escherichia coli overexpressing Pseudomonas sp. NCIMB 9872 cyclopentanone monooxygenase (CPMO, EC 1.14.13.16) and Acinetobacter sp. NCIMB 9871 cyclohexanone monooxygenase (CHMO, EC 1.14.13.22) have been utilized in whole-cell Baeyer-Villiger biotransformations of prochiral bicycloketones. A significant difference in substrate acceptance and stereoselectivity was
observed for bicyclo[3.3.0] and bicyclo[4.3.0] substrates. A plausible mechanism of these transformations was established
by means of high level DFT/B3LYP calculations suggesting an essential difference in electronic requirements for a successful
enzymatic conversion, which was similarly encountered in recombinant whole-cell mediated biooxidations. Some of the lactones
produced in the biocatalytic Baeyer-Villiger oxidation represent key intermediates for the synthesis of indole alkaloids. 相似文献
5.
6.
Vincenzo Piazza Vittorio PellegriniFabio Beltram Werner Wegscheider 《Solid State Communications》2003,127(2):163-168
Time-dependent capacitance measurements reveal an unstable phase of electrons in gallium arsenide quantum well that occurs when two Landau levels with opposite-spin are brought close to degeneracy by applying a gate voltage. This phase emerges below a critical temperature and displays a peculiar non-equilibrium dynamical evolution. The relaxation dynamics is found to follow a stretched-exponential behaviour and correlates with hysteresis loops observed by sweeping the magnetic field. These experiments indicate that metastable randomly distributed magnetic domains with peculiar excitations are involved in the relaxation process in a way that is equivalently tunable by a change in gate voltage or temperature. 相似文献
7.
Vittorio Cantoni 《International Journal of Theoretical Physics》1996,35(10):2121-2124
It is shown that the Kähler equation in a four-dimensional pseudo-Riemannian manifold with Lorentzian signature decomposes uniquely into four uncoupled equations of Duffin type. 相似文献
8.
The heats of dilution of nine ternary solutions of urea and polyols have been determined at 25°C. Excess enthalpies and their virial coefficients h
xy
have been evaluated and compared with the data reported in the literature for mono- and polyfunctional alcohols and other oxygenated nonelectrolytes. The group additivity approach of Savage and Wood was applied and the contributions to the enthalpy coefficients, due to the water mediated interactions between urea and the functional groups –CH2–, –OH, and –O– were determined. On the other hand, by using empirical combination rules among the cross- and self-enthalpic interaction coefficients it is possible to emphasize the large differences in the behavior (even in the presence of urea) of the polyols (and in particular of cyclitols) and of saccharides. 相似文献
9.
Giuseppina Castronuovo Vittorio Elia Filomena Velleca 《Journal of solution chemistry》1995,24(12):1209-1217
Calorimetric measurements were carried out at 25°C on binary and ternary aqueous solutions containing L and D forms fo the following -aminoacids: tryptophan, cysteine, methionine, phenylalanine, histidine, threonine, and citrulline, which contain both hydrophilic and hydrophobic domains. Differences were found between the values of the homochiral and heterochiral pairwise enthalpic interaction coefficients for tryptophan, cysteine, and methionine. To the contrary, chiral recognition was not detected for phenylalanine, histidine, citrulline, and threonine. The data were interpreted in terms of a preferential configuration model. Chiral recognition is detected only when the interactions of the side chains in the homo- and heterochiral configurations are different. Chiral recognition disappears when a competition exists between zwitterion-zwitterion interactions and side chain-side chain interactions. In some cases, such as for citrulline, compensation effects can occur due to thermal contributions from different domains which mask chiral recognition. 相似文献
10.
Vittorio Coti Zelati 《manuscripta mathematica》1987,57(4):417-424
We study the existence of T-periodic solutions for the forced system of differential equations –ÿ=V(y)+h(t), where h is T-periodic and V is defined in an open, bounded and convex subset of RN and V– as y tends to the boundary of the set. We prove existence of at least one solution only requiring convexity of V near the boundary.Supported by Ministero Pubblica Istruzione, Gruppo Nazionale (40%) Calcolo delle Variazioni 相似文献