排序方式: 共有11条查询结果,搜索用时 15 毫秒
1.
Nispa Seetapan Katanchalee Mai-ngam Nopparat Plucktaveesak Anuvat Sirivat 《Rheologica Acta》2006,45(6):1011-1018
Chitosan-g-poly(N-isopropylacrylamide) (chitosan-g-PNIPAM) was synthesized and characterized rheologically in aqueous solutions. The copolymer solution exhibits a thermoassociative behavior in which its elastic response dramatically increases when temperature is above the critical temperature or the association temperature, T
assoc. The copolymer at low concentration shows typical solution property. When the temperature is increased up to the critical temperature, the copolymer exhibits a gel-like characteristic due to the formation of physical cross-links between chitosan backbones through the self-aggregation of PNIPAM side chains. At high concentration, the system exhibits a weak elastic response due to the entanglement of the copolymer at 25°C. As temperature is raised above T
assoc, the system shows a strong elastic behavior due to the formation of additional physical cross-links via the aggregation of PNIPAM side chains. Chitosan-g-PNIPAM offers an attractive associating behavior in aqueous solution at temperature close to the body temperature, thus providing potential applications in pharmaceutical and medical industries. 相似文献
2.
Water pollution assessment problems arise frequently in environmental science. In this research, the finite element method for solving the one-dimensional steady convection-diffusion equation with constant coefficients is presented; it is then used to optimize water treatment costs. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
3.
Jae‐Hong Lim Nopparat Phiboolsirichit Syed Mubeen Youngwoo Rheem MarcA. Deshusses Ashok Mulchandani NosangV Myung 《Electroanalysis》2010,22(1):99-105
The electrical transport and NH3 sensing properties of randomly oriented and aligned SWNT networks were presented and discussed. The results indicate that aligned SWNT‐FETs have better FET characteristics due to the reduced number of interconnected nodes. This was particularly true as the resistance of the devices increased. Gated electrical breakdown was implemented to selectively remove metallic (m‐) SWNTs, thereby reducing scattering centers. This technique provided significant improvements in FET characteristics resulting in greater on/off ratio (e.g. 104). AC dielectrophoretic alignment followed by selective electrical breakdown of m‐SWNTs can significantly enhance the semiconducting properties of SWNT networks which resulted in highly sensitive sensors. 相似文献
4.
5.
Wuttinont Thaweesest Visarut Buranasudja Rianthong Phumsuay Chawanphat Muangnoi Opa Vajragupta Boonchoo Sritularak Paitoon Rashatasakhon Pornchai Rojsitthisak 《Molecules (Basel, Switzerland)》2022,27(12)
Oxyresveratrol (OXY) has been reported for its anti-inflammatory activity; however, the pharmaceutical applications of this compound are limited by its physicochemical properties and poor pharmacokinetic profiles. The use of an ester prodrug is a promising strategy to overcome these obstacles. In previous researches, several carboxylate esters of OXY were synthesized and oxyresveratrol tetraacetate (OXY-TAc) was reported to possess anti-melanogenic and anti-skin-aging properties. In this study, in addition to OXY-TAc, two novel ester prodrugs of OXY, oxyresveratrol tetrapropionate (OXY-TPr), and oxyresveratrol tetrabutyrate (OXY-TBu), were synthesized. Results from the Caco-2-permeation assay suggested that synthesized ester prodrugs can improve the membrane-permeation ability of OXY. The OXY-TAc exhibited the most significant profile, then this prodrug was chosen to observe anti-inflammatory activities with lipopolysaccharide (LPS)-stimulated RAW264.7 macrophages. Our results showed that OXY-Tac significantly alleviated secretion of several pro-inflammatory mediators (nitric oxide (NO), interleukin-6 (IL-6), and tumor necrosis factor-alpha (TNF-α)), mitigated expression of enzyme-regulated inflammation (inducible nitric oxide synthase (iNOS) and cyclooxygenase-2 (COX-2)), and suppressed the MAPK cascades. Interestingly, the observed anti-inflammatory activities of OXY-TAc were more remarkable than those of its parent compound OXY. Taken together, we demonstrated that OXY-TAc improved physicochemical and pharmacokinetic profiles and enhanced the pharmacological effects of OXY. Hence, the results in the present study would strongly support the clinical utilities of OXY-TAc for the treatment of inflammation-related disorders. 相似文献
6.
Traiphol N Rungruangviriya N Potai R Traiphol R 《Journal of colloid and interface science》2011,363(2):481-489
The influence of pH value on gold nanoparticle production in the presence of Pluronic stabilizers is systematically investigated. The reactions are studied as a function of pH and at fixed concentrations of the two reactants, HAuCl(4) and P123 block copolymer. Results indicate that the reaction pathway during the nanoparticle formation can be controlled by varying pH. The nanoparticles synthesized at pH=11.12 have an average diameter of 9.6 nm with a narrow size distribution, and the Pluronics are adsorbed on individual gold particle surfaces to form core-shell structures via hydrophobic interactions. The present work provides an economic way to improve the dispersion and stabilization of gold nanoparticles and throws further light on the understanding of gold nanoparticle production using block copolymers. 相似文献
7.
A mathematical model is used to simulate the water current and the elevation in a uniform reservoir. A non-linear hydrodynamic model that provides the velocity field and elevation of the water flow is considered. In the simulating process, the Lax–Wendroff technique is used to approximate the solutions. The numerical solution can be the input data for a water-quality model that is applicable for the optimal control of water treatment in the system to achieve minimum cost. 相似文献
8.
Mathematical models of water quality assessment problems often arise in environmental science. The modelling often involves numerical methods to solve the equations. In this research, two mathematical models are used to simulate pollution due to sewage effluent in the nonuniform flow of water in a stream with varied current velocity. The first is a hydrodynamic model that provides the velocity field and elevation of the water flow. The second is a dispersion model, where the commonly used governing factor is the one-dimensional advection–dispersion–reaction equation that gives the pollutant concentration fields. In the simulation processes, we used the Crank–Nicolson method system of a hydrodynamic model and the backward time central space scheme for the dispersion model. Finally, we present a numerical simulation that confirms the results of the techniques. 相似文献
9.
Conversion enhancement of tubular fixed-bed reactor for Fischer-Tropsch synthesis using static mixer
Phavanee Narataruksa Sabaithip Tungkamani Karn Pana-Suppamassadu Phongsak Keeratiwintakorn Siriluck Nivitchanyong Piyapong Hunpinyo Hussanai Sukkathanyawat Prayut Jiamrittiwong Visarut Nopparat 《天然气化学杂志》2012,(4):435-444
Recently,Fischer-Tropsch synthesis(FTS) has become an interesting technology because of its potential role in producing biofuels via Biomassto-Liquids(BTL) processes.In Fischer-Tropsch(FT) section,biomass-derived syngas,mainly composed of a mixture of carbon monoxide(CO) and hydrogen(H2),is converted into various forms of hydrocarbon products over a catalyst at specified temperature and pressure.Fixed-bed reactors are typically used for these processes as conventional FT reactors.The fixed-bed or packed-bed type reactor has its drawbacks,which are heat transfer limitation,i.e.a hot spot problem involved highly exothermic characteristics of FT reaction,and mass transfer limitation due to the condensation of liquid hydrocarbon products occurred on catalyst surface.This work is initiated to develop a new chemical reactor design in which a better distribution of gaseous reactants and hydrocarbon products could be achieved,and led to higher throughput and conversion.The main goal of the research is the enhancement of a fixed-bed reactor,focusing on the application of KenicsTM static mixer insertion in the tubular packed-bed reactor.Two FTS experiments were carried out using two reactors i.e.,with and without static mixer insertion within catalytic beds.The modeled syngas used was a mixed gas composed of H2/CO in 2:1 molar ratio that was fed at the rate of 30mL(STP)min1(GHSV≈136mL g1 cat h1) into the fixed Ru supported aluminum catalyst bed of weight 13.3g.The reaction was carried out at 180℃ and atmospheric pressure continuously for 36h for both experiments.Both transient and steady-state conversions(in terms of time on stream) were reported.The results revealed that the steady-state CO conversion for the case using the static mixer was approximately 3.5 times higher than that of the case without static mixer.In both cases,the values of chain growth probability of hydrocarbon products(α) for Fischer-Tropsch synthesis were 0.92 and 0.89 for the case with and without static mixer,respectively. 相似文献
10.
Fazle Mabood Giulio Lorenzini Nopparat Pochai Sheikh Muhammad Ibrahim 《Continuum Mechanics and Thermodynamics》2016,28(6):1925-1932
A numerical treatment for axisymmetric flow and heat transfer due to a stretching cylinder under the influence of a uniform magnetic field and prescribed surface heat flux is presented. Numerical results are obtained for dimensionless velocity, temperature, skin friction coefficient and Nusselt number for several values of the suction/injection, magnetic and curvature parameters as well as the Prandtl number. The present study reveals that the controlling parameters have strong effects on the physical quantities of interest. It is seen that the magnetic field enhances the dimensionless temperature inside the thermal boundary layer, whereas it reduces the dimensionless velocity inside the hydrodynamic boundary layer. Heat transfer rate reduces, while the skin friction coefficient increases with magnetic field. 相似文献