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1.
Novel mixed valence states have been obtained by the treatment of cobaltous ferrocyanides (Co+2FeII) and ferricyanides (Co+2FeIII) in an ozone flow. The CN stretching bands occur at 2085 cm–1 for Co+2FeII and at 2160 cm–1 for Co+2FeIII. After the ozonization process of Co+2FeII, an intense band approximately at 2125 cm–1 is detected. This intermediate band must correspond to a mixed valence state of the type: FeII–CN–Co2+–NC–FeIII Mössbauer spectra recorded in situ during the ozonization of Co+2FeII show the presence of two components: a doublet with isomer shift and quadrupole splitting values close to the cobalti ferricyanide and a very broad line for the mixed valence state. From the Mössbauer and infrared spectra of the aged samples of the Co+2FeII after ozonization, a relaxation process to the initial state of the samples is observed but the mixed valence state is stable. 相似文献
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K. Masenelli‐Varlot E. Reynaud G. Vigier J. Varlet 《Journal of Polymer Science.Polymer Physics》2002,40(3):272-283
Intercalated and exfoliated nanocomposites were prepared by extrusion and injection of polyamide‐6 and highly swollen or slightly swollen montmorillonite, respectively. The microstructure of the nanocomposites has been studied previously. In this article, we investigated the influence of the preferential orientation of the montmorillonite sheets on the mechanical properties of the nanocomposites. Dynamic mechanical analysis and tensile tests showed that the elastic modulus depends mainly on the filler loading. A parallel coupling could well account for the behavior of the nanocomposites. The calculated elastic and storage moduli of montmorillonite were set to 140 and 40 GPa, respectively. Compression tests were performed to study the anisotropy of the mechanical properties. The elastic modulus and flow strain were sensitive to the filler orientation. A Tandon–Weng approach was applied to consider the geometry of the filler. In all low‐deformation tests, no significant difference between intercalated and exfoliated systems was observed. Finally, the influence of the dispersion and exfoliation state of the filler on the ultimate properties of the nanocomposites (tensile tests) is discussed. © 2001 John Wiley & Sons, Inc. J Polym Sci Part B: Polym Phys 40: 272–283, 2002 相似文献
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G. Vigier J. Tatibouet A. Benatmane R. Vassoille 《Colloid and polymer science》1992,270(12):1182-1187
Crystallization of poly(ethylene terephthalate) from the amorphous state has been studied in the temperature range 90°–120°C to characterize the amorphous phase when crystalline microstructure is developing. Small-angle x-ray scattering, scanning electron microscopy, and density measurements were used to investigate the morphology of semi-crystalline materials. Differential scanning calorimetry and dynamical mechanical spectroscopy experiments were carried out on amorphous, partially crystallized and crystallized specimens and, when structural relaxation is allowed (thermal treatments close to but below glass transition temperature), strong evidence is obtained for the existence of two different amorphous phases with different mobilities. 相似文献
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van den Brand JF Ent R Anthony PL Arnold RG Arrington J Beise EJ Belz JE Bosted PE Bulten H Chapman MS Coulter KP Dietrich FS Epstein M Filippone BW Gao H Gearhart RA Geesaman DF Hansen J Holt RJ Jackson HE Jones CE Keppel CE Kinney ER Kuhn S Lee K Lorenzon W Lung A Makins NC Margaziotis DJ McKeown RD Milner RG Mueller B Napolitano J Nelson J O'Neill TG Papavassiliou V Petratos GG Potterveld DH Rock SE Spengos M Szalata ZM Tao LH van Bibber K Wasson DA White JL Zeidman B 《Physical review D: Particles and fields》1995,52(9):4868-4871
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Makins NC Ent R Chapman MS Hansen J Lee K Milner RG Nelson J Arnold RG Bosted PE Keppel CE Lung A Rock SE Spengos M Szalata ZM Tao LH White JL Coulter KP Geesaman DF Holt RJ Jackson HE Papavassiliou V Potterveld DH Zeidman B Arrington J Beise EJ Belz E Filippone BW Gao H Lorenzon W Mueller B McKeown RD O'Neill TG Epstein M Margaziotis DJ Napolitano J Kinney E Anthony PL van Bibber K Dietrich FS Gearhart RA Patratos GG Kuhn SE van den Brand JF Bulten H Jones CE 《Physical review letters》1994,72(13):1986-1989
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The introduction by Dirac of a new aether model based on a stochastic covariant distribution of subquantum motions (corresponding to a vacuum state alive with fluctuations and randomness) is discussed with respect to the present experimental and theoretical discussion of nonlocality in EPR situations. It is shown (1) that one can deduce the de Broglie waves as real collective Markov processes on the top of Dirac's aether; (2) that the quantum potential associated with this aether's modification, by the presence of EPR photon pairs, yields a relativistic causal action at a distance which interprets the superluminal correlations recently established by Aspect et al.; (3) that the existence of the Einstein-de Broglie photon model (deduced from Dirac's aether) implies experimental predictions which conflict with the Copenhagen interpretation in certain specific testable interference experiments. 相似文献
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