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1.
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Image potential resonances on the Sn/Ge(1 1 1) α-phase are investigated by two closely related methods: specular electron reflection and so-called selective electron scattering. Electrons from image resonances are detected on this surface at 120 and 300 K, i.e. below and above the phase transition at about 200 K. The dispersion of the image resonances reveals at these two temperatures equivalent effective electron masses, which are characteristic for this type of electronic surface states. The results of the two methods are consistent according to the similarity of the scattering processes. Changes in the loss peak intensity with the annealing temperature are assigned to the surface quality and are reflected by characteristic photoemission intensities. 相似文献
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4.
Wolfgang?Gutleben Verena?Unterholzner Dietmar?Volgger Andreas?ZemannEmail author 《Mikrochimica acta》2004,146(2):111-117
In the course of this investigation, a method for the characterization and differentiation of paper pulps was developed. After hydrolyzation of the papers and the respective raw pulps with trifluoroacetic acid, the hydrolyzates were analyzed with respect to their carbohydrate composition using ion exchange chromatography. The variations in carbohydrate composition mainly arise from the various hemicelluloses of the papers and pulps. The chromatographic results were then further processed using principal component analysis which allows correlating the various papers to different pulp materials. 相似文献
5.
The CD. spectra of carotenoids in the 220-500 nm region may by inspection be classified as (a) essentially Conservative, (b) intermediate, or (c) essentially nonconservative. A conservative spectrum shows in that spectral region a sequence of 5-6 relatively sharp Cotton effects of alternating sign, the rotatory strengths of which roughly add to zero. In a non-conservative spectrum Δ? has the same sign over the whole region and its absolute value is in general somewhat smaller. In general, typical conservative spectra invert upon isomerization of the molecule from all-trans to mono-cis. Non-conservative spectra do not invert. The model of a chiral polyene of the length of the conjugated carotene chromophore reproduces well the main features of the conservative spectra. The theoretical predictions and the experimental data are shown to conform to the C2-rule [43] [44]. The particular nature of the longest-wavelength transition is interpreted. Based on a summary of the chiroptic data on about 50 naturally occurring compounds, the question is discussed of when conservative spectra arise and when not. 相似文献
6.
A method (laser raster microscopy with thermal excitation, LRMTE) for characterizing high-T
c thin-film superconductors (HTSC) with microscopic resolution is described. By means of spatially resolved laser excitation and subsequent monitoring of the time dependence of the film resistivity at a base temperature near the transition temperature T
c, spatial variations of the transition temperature (T
c), of the temperature coefficient of the resistivity (dQ/dT), of the heat conductivity and heat capacity of the film and of the heat conductivity between film and substrate can be detected with high spatial resolution (15 m have been achieved so far). 相似文献
7.
The following review describes the development of mass spectrometry off-line and on-line coupled with liquid chromatography to the analysis of food proteins. It includes the significant results recently obtained in the field of milk, egg and cereal proteins. This paper also outlines the research carried out in the area of food protein hydrolysates, which are important components in foodstuffs due to their functional properties. Liquid chromatography and mass spectrometry have been particularly used for the characterization of food peptides and especially in dairy products. 相似文献
8.
Colourless single crystals of the caffeine adduct of mercurous perchlorate dihydrate, [Hg2(Caf)2](ClO4)2(H2O)2, were grown from aqueous solutions of mercurous perchlorate and caffeine by isothermal evaporation at ambient temperature. The crystal structure (monoclinic, P21/n, Z = 4, a = 1628.0(2), b = 780.4(1), c = 2229.6(3) pm, β = 99.84(1)°, R1(all data) = 0.0894) contains [trans‐Caf‐Hg‐Hg‐Caf]2+ cations with a Hg‐Hg distance of 250.88(6) pm, Hg‐N (bond) distances of 214.4(6) and 215.1(6) pm and Hg‐Hg‐N angles of 176.9(2) and 165.1(2)°, respectively. These cations are attached via weak Hg‐O contacts to dimers which are further arranged to leave large channels into which one crystal water molecule is included. The second water molecule and the two perchlorate anions are weakly attracted to one Hg atom. 相似文献
9.
Braun T Steffen A Schorlemer V Neumann B Stammler HG 《Dalton transactions (Cambridge, England : 2003)》2005,(20):3331-3336
Treatment of a toluene solution of [PdMe(2)(Cy(2)PCH(2)PCy(2))](1) with pentafluoropyridine in the presence of traces of water affords the generation of the A-frame complexes [(PdMe)(2){mu-kappa(2)(P,P)Cy(2)PCH(2)PCy(2)}(2)(mu-F)][SiMeF(4)]() and [(PdMe)(2){mu-kappa(2)(P,P)Cy(2)PCH(2)PCy(2)}(2)(mu-F)][OC(5)NF(4)](2b). If the reaction is performed in an NMR tube equipped with a PFA inliner, complex 2b is produced, only. Treatment of 1 with pentafluoropyridine in the presence of an excess water yields the pyridyloxy complex [PdMe(OC(5)NF(4))(Cy(2)PCH(2)PCy(2))](3). Compound [(PdMe)(2){mu-kappa(2)(P,P)Cy(2)PCH(2)PCy(2)}(2)(mu-F)][FHF](2c) bearing a bifluoride anion instead of SiMeF(4)(-) or OC(5)NF(4)(-) can be generated by reaction of 1 with substoichiometric amounts of Et(3)N.3HF. The analogous complex [(PdMe)(2){mu-kappa(2)(P,P)Ph(2)PCH(2)PPh(2)}(2)(mu-F)][FHF] (5c) has been synthesized by addition of Ph(2)PCH(2)PPh(2) to a solution of [PdMe(2)(Me(2)NCH(2)CH(2)NMe(2))](4) in THF and subsequent treatment of the reaction mixture with Et(3)N.3HF. The structure of the A-frame complex 5c has been determined by X-ray crystallography. 相似文献
10.
The carborane–siloxane copolymers Dexsil 300, a 34.5% bis(dimethylsilyl)-m-carborane–65.5% dimethylsiloxane copolymer, and Dexsil 400, a 24.9% bis(dimethylsilyl)-m-carborane–50.8% dimethyl, 24.3% methylphenylsiloxane copolymer, were coated on fused silica capillary columns and their gas
chromatographic properties were evaluated. Their selectivity was evaluated using both Rohrschneider–McReynolds constants and
triacylglycerol indices. The bis(dimethylsilyl)-m-carborane unit turned out to be equivalent to two dimethylsiloxy units and one half of a diphenylsiloxy unit. The m-carborane unit was found to cause a 15–25 K shift in the elution temperature between 120 and 360 °C. The working range was
from 20 and 0 °C to 380 °C for Dexsil 300 and Dexsil 400, respectively. The column bleeding levels at 380 °C were below 20
and 15 pA for Dexsil 300 and Dexsil 400, respectively. 相似文献