Sulfamic Acid–Catalyzed One‐Pot Synthesis of 3‐(4,6‐Dimethyl‐oxazolo[4,5‐c]quinolin‐2‐yl)‐chromen‐2‐ones using the Conventional Method and Microwave Irradiation

A rapid and efficient method for the preparation of 3‐(4,6‐dimethyl‐oxazolo[4,5‐c]quinolin‐2‐yl)‐chromen‐2‐ones by the reaction between 3‐amino‐2,8‐dimethyl‐quinolin‐4‐ol and 2‐oxo‐2H‐chromen‐3‐carboxylic acid using sulfamic acid as a acid catalyst and dimethyl formamide as a solvent using the conventional method and microwave irradiation is reported.     

Phase stability of terawatt-class ultrabroadband parametric amplification

The phase stability of broadband (280 nm bandwidth) terawatt-class parametric amplification was measured, for the first time to our knowledge, with a combination of spatial and spectral interferometry. Measurements at four different wavelengths from 750 to 900 nm were performed in combination with numerical modeling. The phase stability is better than 1/23 rms of an optical cycle for all the measured wavelengths, depending on the phase-matching conditions in the amplifier.     

Synthesis,antioxidant activity,and α-glucosidase enzyme inhibition of α-aminophosphonate derivatives bearing piperazine-1,2,3-triazole moiety

A novel series of piperazine-1,2,3-triazole bearing dimethyl(((2-(4-((1H-1,2,3-triazole-4-yl)methyl)piperazin-1-yl)ethylamino)(2-hydroxyaryl)methyl)phosphonate derivatives have been prepared via copper-catalyzed azide-alkyne 1,3-dipolar cycloaddition (CuAAC) (Click Reaction) and Schiff base reactions. The synthesized compounds were confirmed by spectral characterization (¹H, ¹³C and ³¹P NMR, and mass). The title compounds were evaluated for in vitro alpha glucosidase enzyme inhibition and in vitro antioxidant activity using DPPH and H₂O₂ methods.     

Proton transfer and N(+)-H...S(-) hydrogen bonds in the crystal structure of 4-aminothiophenol

4-Aminothiophenol exists as 4-ammonio-1-benzenethiolate in the solid and liquid state. The crystal structure is characterised by a tetrahedral beta-As type network which is the driving force for the proton transfer.     

An ab initio study of ground state, electronic and thermodynamical properties of GaP and Ga2P

In the present paper, we report an ab initio calculation of the ground state, electronic and thermodynamical properties like constant volume lattice specific heat, vibrational energy, internal energy, and entropy for GaP and Ga₂P is presented. These properties are obtained after calculating the phonon spectrum over the entire Brillouin zone. The calculations were performed using the ABINIT program package, which is based on density functional theory (DFT) method and the use of pseudopotentials and plane wave expansion. Difference in the ground state properties such as electronic structure and thermodynamical properties are discussed. The thermodynamical properties follow the expected trend. There is a good agreement between present theoretical and limited available experimental data in the case of ground state such as lattice constant and bulk modulus and electronic properties. With the increase of Ga atoms in the unit cell the semiconducting nature of Ga₂P turns to metallic. There is a noticeable difference in the thermodynamical properties in the case of both gallium compounds.     

Preparation and characterization of aromatic copolyesters containing the o,o′-biphenylene ring system

Poly[oxy-2,2′-diphenyleneoxyisophthaloyl-b-oxy(2-methyl-1,3-phenylene)oxyterephthaloyl] I, poly[oxy-2,2′-diphenyleneoxyterephthaloyl-b-oxy(2-methyl-1,3-phenylene)oxyterephthaloyl] II, poly(oxy-2,2′-diphenyleneoxyisophthaloyl-b-oxy-2,2′-diphenyleneoxyterephthaloyl) III, poly[oxy-2,2′-diphenyleneoxyterephthaloyl-b-oxy(2-methyl-1,4-phenylene)oxyterephthaloyl] IV, poly[oxy2,2′-diphenyleneoxyterephthaloyl-b-oxy(2-chloro-1,4-phenylene)oxyterephthaloyl] V, poly[oxy-2,2′-diphenyleneoxyterephthaloyl-co-oxy(2-chloro-1,4-phenylene)oxyterephthaloyl] VI, and poly[oxy-2,2′-diphenyleneoxyterephthaloyl-co-oxy(2-methyl-1,4-phenylene)oxyterephthaloyl] VII have been synthesized and characterized. Random copolyester VI appears to form a birefringent fluid phase above the melting temperature.