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1.
B. Harihara Venkataraman 《Journal of Physics and Chemistry of Solids》2003,64(11):2105-2112
This paper reports the dielectric and impedance characteristics of ferroelectric SrBi2Nb2O9 (SBN) ceramics in the 100 Hz-1 MHz frequency range at various temperatures (300-823 K). A strong low frequency dielectric dispersion (LFDD) associated with an impedance relaxation has been found to exist in these ceramics in the temperature range 573-823 K. The Z″ of the AC complex impedance showed two distinct slopes in the frequency range 100 Hz-1 MHz suggesting the existence of two dispersion mechanisms. This non-ideal behavior has been explained on the basis of the expression, Z*=R0/(1+(iω/ω1)m+(iω/ω2)n) [J. Phys. Chem. Solids 53 (1992) 1] where ω1 and ω2 characterize the lattice response and the charge carrier behavior, respectively. The exponents m and n were obtained from the curve fitting. The exponent n was found to exhibit a minimum at the Curie temperature, Tc (723 K) whereas the m was temperature independent. 相似文献
2.
On the departure process of a leaky bucket system with long-range dependent input traffic 总被引:2,自引:0,他引:2
Due to the strong experimental evidence that the traffic to be offered to future broadband networks will display long-range
dependence, it is important to study the possible implications that such traffic may have for the design and performance of
these networks. In particular, an important question is whether the offered traffic preserves its long-range dependent nature
after passing through a policing mechanism at the interface of the network. One of the proposed solutions for flow control
in the context of the emerging ATM standard is the so-called leaky bucket scheme. In this paper we consider a leaky bucket
system with long-range dependent input traffic. We adopt the following popular model for long-range dependent traffic: Time
is discrete. At each unit time a random number of sessions is initiated, having the distribution of a Poisson random variable
with mean λ. Each of these sessions has a random duration τ, where the integer random variable τ has finite mean, infinite
variance, and a regularly varying tail, i.e., P(τ >К) ~ К-Lα
L(К), where 1 < α < 2 L(·) is a slowly varying function. Once a session is initiated, it generates one cell at each unit of time until its termination.
We examine the departure process of the leaky bucket policing mechanism driven by such an arrival process, and show that it
too is long-range dependent for any token buffer size and any - finite or infinite - cell buffer size. Moreover, upper and
lower bounds for the covariance sequence of the output process are established. The above results demonstrate that long-range
dependence cannot be removed by the kinds of flow control schemes that are currently being envisioned for broadband networks.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
3.
P.Veeraraghavan Ramachandran Kamlesh J Padiya Vivek Rauniyar M.Venkat Ram Reddy Herbert C Brown 《Journal of fluorine chemistry》2004,125(4):615-620
Asymmetric “allyl”boration of pentafluorobenzaldehyde with various α-pinene based “allyl”boranes provides homoallylic alcohols in high de and ee; the alcohols have been converted into δ-lactones via acryloylation, ring-closing metathesis and hydrogenation. Pentafluorophenyl analog of key pharmacophore of statin drugs has been synthesized using diastereoselective epoxidation and regioselective reduction as key steps. 相似文献
4.
R. Venkat narayan Vinod Kanniah Aruna Dhathathreyan 《Journal of Chemical Sciences》2006,118(2):179-184
Cobalt oxides were prepared by three different methods: (1) by reacting cobalt nitrate with oxalic acid, (2) co-precipitating
cobalt nitrate with sodium carbonate, and (3) using sodium dodecyl sulphate as organic surfactant. All three samples were
characterized before and after calcination by solvent extraction and the resulting products examined by IR spectroscopy. In
the case of method 3, the removal of surfactant was followed by TGA studies. Products from all three methods were identified
by XRD. Peaks in low angle XRD indicate the porous nature of the oxides. The morphology of the pores was studied by transmission
electron microscopy. Some irregular pore structures were obtained for samples from methods 1 and 2, with an average size of
4–6 nm. Only the product from method 3 using SDS as template showed ordered structure and optimum size, and Brunauer-Emmet-Teller
surface areas of the as-prepared, as well as the treated samples, exhibited H3 type hysteresis. The samples from the three
methods were used as catalysts in the oxidation reaction of cyclohexane under mild conditions and the catalytic efficiency
of the cobalt oxide was comparable with mesoporous cobalt oxides. 相似文献
5.
Adsorption of Pb2+ ions on the combustion derived nanosized γ-Fe2O3 and its thiourea complex composite is reported. The adsorbents upon adsorption of Pb2+ ions are characterised by X-ray diffraction, scanning electron microscopy, energy dispersive X-ray microanalysis and infrared spectroscopy techniques. The eluent is characterised by atomic absorption spectroscopy for the estimation of Pb2+ ions. The reduction in the amount of lead after adsorption was estimated to be around 50% in case of complex composite adsorbent and around 15% in case of the γ-Fe2O3 adsorbents. Orthorhombic PbSO4 precipitated out from the eluent and is reported with a model reaction. Adsorption of lead onto the complex composite is explained through the formation of a surface tertiary complex. The advantage of employing a thiourea-γ-Fe2O3 complex composite as solid adsorbent for the adsorption of heavy metal pollutants is envisaged in the present investigation. 相似文献
6.
A. Venkataraman 《Journal of Thermal Analysis and Calorimetry》1996,46(1):219-224
Thermal techniques viz., TG/DTA/DSC methods have been employed in understanding the formation and decomposition of hydrogen ferrite phase (H-F) as a metastable intermediate in the conversion of -Fe2O3·xH2O, to -Fe2O3. Magnetic hysteresis measurements carried out at liquid N2 and at room temperature for the vacancy ordered -Fe2O3 and its H-F phase also supplement these studies.The author thanks prof. M.R. Udpa, IIT, Madras for supplying TG/DTA data on Stanton Redcroft Instrument and to the Head, Department of Chemistry, S.P. University, Vallabh Vidyanagar for providing the facilities. 相似文献
7.
De Jonghe S Lamote I Venkataraman K Boldin SA Hillaert U Rozenski J Hendrix C Busson R De Keukeleire D Van Calenbergh S Futerman AH Herdewijn P 《The Journal of organic chemistry》2002,67(3):988-996
The synthesis of a new series of D-erythro-homoceramide analogues is described. Several synthetic approaches were investigated. Homoceramides can be successfully synthesized from L-homoserine as chiral building block and a protected Weinreb-amide as a key intermediate. The synthesis of short-chain analogues with a heptyl side chain, as well as with a phenyl residue in the sphingoid part (instead of the naturally occurring tridecyl side chain), was effected. The homoceramides 15-17 and 24 were investigated for their potential to reverse the inhibitory effect of fumonisin B(1) on axonal growth. Unfortunately, none of the tested compounds showed any biological activity due to their lack of metabolism to glucosylhomoceramide. 相似文献
8.
1:2-Benzanthracene and the 3′-methyl derivative have been prepared by Raney nickel reduction of the sulphuric esters of the leuco derivatives of 1:2-benzanthraquinone and 4′-chloro-3′-methyl-1:2-benzanthraquinone, followed by dehydrogenation. 3-Hydroxy-1:2-benzanthraquinone was methylated in the 4-position by formaldehyde, sodium hydrosulphite and sodium hydroxide solution (the Marschalk reaction). Simultaneous reduction of the nuclear hydroxyl and quinone groups was effected by Raney nickel reduction of the trisulphuric ester of 3:9:10-trihydroxy-4-methyl-1:2-benzanthracene, and the resultant hexahydro-4-methyl-1:2-benzanthracene was dehydrogenated to 4-methyl-1:2-benzanthracene. The preparation of 3:4:9:10-dibenzopyrene from Mayvat brilliant red AF by Raney nickel reduction of the sulphuric ester of the leuco derivative and subsequent dehydrogenation is described. 相似文献
9.
[reaction: see text] Chiral beta-syn-alkoxyhomoallylic alcohols derived from alkoxyallylboration of aldehydes upon oxidation provided the corresponding chiral ketones. Chelation-controlled nucleophilic addition to these ketones occurred in a highly stereoselective manner to afford anti-homoallylic tertiary alcohols. This methodology has been applied for the synthesis of the C(1)-C(11) subunit of C(8)-epi-fostriecin. 相似文献
10.
A very simple and highly specific method for the determination of cysteine and penicillamine is presented. Treatment with 1,1'-thiocarbonyldiimidazole in slightly basic solutions converts cysteine rapidly and quantitatively to a very stable derivative, 2-thioxothiazolidine-4-carboxylic acid, which is not formed by thiols or amines. The cyclic derivative has a characteristic UV spectrum with a maximum at 272 nm and it can be quantified by one of two ways. (1) When only inorganic ions and common additives are present, a spectrophotometer or a plate reader capable of handling multiple samples is sufficient to estimate cysteine in the concentration range of 2-150 muM. Penicillamine is determined similarly by cyclization to 5,5-dimethyl-2-thioxothiazolidine-4-carboxylic acid. The method is also applicable to derivatives of cysteine modified only at the carboxyl group. (2) To determine cysteine in complex mixtures, a liquid chromatograph connected to a UV detector is used. The elution is rapid with well-separated peaks for the thiazolidine derivatives. The detection limit is 2 pmole of cysteine or penicillamine per injection and the detector response is linear up to 1 nmole. The usefulness of the method is demonstrated by determining cysteine and penicillamine in capsules and by measuring cysteine in a dietary supplement. 相似文献