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1.
Miloš Dubajić Aleksandar Daničić Nikola Vuković Vitomir Milanović Jelena Radovanović 《Optical and Quantum Electronics》2018,50(10):373
In this work we theoretically investigate a possibility to use cubic nitride based multi-layer periodic nanostructure as a semiconductor metamaterial. The structure design is based on an active region of a quantum cascade laser optimized to achieve optical gain in the Terahertz (THz) spectral range. In particular, we test the GaN/AlGaN quantum well configurations, which should exhibit important advantages compared to GaAs-based structures, namely room temperature operation without the assistance of magnetic field and lower doping densities. Our numerical rate-equations model is solved self-consistently and it takes into account electron-longitudinal optical phonon scattering between all the relevant states among the adjacent periods of the structure. A global optimization routine, specifically genetic algorithm is then used to generate new gain-optimized structures. This work confirms the advantages of cubic GaN designs over GaAs ones, namely feasibility of negative refraction at room temperature without the assistance of magnetic field while keeping the doping densities of the same order of magnitude. 相似文献
2.
Ana T. Simonović Marija B. Petrović Milan B. Radovanović Snežana M. Milić Milan M. Antonijević 《Chemical Papers》2014,68(3):362-371
This investigation aimed to study a “green” non-toxic biodegradable copper corrosion inhibitor in an acidic sodium sulphate solution. The methods used in the investigation of cysteine as a copper corrosion inhibitor in an acidic sodium sulphate solution were: potentiodynamic measurements, open circuit potential measurements, and chronoamperometric measurements. Optical microscopy was used in addition to electrochemical methods. Potentiodynamic measurements show that cysteine has good inhibitory properties in an acidic medium. Polarisation curves indicate that the presence of cysteine in a sulphate solution decreases the current density and that using various cysteine concentrations results in the formation of a protective film on the surface of the electrode due to the formation of the Cu(I)-cys complex. These results are confirmed by chronoamperometric measurements. Furthermore, it is clear from microphotographs that a protective film does form on copper electrode in the presence of cysteine. The Langmuir adsorption isotherm indicates that cysteine is chemisorbed on the surface of the electrode. 相似文献
3.
Pierre Aboulker Marko Radovanović Nicolas Trotignon Théophile Trunck Kristina Vušković 《Journal of Graph Theory》2014,75(2):150-166
In Math Program 55(1992), 129–168, Conforti and Rao conjectured that every balanced bipartite graph contains an edge that is not the unique chord of a cycle. We prove this conjecture for balanced bipartite graphs that do not contain a cycle of length 4 (also known as linear balanced bipartite graphs), and for balanced bipartite graphs whose maximum degree is at most 3. We in fact obtain results for more general classes, namely linear balanceable and subcubic balanceable graphs. Additionally, we prove that cubic balanced graphs contain a pair of twins, a result that was conjectured by Morris, Spiga, and Webb in ( Discrete Math 310(2010), 3228–3235). 相似文献
4.
Azra ulovi Franko Bur
ul Vedrana ike uli Mirko Ru
i Petra Brzovi Sabine Montaut Patrick Rollin Ivica Blaevi 《Molecules (Basel, Switzerland)》2021,26(17)
Glucosinolates (GSLs) from Lepidium graminifolium L. were analyzed qualitatively and quantitatively by their desulfo-counterparts using UHPLC-DAD-MS/MS technique and by their volatile breakdown products-isothiocyanates (ITCs) using GC-MS analysis. Thirteen GSLs were identified with arylaliphatic as the major ones in the following order: 3-hydroxybenzyl GSL (glucolepigramin, 7), benzyl GSL (glucotropaeolin, 9), 3,4,5-trimethoxybenzyl GSL (11), 3-methoxybenzyl GSL (glucolimnanthin, 12), 4-hydroxy-3,5-dimethoxybenzyl GSL (3,5-dimethoxysinalbin, 8), 4-hydroxybenzyl GSL (glucosinalbin, 6), 3,4-dimethoxybenzyl GSL (10) and 2-phenylethyl GSL (gluconasturtiin, 13). GSL breakdown products obtained by hydrodistillation (HD) and CH2Cl2 extraction after hydrolysis by myrosinase for 24 h (EXT) as well as benzyl ITC were tested for their cytotoxic activity using MTT assay. Generally, EXT showed noticeable antiproliferative activity against human bladder cancer cell line UM-UC-3 and human glioblastoma cell line LN229, and can be considered as moderately active, while IC50 of benzyl ITC was 12.3 μg/mL, which can be considered as highly active. 相似文献
5.
In this comment, we show that the arguments against the applicability of stationary phase method (SPM) for tunneling time calculations, presented in Letter “Questions concerning the generalized Hartman effect” are not valid for small wave packet energy widths. 相似文献
6.
Ida Bo
ek Pavlinac Katarina Zlati Leentje Persoons Dirk Daelemans Mihajlo Banjanac Vedrana Radovanovi Kristina Butkovi Marijeta Kralj Marijana Hranjec 《Molecules (Basel, Switzerland)》2023,28(1)
A series of cyano- and amidino-substituted imidazo[4,5-b]pyridines were synthesized using standard methods of organic synthesis, and their biological activity was evaluated. Biological evaluation included in vitro assessment of antiproliferative effects on a diverse selection of human cancer cell lines, antibacterial activity against chosen Gram-positive and Gram-negative bacterial strains, and antiviral activity on a broad panel of DNA and RNA viruses. The most pronounced antiproliferative activity was observed for compound 10, which contained an unsubstituted amidino group, and compound 14, which contained a 2-imidazolinyl amidino group; both displayed selective and strong activity in sub-micromolar inhibitory concentration range against colon carcinoma (IC50 0.4 and 0.7 μM, respectively). All tested compounds lacked antibacterial activity, with the exception of compound 14, which showed moderate activity against E. coli (MIC 32 μM). Bromo-substituted derivative 7, which contained an unsubstituted phenyl ring (EC50 21 μM), and para-cyano-substituted derivative 17 (EC50 58 μM) showed selective but moderate activity against respiratory syncytial virus (RSV). 相似文献
7.
Patricia A. Aikens Qi Yin Vedrana Marin Zhiqiang Zhang 《Journal of Dispersion Science and Technology》2013,34(1-2):257-278
The vapor pressure data from previous publications of a model fragrance emulsion system consisting of water, an aromatic fragrance phenethyl alcohol, an aliphatic one limonene, and a nonionic surfactant Laureth 4, were used to calculate the variation in vapor pressures of both fragrances and water during free evaporation. The evaporation path in a three-dimensional four-component phase diagram was estimated from the vapor pressures. The results showed as expected that the high note fragrance compound evaporates first followed by water and the low note one. Unexpectedly, it was found that vapor pressure of low note fragrance, phenethyl alcohol, is significantly increased during evaporation. 相似文献
8.
In this paper, we study the class of graphs defined by excluding the following structures as induced subgraphs: theta, pyramid, 1-wheel, and 3-wheel. We describe the structure of graphs in , and we give a polynomial-time recognition algorithm for this class. We also prove that -free graphs in are 4-colorable. We remark that includes the class of chordal graphs, as well as the class of line graphs of triangle-free graphs. 相似文献
9.
Marković Gordana Marinović-Cincović Milena Vodnik Vesna Radovanović Blaga Budinski-Simendić Jaroslava Veljković Olivera 《Journal of Thermal Analysis and Calorimetry》2009,97(3):999-1006
The properties of chlorosulphonated polyethylene (CSM) rubber, acrylonitrile rubber (NBR) and their blend (50/50 w/w) were
studied. Fourier transform infrared (FTIR) studies supported that CSM/NBR rubber blend is self curable, when cross-linking
takes place between acrylonitrile groups of NBR and –SO2Cl groups or in situ generated allyl chloride moieties of CSM. The thermal stability of vulcanizates was analyzed in nitrogen
by thermogravimetry. It was found that the initial degradation temperature of elastomer based on CSM rubber is lower than
of pure NBR rubber. By adding NBR to CSM rubbers, the degradation temperature of crosslinked material increased, indicating
higher thermal stability. The activation energy for the degradation are determined using the Arrhenius equation The activation
energies for the rubber blends are higher than for elastomers based on pure rubbers. It was found that the mass loss of the
blends at any temperature was between those of the pure rubbers. The differential scanning calorimetry (DSC) was used for
the glass transition temperature determination. It is estimated thermodynamic immiscibility of NBR/CSM blend based on noticed
two different glass transition temperatures, corresponding to CSM and NBR rubbers. 相似文献
10.
S. S. Konstantinović B. C. Radovanović Z. B. Todorović S. B. Ilić B. V. Konstantinović 《Chemical Papers》2007,61(6):485-489
Metal complexes of some divalent metal ions (Co, Ni, Cu, Zn, Hg, and Pd) with isatin-β-thiosemicarbazone (ITS) as the Schiff base have been investigated potentiometrically and spectrophotometrically. The dissociation
constants of the ligand and formation constants of the metal complexes, as well as the corresponding thermodynamic functions
(ΔG, ΔH and ΔS) have been determined at different temperatures in ethanol—water solution. The full stability constants were also evaluated
spectrophotometrically by the Job method. The experimental results indicate that Cu(II), Zn(II), Pd(II), and Hg(II) form one-to-one
molecular complexes (ML) with the studied ligand, whereas Co(II) and Ni(II) form both ML and ML2 species. 相似文献