Rearrangement with oxide ion transfer in reactions of 4-chloro-2-oxo-2,3-dihydrothiazole-5-carbaldehyde with ureas. cis-(Z)-trans-(E) isomerism of N-(2,4-dioxothiazolidin-5-ylidenemethyl)ureas

4-Chloro-2-oxo-2,3-dihydrothiazole-5-carbaldehyde reacted with monosubstituted ureas to give cis-(Z)-and trans-(E)-N-(2,4-dioxothiazolidin-5-ylidenemethyl)ureas via rearrangement involving oxide ion transfer, cis (Z) Isomers were formed in methanol or dimethylformamide, while both individual cis (Z) and trans (E) isomers and their mixtures were isolated in the reaction performed in acetic acid.     

Exchange Processes in Pb(II) Complexes

A novel technique of 2D exchange NMR with suppression of the coherent magnetization transfer is suggested for the collection of useful chemical information on the basis of standard 2D exchange spectroscopy. In this technique, only one nucleus of the coupled spin system involved in chemical exchange is excited (so-called multiplet selectivity or semiselective excitation). In this case, the multiplet structure of the selectively irradiated nucleus behaves as an uncoupled multisite system.     

Effect of Temperature on the Electrorheological Behavior of Porous Chitosan Particles in Polydimethylsiloxane

Doklady Physical Chemistry - The rheological behavior of a 1 wt % suspension of highly porous chitosan particles in polydimethylsiloxane in a high electric field has been studied as a function of...     

Nonstandard magnetic oscillations in the Nambu-Jona-Lasinio model

The Nambu-Jona-Lasinio model at nonzero values of an external magnetic field H and of the chemical potential is considered in the strong-coupling region G>G _c. The phase portrait of the model exhibits an infinitely large number of massless chiral-invariant phases and massive phases resulting from a spontaneous breakdown of chiral invariance. This phase structure is responsible for aperiodic oscillations of some thermodynamic parameters of the system, including the dynamical fermion mass, as functions of H ^?1.     

Quantitative Analysis of Spectral Effects due to the Z/E Conformational Equilibria in Derivatives of the Amides and Hydrazides of Dicarboxylic Acids

The contributions from anisotropic magnetic screening and electronic effects to the relative chemical shifts of the NH protons in the amides and N,N-dimethylhydrazides of succinic and glutaric acids were calculated. It was shown that the splitting of the signals of the NH protons is largely determined by the redistribution of electron density in the molecule during the conformational transition.     

Dispersion properties and field structures of eigenmodes of nonuniform plasma waveguides in a longitudinal magnetic field

We study the field structure and dispersion properties of a hybrid eigenmode guided by a nonuniform magnetized plasma waveguide. It is shown that the rotational and quasi-potential waves contribute to the formation of such a mode in the whistler frequency range. Depending on the plasma density, the rotational component of the hybrid mode is determined by either waves with complex transverse wave numbers or whistler waves, or by true surface waves. In the presence of an axial nonuniformity of the plasma in a channel, the transverse field structure of the propagating mode changes, which is stipulated by changes in both the values of transverse wave numbers and their dependence on the radial coordinate. It is found that the spectrum of axial wave numbers of eigenmodes of a plasma waveguide undergoes a pronounced condensation when smoothing the waveguide walls. The damping of the hybrid mode of a nonuniform waveguide due to electron collisions is found and it is shown that collisional losses determine the damping of waves trapped in the waveguide in the experiments on ionization self-channeling of whistler waves. We have found the effect of “displacing” the strong field from the inner core to the background outer region of the waveguide with increasing plasma density on its axis and broadening background region. __________ Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 49, No. 7, pp. 607–617, July 2006.     

Synthesis and spectroscopic characteristics of σ-vinyl derivatives of platinum(<Emphasis Type="SmallCaps">IV</Emphasis>) chloride complexes

A procedure was developed for the synthesis of previously unknown β-chlorovinyl derivatives of Pt^IV chloride complexes by chloroplatination of terminal alkynes catalyzed by Pt^II chloride complexes. The reaction is highly stereoselective and gives only the products of trans-anti-addition of platinum and chlorine atoms. The regioselectivity of the catalytic reaction formally corresponds to Markovnikov’s rule, e.g., in alkynes containing electron-donating substituents, platinum attacks the terminal carbon atom. The σ-vinyl derivatives of Pt^IV chloride complexes were characterized by IR spectroscopy and ¹H and ¹³C NMR spectroscopy. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2380–2384, October, 2005.