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Experimental data on the equilibria Fe2+/Fe3+ and SO3 2−/SO4 2− in the system Fe(OH)3(H2SO4)-Na2SO3-H2O are presented. The quantitative relations between the reduction of Fe(III) and the precipitation of FeSO3·2.5H2O as a Fe2O3 precursor have considered graphically.__________Translated from Zhurnal Prikladnoi Khimii, Vol. 78, No. 1, 2005, pp. 41–44.Original Russian Text Copyright © 2005 by Vasekha, Motov.  相似文献   
2.
Ranges of stability and regions of the stoichiometric stability of sulfide phases of nickel(II) and cobalt(II) are determined in water–salt solutions. Regions of the homogeneity of NiS and CoS monosulfides are considered. The composition of a microemulsion used as a nanoreactor for synthesizing sulfides is determined, and its phase diagram is plotted. The results from estimating the size of the obtained nanocrystals are presented.  相似文献   
3.
The FeCl2-Na2SO3-H2O system was studied along seven sections with the molar ratios Na2SO3: FeCl2 = 5: 1, 5: 2, 5: 3, 5: 4, 5: 5, 5: 10, and 5: 15, including six points on each section where pH ranges from 1.5 to 4.0 in 0.5 steps. Equal-undersedimentation lines for cations and anions were plotted. The iron(II) system forms sodium ferrisulfites NaFe5O0.5(SO3)5 · 5H2O, NaHFe5(SO3)6 · 5H2O, Na2Fe5(SO3)6 · 4H2O, and NaHFe2(SO3)3; the iron(III) system forms Na2Fe6(SO3)7 · 10H2O. The regions where these compounds sediment were demarcated, and their characterizations were carried out.  相似文献   
4.
Possibility was examined of using spent solutions of sulfur dioxide gas sorbents, together with sodium sulfite and pyrosulfite, for conversion of iron hydrate wastes produced by copper-nickel industries to red iron oxide pigment.  相似文献   
5.
Pourbaix diagrams of Cu–H2SO4–H2O and Ni–H2SO4–H2O systems have been refined, and stability regions of the sulfite phases have been determined. State diagrams of double copper(I)–copper(II) and copper(I)–nickel(II) sulfites have been constructed. Double copper(I)–nickel(II) sulfite has been isolated from aqueous solutions saturated with sulfur dioxide. The solutions at different ratios of the metals have been studied by spectrophotometry; the isolated double sulfite has been studied by X-ray diffraction, IR spectroscopy, dispersion analysis, and thermal analysis. Fundamentals of thermodynamic prognostication of the Cu2SO3·MSO3 double sulfites synthesis have been elaborated.  相似文献   
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