全文获取类型
收费全文 | 702篇 |
免费 | 63篇 |
国内免费 | 13篇 |
专业分类
化学 | 526篇 |
晶体学 | 3篇 |
力学 | 45篇 |
数学 | 76篇 |
物理学 | 128篇 |
出版年
2024年 | 1篇 |
2023年 | 6篇 |
2022年 | 14篇 |
2021年 | 23篇 |
2020年 | 33篇 |
2019年 | 35篇 |
2018年 | 37篇 |
2017年 | 34篇 |
2016年 | 72篇 |
2015年 | 49篇 |
2014年 | 62篇 |
2013年 | 89篇 |
2012年 | 85篇 |
2011年 | 66篇 |
2010年 | 25篇 |
2009年 | 24篇 |
2008年 | 20篇 |
2007年 | 22篇 |
2006年 | 14篇 |
2005年 | 13篇 |
2004年 | 12篇 |
2003年 | 8篇 |
2002年 | 5篇 |
2001年 | 2篇 |
2000年 | 3篇 |
1999年 | 2篇 |
1997年 | 1篇 |
1995年 | 1篇 |
1994年 | 4篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1987年 | 2篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1980年 | 1篇 |
排序方式: 共有778条查询结果,搜索用时 15 毫秒
1.
Goudarzy Forough Zolgharnein Javad Alizadeh Vahid 《Journal of Analytical Chemistry》2022,77(6):711-716
Journal of Analytical Chemistry - In this article, a new spectrofluorometric method was developed for the determination of methamphetamine based on a turn-on luminescence response of captopril... 相似文献
2.
Hamid R. Memarian Mohammad Bagheri Dietrich D?pp 《Monatshefte für Chemie / Chemical Monthly》2004,42(3):833-838
In continuation of previous work some novel 3,5-diacetyl-1,4-dihydropyridine derivatives were synthesized and their photochemical behavior was studied under oxygen and argon atmosphere. Oxidation of the dihydropyridine ring and formation of pyridine derivatives was the result of the reaction. The presence of oxygen affects not only on the rate of oxidation, but also the formation of some unidentified by-products was observed on irradiation under this atmosphere. 相似文献
3.
Vahid Karimipour 《Letters in Mathematical Physics》1994,30(2):87-98
Quantum de Rham complexes on the quantum plane and the quantum group itself are constructed for the nonstandard deformation of Fun(SL(2)). It is shown that in contrast to the standardq-deformation of SL(2), the above complexes are unique for SL
h
(2). Also, as a byproduct, a new deformation of the two-dimensional Heisenberg algebra is obtained which can be used to construct models ofh-deformed quantum mechanics. 相似文献
4.
A. Bagheri K. L. Baluja Savita M. Datta 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1994,32(3):211-217
The density (N) dependence of electron mobility (μ) in various dense gases (H2, N2, O2, CO2 and rare gases) has been calculated using a multiple-scattering approach. Deviation of the high density gas from its perfect gas behaviour has been taken into account through the temperature-dependent second virial coefficient. Multiple scattering of electrons leads to shifts in their kinetic energy and it also changes their distribution functions. This unified approach predicts both positive and negative effects. The positive (negative) effect entails on increase (decrease) of μ withN. We have assessed the available data on momentum transfer cross-sections by comparing the mobility at very low densities (Nμ)0 with experimental results. The density dependence is studied by comparing the calculated ratioNμ)/Nμ)0 with the observed values and other theoretical work. The Legler model which assumes a constant cross-section is inadequate for predicting the observed density dependence. We obtain good agreement with available experimental work for all the atomic and molecular species studied here. 相似文献
5.
In this work a modified form of the Ghotbi–Vera Mean Spherical Approximation model (MGV-MSA) has been used to correlate the mean ionic activity coefficients (MIAC) for a number of symmetric and asymmetric aqueous electrolyte solutions at 25 °C. In the proposed model the hard sphere as well as the electrostatic contributions to the MIAC and the osmotic coefficient of the previously GV-MSA model has been modified. The results of the proposed model for the MIAC of the electrolyte solutions studied in this work are used to directly calculate the values of the osmotic coefficients without introducing any new adjustable parameter. In the MGV-MSA model the cation diameter as well as the relative permittivity of water depends on the electrolyte concentration. Having considered such dependency for both cation and relative permittivity for water in an electrolyte solution the modification of the GV-MSA has been made. It should be stated that in the MGV-MSA model the anion diameter in the solution similar to that in the GV-MSA model remains constant and independent of the electrolyte concentration. The results obtained from the proposed model have been favorably compared with those of the GV-MSA model. The results showed that the MGV-MSA model can more accurately correlate the MIAC of the single electrolyte solutions than those of the GV-MSA model. The same comparison has been observed in case of the osmotic coefficients for the electrolyte solutions studied in this work. It should be noted that in order to do an unequivocal comparison between the results obtained from the models used in this work the same minimization procedure and the same experimental data for the MIAC and the osmotic coefficients have been used. Also it should be mentioned that in the MGV-MSA model the conversion from the McMillan–Mayer (MM) framework to that of the Lewis–Randall (LR) has been performed. It has been concluded that such transformation can affect the results in particular at higher electrolyte concentrations. 相似文献
6.
The new thermotropic polyester/polyaniline (PIn/PAni) blends have been prepared by solution blend of synthesized liquid crystalline poly[4,4′‐bis (ω‐alkoxy) biphenylisophthalate]s having four and six methylene units in spacer (PI4 and PI6) with PAni doped with camphorsolfonic acid (CSA). The percolation threshold electroactivity of prepared blend films has been determined by cyclic voltammetry. The effect of the PAni concentration, solvent nature and polyester structure on the electroactivity of the blends has been investigated. The extremely low percolation threshold of prepared PIn/PAni‐CSA blends from dimethylformamide (DMF) and m‐cresol solution was 3% weight of PAni‐CSA. The amount of conducting polymer necessary to retard the formation of the liquid crystalline (LC) phase is up to 45% by weight. Phase behavior studies by differential scanning calorimetry and polarizing microscopy show that blends with 45% of conducting polymer are both liquid crystal and conductive. The morphology of the blends has been investigated by scanning electron microscopy. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
7.
A simple and selective method for rapid and efficient concentration and determination of μg l−1 levels of Au(III) ions in aqueous solution using octadecyl silica membrane disks modified by pentathia-15-crown-5 and flame atomic absorption spectrometry is presented. The influence of flow rates of eluent and sample solution, amount of ligand, types and least amount of eluent for elution of Au from disks were investigated. Break through volume and limit of detection of the membrane disks modified by 5 mg of the thiacrown ether was found to be 2.0 l and 1.0 μg l−1, respectively. The effects of various cationic interferences on percent recovery of gold were studied. The method was successfully applied for the determinations of gold in some pharmaceutical samples and for the recovery of trace Au3+ ions from synthetic and water samples. 相似文献
8.
Michael P. Doyle Robert L. Dow Vahid Bagheri William J. Patrie 《Tetrahedron letters》1980,21(29):2794-2798
Oxidations of 2,2-disubstituted-1,4-butanediols by the combination of nickel(II) bromide and benzoyl peroxide and by trityl tetrafluoroborate produce β,β-disubstituted-γ-butyrolactones with exceptional selectivity. 相似文献
9.
The reaction of an ethanolic solution 2,6‐pyridinedicarboxylic acid ( 1 , LH2) with TlNO3 in the presence of triethylamine led to the coordination polymer [Tl(LH)]n ( 2 ). The complex was characterized by elemental analysis, IR spectroscopy and single‐crystal X‐ray diffraction. Crystal data for 2 at –80 °C: monoclinic, space group I2/a, a = 696.1(1), b = 1190.6(2), c = 931.0(2) pm, β = 103.28(1)°, Z = 4, R1 = 0.0256. 相似文献
10.
Paul Müller Nicole Pautex Michael P. Doyle Vahid Bagheri 《Helvetica chimica acta》1990,73(5):1233-1241
The thermocatalytic rearrangements of cyclopropenes 1-4 have been investigated in the presence of Rh(IT) perfiuorobutyrate. 1, 2, 3-Triphenylcyclopropene ( 1a ) undergoes rearrangement lo diphenylindene 5a or, with alkoxycyclopropene derivatives, to α, β-unsaturated ketone 6. Furan formation occurs with 2, 3-diphenylcyclo-propenecarboxylate 2, but the diethyl counterpart 3 rearranges to dienoate 8. 2-Alkylcyclopropenecarboxylates 4 afforded (E)-methylidenecyclopentane derivatives 9 as the only isolable product in yields of ca. 35 %. A mechanism involving regio- and stereospecific cyclopropene ring opening to a Rh-complexed vinylcarbene and insertion of the latter into the C? H bond to give 9 is proposed. An analogous mechanism should account for the rearrangement products of 1 to 3 . 相似文献