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1.
Heavy ion irradiation in the electronic stopping power region induces macroscopic dimensional change in metallic glasses and introduces magnetic anisotropy in some magnetic materials. The present work is on the irradiation study of ferromagnetic metallic glasses, where both dimensional change and modification of magnetic anisotropy are expected. Magnetic anisotropy was measured using Mössbauer spectroscopy of virgin and irradiated Fe40Ni40B20 and Fe40Ni38Mo4B18 metallic glass ribbons. 90 MeV 127I beam was used for the irradiations. Irradiation doses were 5×1013 and 7.5×1013 ions/cm2. The relative intensity ratios D 23 of the second and third lines of the Mössbauer spectra were measured to determine the magnetic anisotropy. The virgin samples of both the materials display in-plane magnetic anisotropy, i.e., the spins are oriented parallel to the ribbon plane. Irradiation is found to cause reduction in magnetic anisotropy. Near-complete randomization of magnetic moments is observed at high irradiation doses. Correlation is found between the residual stresses introduced by ion irradiation and the change in magnetic anisotropy. 相似文献
2.
The static vessel pyrolysis of bicyclo[2.2.2]octa-2,5,7-triene (barrelene) has been studied between 483 and 523 K. The products were acetylene and benzene (in equal quantities) with no other detectable C8H8 isomer (down to less than 1% of total). The time dependence fitted first-order kinetics, and the data are consistent with a homogeneous unimolecular reaction close to, if not at, its high-pressure limit at 0.25 torr. The rate constant was fitted to the Arrhenius equation These Arrhenius parameters are shown to imply a concerted single-step process. Alternative mechanisms are discussed and a comparison is made with the retro-Diels—Alder reactions of other bicyclo[2.2.2]octa-olefin systems. 相似文献
3.
In subnormal glow discharge under d.c. excitation at different pressure in a varying transverse magnetic field (0 to 30 G)
some measurements have been carried out for various initial average tube currents. The voltage across the discharge increases
and average tube current and residual current decreases in the magnetic field. With the help of Beckman’s expression [4] for
the axial field and the electron density distribution in a transverse magnetic field the observed variation of current and
voltage can be satisfactorily explained. The variation of axial electric field with transverse magnetic field can be represented
to a fair degree of accuracy by the derived equation. The behaviour of residual current with magnetic field has been observed
in these oscillations. 相似文献
4.
A high-power linearly polarized Yb-doped silica fiber master oscillator power amplifier at 1150 nm is reported. It produced 3.35 W cw and 2.33 W of average power in 1 micros pulses at a 100 kHz repetition rate, both with 8 pm linewidth. This is the first report, to the best of our knowledge, of a high-power Yb-doped fiber amplifier at a wavelength longer than 1135 nm. The pulsed output was frequency doubled in a bulk periodically poled near-stoichiometric LiTaO(3) chip to generate 976 mW of average power at 575 nm with an overall system optical-to-optical efficiency of 9.8% with respect to launched pump power. 相似文献
5.
6.
We demonstrated a stable degenerate synchronously pumped femtosecond optical parametric oscillator (SPOPO) as a divide-by-2 subharmonic generator. The SPOPO exhibited passive all-optical self-phase-locking between the pump and signal/idler and thus required no external electronic feedback to produce the phase-locked subharmonic. We employed a type I phase-matched, 1-mm-long, periodically poled MgO:LiNbO3 crystal as the nonlinear gain element and an 80 MHz mode-locked Ti:sapphire laser with 180 fs pulses tuned at 775 nm as the pump. The SPOPO generated transform-limited 70 fs phase-locked output pulses centered at 1550 nm. The self-phase-locking operation was confirmed by separate beat-note measurement techniques with respect to the pump laser and with respect to an external cw laser. 相似文献
7.
DC Muddiman AP Null JC Hannis 《Rapid communications in mass spectrometry : RCM》1999,13(12):1201-1204
Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICRMS) has been used to determine the mass of a double-stranded 500 base-pair (bp) polymerase chain reaction (PCR) product with an average theoretical mass of the blunt-ended (i.e. unadenylated) species of 308 859.35 Da. The PCR product was generated from the linearized bacteriophage Lambda genome which is a double-stranded template. Utilization of ethanol precipitation in tandem with a rapid microdialysis step to purify and desalt the PCR product was crucial to obtain a precise mass measurement. The PCR product (0.8 pmol/μL) was electrosprayed from a solution containing 75% acetonitrile, 25 mM piperidine, and 25 mM imidazole and was infused at a rate of 200 nL/min. The average molecular mass and the corresponding precision were determined using the charge-states ranging from 172 to 235 net negative charges. The experimental mass and corresponding precision (reported as the 95% confidence interval of the mean) was 309 406 +/- 27 Da (87 ppm). The mass accuracy was compromised due to the fact that the PCR generates multiple products when using Taq polymerase due to the non-template directed 3'-adenylation. This results in a mixture of three PCR products with nearly identical mass (i.e. blunt-ended, mono-adenylated and di-adenylated) with unknown relative abundances that were not resolved in the spectrum. Thus, the experimental mass will be a weighted average of the three species which, under our experimental conditions, reflects a nearly equal concentration of the mono- and di-adenylated species. This report demonstrates that precise mass measurements of PCR products up to 309 kDa (500 bp) can be routinely obtained by ESI-FTICR requiring low femtomole amounts. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
8.
DC Bassett 《Macromolecular Symposia》1997,114(1):121-126
Molecular cilia, the uncrystallized portions of chains already partly attached to polymer crystals, exert a profound influence on the course of polymeric crystallization with ultimate responsibility for the divergence of adjacent lamellae which leads to spherulitic growth. Their effective size and pressure have been measured, in α-polypropylene, from electron microscopic measurements of the separation and maximum curvature of lamellae in row structures. That cilia exist and extend the effective region occupied by a lamella beyond the geometrical confines of its fold surfaces is important for crystallization theory and may well have implications for the connection of lamellae into networks and for gelation. 相似文献
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