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排序方式: 共有243条查询结果,搜索用时 15 毫秒
1.
I. V. Kuchin N. B. Ur’ev 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2007,81(3):349-353
The main rules governing the redistribution of microparticles in disperse systems were revealed by computer simulation. These rules predetermine the character and properties of the structure being formed, which opens up the possibility to control the properties of disperse materials, including sorbents and catalysts based on high-dispersity solid phases. 相似文献
2.
3.
Urška L. Štangar Urh Černigoj Polonca Trebše Ksenija Maver Silvia Gross 《Monatshefte für Chemie / Chemical Monthly》2006,137(5):647-655
Summary. Transparent TiO2 films with a high photodegradation activity towards an azo dye in aqueous solution were prepared by sol–gel processing. Films
on soda–lime glass supports protected with a thin silica barrier layer exhibited better crystallization and monodisperse nanoparticles,
higher absorption of light below 370 nm, and higher photocatalytic activity than those films deposited on bare glass supports
proving the detrimental effect of interdiffused sodium ions on the development of the anatase nanostructure. The effect of
substrate was more pronounced in thinner films (300 nm) than in thicker ones (1200 nm), which were achieved by adding a template
(i.e. Pluronic F127) to the sol. 相似文献
4.
A simple continuous flow generation of volatile bromine is described for the determination of low concentrations of the elements by atmospheric-pressure argon microwave induced plasma (MIP) surfatron. Bromine is continuously generated by mixing the bromide with sulphuric acid and hypochlorite solutions. The bromine vapor is separated from the aqueous phase by a gas-liquid separator and is desiccated by passing it through concentrated sulphuric acid. The detection limit attained was 2 microg/l. and the precision was +/-0.7% (at the 80 microg/l. level). The proposed determination is very selective if oxidizing/reducing agents are absent. The procedure has been tested for bromide determination in two drug preparations. Good agreement between the experimental results and the certified values has been obtained. 相似文献
5.
Ur?ka L. ?tangar Urh ?ernigoj Polonca Treb?e Ksenija Maver Silvia Gross 《Monatshefte für Chemie / Chemical Monthly》2006,1(6):647-655
Transparent TiO2 films with a high photodegradation activity towards an azo dye in aqueous solution were prepared by sol–gel processing. Films
on soda–lime glass supports protected with a thin silica barrier layer exhibited better crystallization and monodisperse nanoparticles,
higher absorption of light below 370 nm, and higher photocatalytic activity than those films deposited on bare glass supports
proving the detrimental effect of interdiffused sodium ions on the development of the anatase nanostructure. The effect of
substrate was more pronounced in thinner films (300 nm) than in thicker ones (1200 nm), which were achieved by adding a template
(i.e. Pluronic F127) to the sol. 相似文献
6.
N. V. Grishatova V. F. Ur’yash A. E. Gruzdeva N. V. Novoselova 《Russian Journal of Applied Chemistry》2006,79(12):1930-1934
The enthalpy of hydrolysis of potato starch and some starch-containing components of Lider-1 nutrition product for enteral (tube) feeding in the presence of α-amylase enzyme was studied on a DAK-1-1 differential microcalorimeter. 相似文献
7.
V. F. Ur’yash A. E. Gruzdeva N. Yu. Kokurina N. V. Grishatova L. A. Faminskaya 《Polymer Science Series A》2007,49(9):1020-1025
For the mixtures of pectin of different esterification degrees and water, heat capacities in the range of 80–320 K have been measured, and DTA measurements have been carried out in the range 80–450 K. The effect of water on the physical transitions of pectin has been studied, and the solubility of water in pectins of different esterification degrees at the temperature of melting of a liquid component has been determined. On the basis on the experimental data, the physical state diagram of the pectin-water system has been constructed and analyzed for the whole range of component concentrations within a wide temperature interval. 相似文献
8.
The principle of tandem on-line continuous separation techniques as an alternative means of introducing samples into plasmas was applied to the development of a sensitive, selective and convenient method for the determination of arsenic by inductively coupled plasma atomic emission spectrometry (ICP-AES). Arsenic is continuously extracted as AsI3 into xylene from the sample dissolved in 0.1 M potassium iodide solution in 7.2 M hydrochloric acid. The xylene phase (containing the analyte) is continuously mixed on-line with NaBH4 in dimethylformamide and acetic acid solutions. Arsine is thus continuously generated directly from the organic phase and is separated in a gas—liquid separation device which prevents most of the xylene phase vapour from reaching the ICP. The system was optimized for the continuous extraction of AsI3, the direct generation of arsine from xylene and the final ICP determination of arsenic. Finally, the tandem on-line continuous separation ICP detection system was applied to the determination of arsenic in real samples (white metal, cast iron, cupro-nickel and orchard leaves standard materials). Very good agreement between the experimental results and the certified values was obtained. 相似文献
9.
V. F. Ur’yash V. I. Sevast’yanov N. Yu. Kokurina Yu. V. Porunova N. V. Perova L. A. Faminskaya 《Russian Journal of General Chemistry》2006,76(9):1363-1367
The heat capacities of cattle and poultry collagen samples were measured by adiabatic calorimetry in the range 80–330 K. The temperatures of physical transitions in these samples were determined. Endothermic relaxation transitions (γ1, γ2, and β) were observed in the heat capacity curves of the studied collagen samples. The solubility of water in collagen samples obtained from various sources was determined by calorimetry from the enthalpy of melting of the “free” water phase. 相似文献
10.
Lucija Jukić Urška Bratušek Marko Škof Jurij Svete Branko Stanovnik 《Chemistry of Heterocyclic Compounds》1996,32(11-12):1295-1299
A novel approach to the synthesis of 3-acylindolizines and the transformations of some acids into tryptophane analogues are described. Reaction of ethyl 2-pyridinylacetate and methyl 2-quinolinylacetate with N-trifluoroacetyl-5-bromo-4-oxonorvaline methylester led to N-trifluoroacetyl-3-(1-ethoxycarbonylindolizinyl-2) alanine methyl ester and N-trifluoroacetyl-3-(3-methoxycarbonylpyrrolo [1,2-a]quinolinyl-2) alanine methyl ester, respectively. Treatment of ethyl 2-pyridinylacetate and 2-pyridinylacetonitrile, first with N,N-dimethylformamide dimethyl acetal (DMFDMA), followed by reaction with phenacyl bromide, gave the corresponding 3-benzoylindolizines, while the reaction of ethyl 2-pyridinylacetate and 2-pyridinylacetonitrile with DMFDMA, followed by treatment with (S)-N-trifluoroacetyl-5-bromo-4-oxonorvaline methyl ester, gave the corresponding N-trifluoroacetyl-4-oxo-4-(indolizinyl-3)homoalanine methyl esters. 相似文献