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1.
Synthesis and application of cinnamate-functionalized rubber for the preparation of UV-curable films
A butyl rubber derivative that can be cured upon exposure to UV light in the absence of additional chemical additives was developed. This polymer was prepared by the reaction of hydroxyl-functionalized butyl rubber with cinnamoyl chloride to provide a cinnamate functionalized rubber. The cinnamate content was varied by starting with derivatives prepared from butyl rubber containing either 2 or 7 mol% isoprene. The kinetics of the cross-linking was studied by UV–visible spectroscopy and it was found to vary according to the film thickness. The changes in gel content and volume swelling ratio with irradiation time were dependent on the cinnamate content. Toxicity studies suggested that the cross-linked materials do not leach toxic molecules. The approach was also applied to obtain cross-linked films of butyl rubber-poly(ethylene oxide) graft copolymers, leading to surfaces that resisted the adhesion and growth of cells. Thus the approach is versatile and is of particular interest when non-leaching coatings of cross-linked butyl rubber are desired for biomedical or other applications. 相似文献
2.
Mojtaba Abbasian Nafiseh Khakpour Aali Solmaz Esmaeily Shoja 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(9):966-975
A method to prepare zinc oxide (ZnO) nanoparticles with a covalently bonded poly(methyl methacrylate) (PMMA) shell by surface initiated atom transfer radical polymerization (ATRP) was reported. First, the initiator for ATRP was covalently bonded onto the surface of zinc oxide nanoparticles through our novel method. Firstly, the surface of ZnO nanoparticle was treated with 3-aminopropyl triethoxysilane, a silane coupling agent, and then this functionalization nanoparticle was reacted with α-chloro phenyl acetyl chloride to prepare atom transfer radical polymerization macroinitiator. The metal-catalyzed radical polymerization of MMA with ZnOmacroinitiator was performed using a copper catalyst system to give the ZnO-based nanoparticles hybrids linking PMMA segments (poly (methyl methacrylate)/zinc oxide nanocomposite). These hybrid nanoparticles had an exceptionally good dispersability in organic solvents and were subjected to detailed characterization using FTIR, TEM and TGA and DSC analyzed. 相似文献
3.
Yaghoubi-berijani Marzieh Bahramian Bahram Zargari Solmaz 《Research on Chemical Intermediates》2020,46(1):197-213
Research on Chemical Intermediates - The bismuth oxybromide (BiOBr) photocatalyst was first synthesized via a simple co-precipitation method. To improve the visible light photocatalytic activity of... 相似文献
4.
Coupling of CFD Simulations and Population Balance Modeling to Predict Brownian Coagulation in an Emulsion Polymerization Reactor 下载免费PDF全文
In this study a framework consisting of a computational fluid dynamics simulation coupled to a population balance model for the modeling of emulsion polymerizations is proposed. The combined approach is used to understand the impact of changing length and time scales, as well as mixing conditions on the particle size distribution (PSD) of a polymer latex under different conditions. It is shown that the effect of agitation rate can have a profound impact on the distribution of ionic species in the reactor, and thus on the evolution of the PSD.
5.
Solmaz Aslanzadeh Andreas Berg Mohammad J. Taherzadeh Ilona Sárvári Horváth 《Applied biochemistry and biotechnology》2014,172(6):2998-3008
Lignocellulosic biomass represents a great potential for biogas production. However, a suitable pretreatment is needed to improve their digestibility. This study investigates the effects of an organic solvent, N-Methylmorpholine-N-oxide (NMMO) at temperatures of 120 and 90 °C, NMMO concentrations of 75 and 85 % and treatment times of 3 and 15 h on the methane yield. The long-term effects of the treatment were determined by a semicontinuous experiment. The best results were obtained using 75 % NMMO at 120 °C for 15 h, resulting in 141 % increase in the methane production. These conditions led to a decrease by 9 % and an increase by 8 % in the lignin and in the carbohydrate content, respectively. During the continuous digestion experiments, a specific biogas production rate of 92 NmL/gVS/day was achieved while the corresponding rate from the untreated sample was 53 NmL/gVS/day. The operation conditions were set at 4.4 gVS/L/day organic loading rate (OLR) and hydraulic retention time (HRT) of 20 days in both cases. NMMO pretreatment has substantially improved the digestibility of forest residues. The present study shows the possibilities of this pretreatment method; however, an economic and technical assessment of its industrial use needs to be performed in the future. 相似文献
6.
Mohsen Padervand Solmaz Ghaffari Mahdieh Mohammad Nejad 《Journal of Analytical Chemistry》2017,72(5):567-574
Sunitinib malate, as an anticancer compound and a multi-targeted tyrosine-kinase inhibitor for treatment of glioma, was comprehensively studied by using different liquid chromatography methods. Since sunitinib malate shows Z-E isomerism, various reverse phase high performance liquid chromatography (RP-HPLC) programs were designed to access quantitative determination and good separation of Z-E stereoisomers. Moreover, some impurities including N-oxide and impurity B were to be separated from the main isomer with acceptable resolution. In the present work, different RP-HPLC programs were developed in which the type of mobile phase, flow rate, pH, and temperature were optimized to reach the best analysis conditions and control the rate of Z to E conversion. In addition, the effect of some operational parameters during the solution preparation including initial concentration of the analyte, temperature, pH, and type of solvent on the stability of Z isomer were investigated. The opted conditions for quantitative analysis were C8-Hector column as stationary phase, methanol as solvent, ammonium acetate buffer containing triethylamine as mobile phase, the pH of mobile phase of 8.5, the flow rate of 1.0 mL/min, and detection at 425 nm. In this situation the peaks of E and Z isomers were at 16.3 and 19.7 min. Full validation of the designed method was done based on ICH guidelines. 相似文献
7.
Molecular Diversity - This study describes the use of 3-aminotriazole, different aldehydes and N-methyl-1-(methylthio)-2-nitroethenamine as a ketene N,S-acetal in a three-component condensation for... 相似文献
8.
In this paper we have considered a red-shift based linear correction in derivative of action in the context of vacuum f (R) gravity. Here we have found out that the linear correction may describe the late time acceleration which is appeared by
SuperNovae Ia with no need of dark energy. Also we have calculated the asymptotic action for the desired correction. The value
of all solutions may reduce to de’ Sitter universe in the absence of correction term. 相似文献
9.
Abstract
The characterization of an optical sensor membrane is described for the determination of tin (II) based on the immobilization of dithizone on a triacetylcellulose membrane. The membrane responds to tin (II) ions by changing color reversibly from green to red in buffer solution at pH 6 and wavelength 611 nm. This optode has a linear range of 0.3–6.33 μg cm−3 (2.52–53.32 μmol dm−3) of Sn2+ ions with a limit of detection of 0.15 μg cm−3 (1.26 μmol dm−3). The response time of the optode was about 8–10 min depending on the concentration of Sn2+ ions. The selectivity of the optode to tin (II) ions at pH 6 was good. The sensor can be readily regenerated by exposure with EDTA solution. The color is fully reversible, and the optical sensor could be fully regenerated. Experimental results showed that the optode could be used as an effective tool in analyzing the tin content in canned foods. 相似文献10.
Solmaz Hajizadeh Harald Kirsebom Igor Y. Galaev Bo Mattiasson 《Journal of separation science》2010,33(12):1752-1759
Bromate, which is a potential carcinogen, should be removed from drinking water to levels of less than 10 μg/L. A chitosan‐based molecularly imprinted polymer (MIP) and a sol–gel ion‐exchange double hydrous oxide (Fe2O3·Al2O3·xH2O) adsorbent (inorganic adsorbent) were prepared for this purpose. The sorption behavior of each adsorbent including sorption kinetics, isotherms, effect of pH and selective sorption were investigated in detail. Sorption experimental results showed that the MIP adsorbents had better selectivity for bromate, even in the presence of high concentrations of nitrate, as compared to the inorganic adsorbent. It was found that pH does not affect the adsorption of bromate when using the inorganic adsorbent. Additionally, both adsorbents were immobilized in a polymeric cryogel inside plastic carriers to make them more practical for using in larger scale. Regeneration of the cryogels either containing MIP or inorganic adsorbents were carried out by 0.1 M NaOH and 0.1 M NaCl, respectively. It was found that the regenerated MIP and inorganic adsorbents could be used at least three and five times, respectively, without any loss in their sorption capacity. 相似文献