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1.
A theoretical and experimental study is made on light diffraction from holographic diffraction gratings, recorded in cubic photorefractive crystals Bi12SiO20 with (110) cut, for two orientation of the grating wave vector,K [001] andK [110], when an external electric field is applied. 相似文献
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This paper presents a detailed analysis of the electro-optic behavior of suspensions of noninteracting monodisperse beta-FeOOH particles. The electro-optic parameters are determined for aqueous suspensions of the oxide particles and the influences of surface charge and Debye layer thickness are verified. Since the conventional method of frequency analysis is inconsistent in the low-frequency range, new electro-optic parameters are introduced to define the frequency variation of the effects. Electric polarizability is determined with precision to a constant, and its relative variations are followed. As reported for other oxides, electric polarizability correlates with charge variations in the diffuse part of the particle surface electric layer, and its relaxation frequency increases with surface charge density, indicating a Maxwell-Wagner type of surface polarization. The alternating component of the responses yields particle relaxation frequency and the phase shift of the responses at this frequency. For all studied samples the phase shift at particle relaxation frequency is 45 degrees. The relative changes in the steady component of the responses in the low-frequency range are followed by field intensity curves at characteristic frequencies of the samples. Electrophoretic rotation is the process consistent with our data for the low-frequency effect. The results show that it is enhanced by the combined actions of low or slowly relaxing polarizability and significant electrophoretic mobility. 相似文献
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We demonstrate reversible photoinduced in situ reorientation of low molecular mass liquid crystals (LCs) by means of photoaddressable polymers (PAPs). These polymers contain mesogenic azobenzene side chains optimized to reorient cooperatively and effectively upon illumination with polarized light. Various low molecular mass LCs were introduced between two PAP layers and these sandwich devices were tested with respect to stability and reversibility of photoinduced orientation. Dissolution of the PAP layer by the low molecular mass LC was observed for several material combinations and systematically investigated. Different anisotropic dyes were added as fluorescence markers in order to monitor the photoinduced LC orientation. With an optimized material combination, more than 10 reversible reorientation processes could be realized with polarized light of either 514 or 405 nm wavelength, without any reduction in alignment quality. Further, microscopic polarized fluorescence patterns could be produced and erased within short exposure times. 相似文献
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L. S. Uspenskaya T. Nurgaliev B. Blagoev T. Donchev S. Miteva 《Bulletin of the Russian Academy of Sciences: Physics》2008,72(4):540-542
The change in the magnetic domain structure due to the proximity of a superconductor has been experimentally investigated for the first time. The complex character of magnetization reversal at temperatures below critical, caused by the mutual long-range effect of a superconductor and a magnet, has been shown. In particular, it is found that even magnetization reversal of the heterostructure by an in-plane field leads to the formation of Abrikosov vortices in the superconductor, carrying a flux perpendicularly to the film plane. It is shown that this is a consequence of the transformation of narrow domain walls into wide stripes due to the interaction with scattering fields from the superconductor. In turn, after penetration of the magnetic flux into the superconductor at some depth, the scattering fields cause backward magnetization reversal of the external film edge, as a result of which vortices with oppositely directed fluxes enter the crystal and propagate in the superconductor bulk in the form of chains along twins, as in the case of magnetization by a perpendicular magnetic field. Thus, at longitudinal magnetization, the flux enters the superconducting film in the form of wide stripes with alternating perpendicular induction, which is explained by the long-range interaction of the scattering fields of the superconductor with the manganite magnetization. 相似文献
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Heinz‐Georg Nothofer Andreas Meisel Tzenka Miteva Dieter Neher Michael Forster Masao Oda Günter Lieser Dessislava Sainova Akio Yasuda Donald Lupo Wolfgang Knoll Ullrich Scherf 《Macromolecular Symposia》2000,154(1):139-148
A series of 9,9‐dialkyl‐poly(fluorene‐2,7‐diyl)s containing linear and branched alkyl substituents with a Mn of up to 200000 g/mol has been synthesized. Moreover, some of the polymers were end capped with a suitable hole transport functionality, such as a triphenylamine derivative, to improve their charge transport properties and to control the molecular weight. The thermal alignment of these novel polymers on a rubbed polyimide layer led to highly anisotropic film formation with dichroic ratios (absorption parallel and perpendicular to the rubbing direction) of up to 26 in absorption and 21 in emission. 相似文献
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David Lagorce Tania Pencheva Bruno O Villoutreix Maria A Miteva 《BMC chemical biology》2009,9(1):6-10
Background
Discovery of new bioactive molecules that could enter drug discovery programs or that could serve as chemical probes is a very complex and costly endeavor. Structure-based and ligand-based in silico screening approaches are nowadays extensively used to complement experimental screening approaches in order to increase the effectiveness of the process and facilitating the screening of thousands or millions of small molecules against a biomolecular target. Both in silico screening methods require as input a suitable chemical compound collection and most often the 3D structure of the small molecules has to be generated since compounds are usually delivered in 1D SMILES, CANSMILES or in 2D SDF formats. 相似文献8.
The presented study provides a possibility to create ultrafiltration (UF), polyacrylonitrile(PAN)/butadiene-acrylonitrile elastomer (BNR)/N,N-dimethylformamide (DMF) membranes. Influence of different concentrations of the elastomer on the formation of a more porous structure was studied and compared with that observed using membranes made of polyacrylonitrile. Specific influence of copper ions in a solution of polymers on the formation of an asymmetric selective layer was also monitored. The study was conducted to prepare membranes with high efficiency in emulsion and colloidal systems separation. 相似文献
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The processes used by academic and industrial scientists to discover new drugs have recently experienced a true renaissance with many new and exciting techniques. The number of protein structures and/or chemical ligands is constantly growing, through the use of parallel chemistry, X-ray crystallography, NMR or homology modeling methods and so is the theoretical understanding of protein-ligand interactions. As such, structure-based approaches to drug-design and in silico screening are becoming routine part of most modern lead discovery programs. Prioritization of compound libraries is an extremely important task that aims at the rapid identification of tight-binding ligands and ultimately new therapeutic compounds. These in silico approaches combined with other experimental methods facilitate the design of new medicines to treat cardiovascular, degenerative, infectious, and neoplastic diseases, among others. Here, we review key concepts and specific features of several selected ligand-receptor docking/scoring methods while several other topics pertaining to the field of in silico screening are reviewed in the following articles of this special issue of Current Protein and Peptide Science. 相似文献
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Baluschev S Miteva T Yakutkin V Nelles G Yasuda A Wegner G 《Physical review letters》2006,97(14):143903
We demonstrate up-conversion of noncoherent sunlight realized by ultralow excitation intensity. The bimolecular up-conversion process in our systems relies on the presence of a metastable triplet excited state, and thus has dramatically different photophysical characteristics relative to the other known methods for photon up-conversion (two-photon absorption, parametric processes, second harmonic generation, sequential multiphoton absorption, etc.). 相似文献