紫外光照射下 Fe-碳纳米管/TiO2 复合材料降解罗丹明 B

 The composites comprising Fe-carbon nanotubes (CNTs) on TiO2 were prepared by a modified sol-gel method and characterized by nitrogen adsorption, scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and energy dispersive X-ray analysis. The photocatalytic decomposition of rhodamine B (Rh.B) under UV irradiation and air aeration catalyzed by the composites was measured. The photocatalytic activity of TiO2 nanoparticles was significantly enhanced by the large CNT network that facilitated electron transfer between adsorbed Rh.B molecules and the catalyst substrate and the simultaneous occurrence of the photo-Fenton reaction in the presence of Fe particles. A marked acceleration of the decomposition rate was observed with aeration by flowing air aeration due to the formation of the circulatory photo-Fenton system. Chemical oxygen demand of piggery waste was measured at regular intervals to evaluate the mineralization of wastewater.     

Dynamic behaviour of an axially moving plate undergoing small cylindrical deformation submerged in axially flowing ideal fluid

The out-of-plane dynamic response of a moving plate, travelling between two rollers at a constant velocity, is studied, taking into account the mutual interaction between the vibrating plate and the surrounding, axially flowing ideal fluid. Transverse displacement of the plate (assumed cylindrical) is described by an integro-differential equation that includes a local inertia term, Coriolis and centrifugal forces, the aerodynamic reaction of the external medium, the vertical projection of membrane tension, the bending resistance, and external perturbation forces. In the two-dimensional model thus set up, the aerodynamic reaction is found analytically as a functional of the cylindrical displacement, using the techniques of complex analysis. The resulting integro-differential problem is discretized in space with the Fourier-Galerkin method, and integrated in time with the diagonalization method. Examples are computed with physical parameters corresponding to air and some paper materials. The effects of the surrounding fluid on the critical velocity and first natural frequency are investigated, for stationary air, for an air mass moving with the plate, and for some arbitrary axial fluid velocities. The obtained results are applicable for both an ideal membrane and a plate with nonzero bending rigidity.     

简单水热法合成石墨-CdSe复合材料及其光催化降解有机染料(英文)

A graphene-CdSe composite was synthesized by a facile hydrothermal method,and characterized by X-ray diffraction,scanning electron microscopy with energy dispersive X-ray analysis,transmission electron microscopy and UV-vis diffuse reflectance spectrophotometry.The graphene-CdSe composite efficiently catalyzed the photodegradation of methylene blue(MB),methyl orange(MO) and rhodamine B(Rh.B) in aqueous solution under UV or visible light irradiation.The graphene-CdSe composite exhibited a higher photocatalyt...     

Fabrication and Characterization of Tailored TiO_2 and WO_3/MWCNT Composites for Methylene Blue Decomposition

A sol-gel method was used to prepare WO3/MWCNT-TiO2 composites.Their photocatalytic activities were evaluated by the degradation of methylene blue (MB) solution under UV light.The catalysts were characterized by X-ray diffraction,specific surface area measurement,energy-dispersive X-ray analysis,transmission and scanning electron microscopy.Aqueous MB solutions of 100 ml were photodegraded by a small amount of the WO3/MWCNT-TiO2 composite under UV light irradiation.The photocatalytic data showed that the WO...     

CoS2-碳(C60,石墨,碳纳米管)/TiO2复合光敏剂光降解有机染料（英文）

CoS2,CoS 2-C60 /TiO2,CoS2-CNT/TiO2,and CoS2-Graphene/TiO2 were prepared.The TiO2 products had the anatase phase structure and interesting surface compositions.X-ray diffraction patterns of the CoS2-carbon/TiO2 composites showed a single and clear anatase phase and the CoS2 structure.Scanning electron microscopy characterization of the texture on the CoS 2-carbon/TiO2 composites showed a homogenous composition.Energy-dispersive X-ray spectra for elemental identification showed the presence of C and Ti with strong Co and S peaks from the CoS2-carbon/TiO2 composites.The composites obtained were also characterized by transmission electron microscopy and UV-Vis spectroscopy.CoS2-carbon/TiO2 composites showed excellent photocatalytic activity for the degradation of methylene blue under visible light irradiation.This was attributed to both photocatalysis on the TiO2 support and charge transfer by the carbon nanomaterial,and the introduction of CoS2 to enhance transfer of photogenerated electrons.     

Dynamic analysis for axially moving viscoelastic panels

In this study, stability and dynamic behaviour of axially moving viscoelastic panels are investigated with the help of the classical modal analysis. We use the flat panel theory combined with the Kelvin–Voigt viscoelastic constitutive model, and we include the material derivative in the viscoelastic relations. Complex eigenvalues for the moving viscoelastic panel are studied with respect to the panel velocity, and the corresponding eigenfunctions are found using central finite differences. The governing equation for the transverse displacement of the panel is of fifth order in space, and thus five boundary conditions are set for the problem. The fifth condition is derived and set at the in-flow end for clamped–clamped and clamped-simply supported panels. The numerical results suggest that the moving viscoelastic panel undergoes divergence instability for low values of viscosity. They also show that the critical panel velocity increases when viscosity is increased and that the viscoelastic panel does not experience instability with a sufficiently high viscosity coefficient. For the cases with low viscosity, the modes and velocities corresponding to divergence instability are found numerically. We also report that the value of bending rigidity (bending stiffness) affects the distance between the divergence velocity and the flutter velocity: the higher the bending rigidity, the larger the distance.     

Determination of soman and VX degradation products by an aspiration ion mobility spectrometry

An aspiration type ion mobility spectrometry (IMS) has been used to determine chemical warfare agent (CWA) degradation products from liquid samples. This technique is based on ion mobility which depends on the molecular weight, charge and shape. With this method, it is possible to measure the mobility distribution of positive and negative ion clusters simultaneously in six different electrodes. Each measuring electrode determines a different portion of the ion mobility distribution formed within the cell’s radioactive source. The strongest responses for all CWA degradation products and 2-propanol were seen in the order of sixth, fifth and second channels. On the basis of projection calculation, the fingerprints for 2-propanol and soman (GD; pinacolyl methylphosphonofluoridate) and VX o-ethyl-S-[2(diisopropylamino)ethyl] methylphosphonothioate) degradation products can be separated from each other. The detection levels for ethyl methylphosphonate (EMPA), pinacolyl methylphosphonate (PMPA), and ethylphosphonic acid (EPA) were 37.2 (37.2 μg/ml), 54.1 (54.1 μg/ml) and 55.1 ppm (55.1 μg/ml), respectively. However, the separation efficiency between different CWA degradation products was quite poor. The projections of these compounds were between 0.9976 and 0.9989, and this means that these fingerprints were identical. Thus, it is only possible to get one profile for all these degradation products of soman and VX. The data provided show that IMS is suitable as a simple technique for screening of CWA degradation products.