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1.
McElroy Tucker S. Politis Dimitris N. 《Statistical Inference for Stochastic Processes》2022,25(3):471-483
Statistical Inference for Stochastic Processes - The problem of linear interpolation in the context of a multivariate time series having multiple (possibly non-consecutive) missing values is... 相似文献
2.
Tevian Dray Corinne A. Manogue Robin W. Tucker 《General Relativity and Gravitation》1991,23(8):967-971
We consider the (massless) scalar field on 2-dimensional manifolds whose metric changes signature and which admit a spacelike isometry. Choosing the wave equation so that there will be a conserved Klein-Gordon product implicitly determines the junction conditions one needs to impose in order to obtain global solutions. The resulting mix of positive and negative frequencies produced by the presence of Euclidean regions depends only on the total width of the regions, and not on the detailed form of the metric.This essay received honorable mention in the 1991 competition of the Gravity Research Foundation. 相似文献
3.
Thresholds for the detection of the direction of travel of a moving sound source were determined in a single-interval, forced-choice paradigm. Both the rate at which the sound source is displaced (8 degrees-128 degrees/s) and the frequency of the signal to be localized (500-3700 Hz) affect dynamic spatial resolution. There is an inverse relationship between spatial resolution and the rate of travel, a finding that replicates an earlier observation on performance with sources displaced at high velocities [Perrott and Musicant, J. Acoust. Soc. Am. 62, 1463-1466 (1977)]. However, the magnitude of this effect depends on the actual velocities employed. Relatively small changes in spatial resolution are apparent for velocities below approximately 32 degrees/s. The significant frequency effect can be summarized as follows: Dynamic spatial resolution is better for signals below 1000 Hz than for signals above this value (within the range tested). Particularly poor resolution is evident for signals between 1300-2000 Hz. The present results indicate that signal frequency affects dynamic spatial resolution in a fashion similar to that which has been observed in the more common "static" localization test situation. There is no indication of an interaction between these two variables. These results provide additional support for the hypothesis that both static and dynamic spatial discrimination functions are dependent upon the same underlying mechanisms. The effects of velocity upon the spatial resolution problem, a unique aspect of the dynamic paradigm, can probably be explained without the necessity of additional hypothetical mechanisms in the auditory system (e.g., a specialized motion detector). 相似文献
4.
5.
Tucker M. P. Farmer J. D. Keller F. A. Schell D. J. Nguyan Q. A. 《Applied biochemistry and biotechnology》1998,(1):25-35
Single-stage cocurrent dilute acid pretreatments were carried out on yellow poplar (Liriodendron tulipifera) sawdust using an as-installed and short residence time modified pilot-scale Sunds hydrolyzer and a 4-L bench-scale NREL
digester (steam explosion reactor). Pretreatment conditions for the Sunds hydrolyzer, installed in the NREL process development
unit (PDU), which operates at 1 t/d (bone-dry t) feed rate, spanned the temperature range of 160 – 210°C, 0.1 – 1.0% (w/w)
sulfuric acid, and 4-10-min residence times. The batch pretreatments of yellow poplar sawdust in the bench-scale digester
were carried out at 210 and 230°C, 0.26% (w/w) sulfuric acid, and 1-, 3-, and 4-min residence times. The dilute acid prehydrolysis
solubilized more than 90% of the hemicellulose, and increased the enzymatic digestibility of the cellulose that remained in
the solids. Compositional analysis of the pretreated solids and liquors and mass balance data show that the two pretreatment
devices had similar pretreatment performance. 相似文献
6.
3-Methyl-2-butenenitrile (1) cyclodimerised on treatment with lithium diisopropylamide in dimethoxyethane at temperatures between ?78°C and 0°C to 3-amino-4-cyano-1,5,5-trimethyl-1,3-cyclohexadiene (2) the structure of which was established by acid hydrolysis to the known 4-cyano-1,5,5-trimethyl-1-cyclohexene-3-one (3). 相似文献
7.
The calculation of rovibrational transition energies and intensities is often hampered by the fact that vibrational states are strongly coupled by Coriolis terms. Because it invalidates the use of perturbation theory for the purpose of decoupling these states, the coupling makes it difficult to analyze spectra and to extract information from them. One either ignores the problem and hopes that the effect of the coupling is minimal or one is forced to diagonalize effective rovibrational matrices (rather than diagonalizing effective rotational matrices). In this paper we apply a procedure, based on a quantum mechanical canonical transformation for deriving decoupled effective rotational Hamiltonians. In previous papers we have used this technique to compute energy levels. In this paper we show that it can also be applied to determine intensities. The ideas are applied to the ethylene molecule. 相似文献
8.
In this paper we propose a scheme for choosing basis functions for quantum dynamics calculations. Direct product bases are frequently used. The number of direct product functions required to converge a spectrum, compute a rate constant, etc., is so large that direct product calculations are impossible for molecules or reacting systems with more than four atoms. It is common to extract a smaller working basis from a huge direct product basis by removing some of the product functions. We advocate a build and prune strategy of this type. The one-dimensional (1D) functions from which we build the direct product basis are chosen to satisfy two conditions: (1) they nearly diagonalize the full Hamiltonian matrix; (2) they minimize off-diagonal matrix elements that couple basis functions with diagonal elements close to those of the energy levels we wish to compute. By imposing these conditions we increase the number of product functions that can be removed from the multidimensional basis without degrading the accuracy of computed energy levels. Two basic types of 1D basis functions are in common use: eigenfunctions of 1D Hamiltonians and discrete variable representation (DVR) functions. Both have advantages and disadvantages. The 1D functions we propose are intermediate between the 1D eigenfunction functions and the DVR functions. If the coupling is very weak, they are very nearly 1D eigenfunction functions. As the strength of the coupling is increased they resemble more closely DVR functions. We assess the usefulness of our basis by applying it to model 6D, 8D, and 16D Hamiltonians with various coupling strengths. We find approximately linear scaling. 相似文献
9.
QI Qu Edward Tucker Sherril D. Christian 《Journal of inclusion phenomena and macrocyclic chemistry》2002,43(3-4):213-222
A series of sulfoalkyl ether -cyclodextrin derivatives, including sulfoethyl, sulfopropyl and sulfobutyl ethyl -cyclodextrins, have been synthesized and characterized. Each sulfoalkyl ether -cyclodextrin is a mixture of various degrees of substitution and different positional isotherms. Elemental analysis, 1H NMR, MS, and Differential Scanning Calorimetry analysis were used to determine the average degree of substitution for each -cyclodextrin derivative. The average degrees of substitution are 3.4, 1.6 and 2.5 for sulfoethyl, sulfopropyl and sulfobutyl ether -cyclodextrin, respectively. The water solubility of these derivatives is substantially higher than that of -cyclodextrin. 1H NMR indicates thatsulfoethyl ether -cyclodextrin may have major substitution on the secondaryhydroxyl group while the major substitution in sulfopropyl and sulfobutyl ether-cyclodextrin could be on the primary hydroxyl group. MS spectra showthat no more than one substitution occurred on a single glucose unit. 相似文献
10.
A comparison of some results from Xα-scattered wave (Xα-SW) and extended Hückel (EH) calculations for metal clusters is given. It is found that small clusters of atoms (≈ 13 atoms) using the Xα-SW method reproduce many of the features of the electronic structure of the bulk metals, whereas this is not the case for the same clusters using the EH method. A more systematic approach to EH parametrizations is suggested in order to make this method a more viable approach to treating metal clusters. 相似文献