排序方式: 共有19条查询结果,搜索用时 13 毫秒
1.
Anelia Achanova Ivan Zhelyazkov Tsvetelina Petrova 《Czechoslovak Journal of Physics》2004,54(2):211-223
Microwave discharges produced by travelling/standing electromagnetic waves have drawn considerable attention in recent years
due to their wide application in microelectronic industry. Here are presented the axial distributions of the electrons and
ions as well as those of excited atoms in an argon microwave discharge at a low gas pressure (400 mTorr) sustained by a 2.45
GHz travelling dipolar electromagnetic wave. The numerical calculations are based on a self-consistent kinetic-electrodynamic
model and the results obtained are in a good agreement with the experimental data. The model yields also the magnitude of
the wave power sustaining the discharge and the axial profiles of all electromagnetic-wave characteristics and the axial distribution
of the neutral gas temperature. 相似文献
2.
Novel interconnection scheme for thin‐film silicon solar modules with conductive intermediate reflector
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Bugra Turan Andreas Bauer Andreas Lambertz Tsvetelina Merdzhanova Stefan Haas 《固体物理学:研究快报》2015,9(2):103-107
Intermediate reflector layers are commonly used for light man‐agement purposes in multi‐junction silicon based devices containing a‐Si:H top‐ and µc‐Si:H bottom‐sub‐cells. A low resistance of such layers can have a severe impact on the solar module performance due to shunting of the bottom sub‐cell by the P2 scribe. A common solution for this problem is the use of an additional scribe line. However, not only the additional processing step is disadvantageous but also the dead area losses are increased as well by the additional scribe. This work introduces a novel solar cell stripe interconnection scheme that requires only three scribing processes with similar dead area losses as they would be apparent in the standard interconnection scheme. An implementation to mini modules shows no negative impact on the electrical properties and simultaneously reducing the required number of scribing steps. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献
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Tsvetelina Doncheva Nadezhda Kostova Violeta Valcheva Radostina Toshkovska Vassil Vutov Stefan Philipov 《Natural product research》2020,34(5):668-674
AbstractNew isoquinoline alkaloid hypepontine (1) together with a five known compounds, were identified in Hypecoum ponticum Velen, the partial synonym of Hypecoum procumbens L. The structure of the new substance was elucidated based on spectroscopic evidence. The tertiary and quaternary alkaloid mixtures as well as the isolated alkaloids were evaluated for their antibacterial and antifungal activity. The result revealed that the crude alkaloid mixture containing quaternary isoquinoline alkaloids showed potent antifungal and antibacterial activity. 相似文献
5.
[reaction: see text] A novel ring opening ring closing metathesis (ROM-RCM) was demonstrated for cyclic conjugated dienes, effecting the excision of a C(2)H(2) unit and a net ring contraction. Applying the ring contraction metathesis, new 14-membered ring macrolide antibiotics were synthesized in a single step from existing 16-membered ring macrolides. This new class of macrolide antibiotics will provide access to new therapeutics for the treatment of macrolide-resistant bacterial infections. 相似文献
6.
Tsvetelina Doncheva Amgalan Solongo Nadezhda Kostova Yadamsuren Gerelt-Od Dangaa Selenge 《Natural product research》2015,29(9):853-856
A new type of isoquinoline alkaloid leptopyrine was isolated from the aerial parts of Leptopyrum fumarioides L. (Ranunculaceae) of Mongolian origin. The known alkaloids protopine and thalifoline were isolated for the first time from this the species. All structures were established by physical and spectral analyses. 相似文献
7.
Alexander Vasil'kov Tsvetelina Batsalova Balik Dzhambazov Alexander Naumkin 《Surface and interface analysis : SIA》2022,54(3):189-202
Silver and copper nanoparticles were produced by an ecologically safe metal vapor synthesis (MVS) method using acetone as an organic dispersion medium. Transmission electron microscopy (TEM) showed that the specimens are spherical and polydisperse, and their average size is 2.5 nm for silver nanoparticles (Ag NPs) and 2.6 nm for copper nanoparticles (Cu NPs). X-ray photoelectron spectroscopy analyses showed that the state of silver in the nanoparticles is close to that of silver in the Ag0 state, whereas copper black contains two oxidized states of the metal—Cu+ and Cu2+. Biological in vitro studies demonstrated that the nanoparticles have antibacterial activity against Gram-positive and Gram-negative bacterial species. Cu NPs exhibited more prominent antibacterial effects and induced significant growth inhibition of Bacillus cereus and Escherichia coli. Both types of nanoparticles showed anticancer properties in vitro. Cu NPs induced intense cytotoxicity in cancer and normal fibroblasts in vitro cultures, but their inhibitory effect against noncancerous cells was milder compared with cancer cell lines. Ag NPs demonstrated selective cytotoxicity against human lung and cervical adenocarcinoma cell lines. Further in vitro studies indicated that the mechanism of Ag NPs and Cu NPs anticancer effects involves induction of apoptosis. The present study describes a green synthesis approach for production of biologically active silver and copper nanoparticles and highlights their potential for medical application. 相似文献
8.
Ralitsa H. Georgieva Paunka S. Vassileva Albena K. Detcheva Dimitrinka K. Voykova Tsvetelina I. Gerganova Yordanka Y. Ivanova 《Central European Journal of Chemistry》2012,10(5):1484-1494
The adsorption properties of two new nanostructured hybrid materials containing B2O3 and ZrO2 were studied. The new organic-inorganic materials were synthesized via a sol-gel method. As a modifying agent, a quantity of 10 wt.% Zr(OPr)4 or B(OCH3)3 was added. The structure of the hybrid materials was investigated by means of (Fourier transform infrared spectroscopy (FTIR), x-ray diffractometry (XRD), scanning electron microscopy (SEM), (atomic force microscopy (AFM) and nuclear magnetic resonance spectroscopy (NMR). Based on the obtained data, the most probable cross-linking mechanism for the derived gels was proposed. The characterization of texture parameters of both materials was carried out with the use of low-temperature adsorption of nitrogen. Adsorption of Cu(II), Fe(III), Cr(III), Cd(II) and Pb(II) ions on both materials was investigated using multi-component solutions with different concentrations and acidity by means of the batch method. Kinetics of adsorption was also investigated. Pseudo-first order, pseudo-second order and intraparticle diffusion models were used to analyze kinetic data. The adsorption was significantly affected by the pH value. Equilibrium data were fitted to linear Langmuir, Freundlich and Dubinin-Radushkevich models and maximum adsorption capacities were calculated. 相似文献
9.
Yordanka Y. Ivanova Tsvetelina I. Gerganova M. Helena V. Fernandes Isabel M. Miranda Salvado 《Central European Journal of Chemistry》2009,7(1):42-46
Nanostructured hybrid materials containing Al2O3 were synthesized via a sol-gel method through hydrolysis and co-condensation reactions using trimethylsilyl isocyanate (TMSI) as a new silica
source in the presence of tetramethoxysilane (TMOS) and three different quantities (10, 20 and 30 wt.%) of aluminum sec-butoxide
(Al(OBusec)3 as a modifying agent. The xerogel nanostructured materials are pyrolyzed in nitrogen atmosphere in the temperature range
from 400°C to 1100°C. The transformation of the xerogel hybrid networks into Al-Si oxycarbonitride materials has been investigated
by XRD, FTIR, SEM, AFM, and 29Si MAS-NMR. To the best of our knowledge, the work reported here is the first synthesis of porous di-urethanesils modified
with aluminum and one of the few examples of alumosilica oxycarbonitride materials
相似文献
10.
Yordanka Y. Ivanova Yanko B. Dimitriev Tsvetelina I. Gerganova Raina G. Bryaskova Maria H. V. Fernandes Isabel M. Miranda Salvado 《Central European Journal of Chemistry》2005,3(3):452-469
This work investigates the influence of the precursor trimethylsilil isocyanate on the sol-gel synthesis of hybrid materials.
The obtained Si−O−C−N network is additionally modified by titanium and zirconium alcoxypropoxides in the range of 10 to 30
wt. %. The structure of the obtained hybrid materials before and after pyrolysis up to 1100°C was investigated by methods
of XRD, FTIR and 29Si MAS NMR. We established that the hybrid structure was stable up to 600°C based on IR study. The structural transformation
of the hybrid materials into oxycarbonitrogen system started at 800°C. The network of the hybrids modified by titanium remained
stable and amorphous up to the final temperature of the pyrolysis (1100°C) compared to the gels modified by more than 10 wt.%
Zr. It was confirmed by XRD analysis that the last mentioned are nanocomposite materials, built from carbooxynitrogen vitreous
matrix and ZrO2-nanocrystals (tetragonal). The NMR method verified the presence of heterometallic bonds (Si−O−Ti and Si−O−Zr) and Q4, ZrQ3 or TiQ3, NSiO3 and D structural units in the gels. 相似文献