全文获取类型
收费全文 | 1409篇 |
免费 | 84篇 |
国内免费 | 3篇 |
专业分类
化学 | 1130篇 |
晶体学 | 18篇 |
力学 | 26篇 |
数学 | 73篇 |
物理学 | 249篇 |
出版年
2023年 | 15篇 |
2022年 | 17篇 |
2021年 | 9篇 |
2020年 | 26篇 |
2019年 | 29篇 |
2018年 | 16篇 |
2017年 | 10篇 |
2016年 | 47篇 |
2015年 | 35篇 |
2014年 | 46篇 |
2013年 | 64篇 |
2012年 | 89篇 |
2011年 | 129篇 |
2010年 | 52篇 |
2009年 | 53篇 |
2008年 | 105篇 |
2007年 | 78篇 |
2006年 | 97篇 |
2005年 | 91篇 |
2004年 | 86篇 |
2003年 | 69篇 |
2002年 | 58篇 |
2001年 | 23篇 |
2000年 | 17篇 |
1999年 | 13篇 |
1998年 | 12篇 |
1997年 | 11篇 |
1996年 | 13篇 |
1995年 | 12篇 |
1994年 | 17篇 |
1993年 | 5篇 |
1992年 | 11篇 |
1991年 | 15篇 |
1990年 | 7篇 |
1989年 | 10篇 |
1988年 | 8篇 |
1987年 | 6篇 |
1986年 | 8篇 |
1985年 | 5篇 |
1984年 | 8篇 |
1983年 | 11篇 |
1982年 | 9篇 |
1981年 | 8篇 |
1980年 | 9篇 |
1979年 | 9篇 |
1978年 | 9篇 |
1976年 | 3篇 |
1975年 | 3篇 |
1974年 | 3篇 |
1971年 | 2篇 |
排序方式: 共有1496条查询结果,搜索用时 15 毫秒
1.
2.
Watanabe Sou Senzaki Tatsuya Shibata Atsuhiro Nomura Kazunori Takeuchi Masayuki Nakatani Kiyoharu Matsuura Haruaki Horiuchi Yusuke Arai Tsuyoshi 《Journal of Radioanalytical and Nuclear Chemistry》2019,322(3):1273-1277
Journal of Radioanalytical and Nuclear Chemistry - Extraction chromatography flow-sheet employing octyl(phenyl)-N,N-diisobutylcarbonoylmethylphosphine oxide and bis(2-ethylhexyl) hydrogen phosphate... 相似文献
3.
Kouichi Akahane Naokatsu Yamamoto Naoki Ohtani 《Physica E: Low-dimensional Systems and Nanostructures》2004,21(2-4):295
We fabricated InAs quantum dots (QDs) with a GaAsSb strain-reducing layer (SRL) on a GaAs(0 0 1) substrate. The wavelength of emission from InAs QD is shown to be controllable by changing the composition and thickness of the SRL. An increase in photoluminescence intensity with increasing compositions of Sb and thickness of the GaAsSb SRL is also seen. The efficiency of radiative recombination was improved under both conditions because the InAs/GaAsSb/GaAs hetero-interface band structure more effectively suppressed carrier escape from the InAs QDs. 相似文献
4.
Xinjiang Chen Goh Matsuo Bunsho Ohtani Kaoru Tsujii 《Journal of polymer science. Part A, Polymer chemistry》2007,45(21):4891-4900
A racemic amphiphilic monomer, n‐dodecyl glyceryl itaconate (DGI), forms bilayer membranes in water in the presence of small amount of ionic cosurfactant and shows iridescent color. A chiral DGI, S‐DGI, also shows an iridescent property, but with a rather red shift in the color, which can be ascribed to the increased packing density of the monomer in the bilayer membranes. Chrial DGI has a more compact packing density than racemic one owing to closer distance between the monomer molecules; the conversion rate, however, is slower than that of racemic one when H2O2 is used as an initiator. When the initiator is changed to an amphiphilic one, 4‐(2‐hydroxyethoxy) phenyl‐(2‐hydroxy‐2‐propyl) ketone (Irgacure 2959), the chiral DGI shows even a little faster conversion rate than that of racemic one. The NMR chemical shift results of protons in benzene ring show that the molecules of Irgacure 2959 insert into the bilayer membranes. The molecular weights of the corresponding polymers prove that the initiation by H2O2 is restricted compared to that by Irgacure 2959. It is concluded that the decelerated polymerization behavior of chiral DGI initiated by H2O2 is a result of limited diffusion of the initiator into the lamellar bilayer structures. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4891–4900, 2007 相似文献
5.
Tsuyoshi Kitamura 《Tetrahedron》2004,60(43):9649-9657
Synthesis of (+)-anthramycin was examined. A pyrrolobenzodiazepine skeleton could be synthesized by reductive cyclization of pyrrolidine derivative, which was obtained by enyne metathesis. The conjugated enamide ester part of (+)-anthramycin derivative was constructed by cross-metathesis. 相似文献
6.
The double-bond conversion of UV-cured resins prepared from pentaerythritol triacrylate (PETA) was determined by pyrolysis-gas chromatography in the presence of an organic alkali, tetramethylammonium hydroxide (TMAH). The pyrogram of the uncured prepolymer compound, consisting of PETA and a photoinitiator, 2,2-dimethoxy-2-phenylacetophenone, contained specific products reflecting the original acrylate structure, such as methyl acrylate (MA) and methyl ethers of pentaerithritol. Meanwhile, in pyrograms of the UV-cured PETA, the yields of MA considerably decreased. The double-bond conversions of the cured resins, irradiated with various UV dosages, were calculated based on the relative yields of MA among specific products in the pyrograms. The conversions determined by this approach were analyzed by comparing them with those estimated by Fourier-transform infrared spectroscopy. 相似文献
7.
It was found that a beta-fructofuranosidase produced by Microbacterium sp. H-1 has potent trans-beta-fructofuranosylation activity from sucrose (donor). By means of this enzyme system, rebaudioside A (RA), the second major sweet steviol glycoside of the leaves of Stevia rebaudiana, was subjected to transfructosylation, affording a mono-beta-fructofuranosylated product (RA-F) in a high yield. The structure of RA-F was elucidated as beta-D-fructofuranosyl-(2----6)-beta-D-glucopyranosyl ester of steviol-13-O-[beta-D-glucopyranosyl-(1----2)]- [beta-D-glucopyranosyl-(1----3)]-beta-D-glucopyranoside. Some improvement in the quality of sweetness was observed for RA-F. 相似文献
8.
9.
Tsuyoshi Katayama 《Queueing Systems》1992,11(3):299-306
This paper derives a conservation law for mean waiting times in a single-server multi-class service queueing system (M
X/G/1 type queue) with setup times which may be dependent on multiple customer classes and its arrival batch size by using the work decomposition property in the queueing system with vacations. 相似文献
10.
We investigate low-temperature behaviors of a system with chirality-pair interaction on a one-dimensional lattice. In the course of the investigation, we evaluate asymptotic forms of the characteristic values of the integral equation satisfied by the Mathieu functions. It turns out that the low-temperature behavior of correlation length of the chirality-pair correlation function is different from the one for the Ising model of spin ±1 but akin to the one for the Ising model of infinite spin. 相似文献