全文获取类型
收费全文 | 1030篇 |
免费 | 29篇 |
国内免费 | 3篇 |
专业分类
化学 | 772篇 |
晶体学 | 10篇 |
力学 | 17篇 |
数学 | 53篇 |
物理学 | 210篇 |
出版年
2022年 | 8篇 |
2021年 | 6篇 |
2019年 | 18篇 |
2018年 | 12篇 |
2017年 | 12篇 |
2016年 | 25篇 |
2015年 | 19篇 |
2014年 | 10篇 |
2013年 | 31篇 |
2012年 | 61篇 |
2011年 | 62篇 |
2010年 | 29篇 |
2009年 | 38篇 |
2008年 | 72篇 |
2007年 | 44篇 |
2006年 | 54篇 |
2005年 | 60篇 |
2004年 | 50篇 |
2003年 | 53篇 |
2002年 | 35篇 |
2001年 | 17篇 |
2000年 | 25篇 |
1999年 | 10篇 |
1998年 | 10篇 |
1997年 | 11篇 |
1996年 | 10篇 |
1995年 | 9篇 |
1994年 | 10篇 |
1993年 | 12篇 |
1992年 | 21篇 |
1991年 | 19篇 |
1990年 | 19篇 |
1989年 | 8篇 |
1988年 | 10篇 |
1987年 | 14篇 |
1986年 | 14篇 |
1985年 | 13篇 |
1984年 | 6篇 |
1983年 | 6篇 |
1982年 | 7篇 |
1981年 | 6篇 |
1980年 | 10篇 |
1979年 | 7篇 |
1978年 | 12篇 |
1976年 | 11篇 |
1975年 | 8篇 |
1974年 | 9篇 |
1972年 | 6篇 |
1970年 | 6篇 |
1969年 | 8篇 |
排序方式: 共有1062条查询结果,搜索用时 15 毫秒
1.
Yumi ShimadaMakoto Nakamura Toshimasa SuzukaJunji Matsui Ryo TatsumiKen Tsutsumi Tsumoru MorimotoHideo Kurosawa Kiyomi Kakiuchi 《Tetrahedron letters》2003,44(7):1401-1403
A new method for the construction of the AB-ring core of Taxol was developed utilizing a new skeletal transformation protocol as a pivotal step. The acid-catalyzed rearrangement of the cyclopentenone-allene photoadduct gave a bridged seven-membered ketone, which was easily transformed, using the intramolecular Suzuki reaction and the oxidative cleavage of the vicinal diol, to the bicyclic diketone. 相似文献
2.
Various topological properties of projective duality between real projective varieties and their duals are obtained by making use of the microlocal theory of (subanalytically) constructible sheaves developed by Kashiwara [M. Kashiwara, Index theorem for constructible sheaves, Astérisque 130 (1985) 193-209] and Kashiwara-Schapira [M. Kashiwara, P. Schapira, Sheaves on Manifolds, Grundlehren Math. Wiss., vol. 292, Springer, Berlin-Heidelberg-New York, 1990]. In particular, we prove in the real setting some results similar to the ones proved by Ernström in the complex case [L. Ernström, Topological Radon transforms and the local Euler obstruction, Duke Math. J. 76 (1994) 1-21]. For this purpose, we describe the characteristic cycles of topological Radon transforms of constructible functions in terms of curvatures of strata in real projective spaces. 相似文献
3.
4.
Atsushi Ikeda Tsukasa HatanoToshifumi Konishi Jun-ichi KikuchiSeiji Shinkai 《Tetrahedron》2003,59(19):3537-3540
In a light-to-photocurrent conversion system based on a C60-porphyrin bilayer prepared by electrostatic alternate adsorption, porphyrin units in a porphyrin polymer have been isolated by cyclodextrin utilizing the host-guest interaction. In this system, a high quantum yield was achieved by suppression of self-quenching of porphyrin units. 相似文献
5.
Atsushi Ikeda Masaru Kawaguchi Yoshio Suzuki Tsukasa Hatano Munenori Numata Seiji Shinkai Akio Ohta Makoto Ohta 《Journal of inclusion phenomena and macrocyclic chemistry》2000,38(1-4):163-170
The calixarene-fullerene interaction,which causes only a slight change in the absorptionspectra, has been substantiated by calorimetricmeasurements: the H° values arecomparable with those obtained from the associationconstants estimated by a spectroscopic method. Furthermore, we determined the association constantbetween homooxacalix[3]arene and [60]fullerenederivatives with a porphyrin moiety by fluorescencespectra. 相似文献
6.
Some o-xylylene (o-quinodimethane) derivatives were isolated as stable cyrstalline materials. A strong through-bond interaction in tetracyanoethylene addition product of tetraphenylbenzodicyclobutadiene ( is suggested. 相似文献
7.
Masatoshi Oue Akira Ishigaki Keiichi Kimura Yousuke Matsui Toshiyuki Shono 《Journal of polymer science. Part A, Polymer chemistry》1985,23(7):2033-2042
Poly- and bis(thiacrown ether) derivatives in which some oxygen atoms of benzocrown ether moiety are replaced by sulfur atoms have been synthesized. Their cation-binding abilities were investigated by using the solvent extraction method. The poly- and bis(benzothiacrown ether)s showed great affinity for silver ion, being more excellent in the affinity than the corresponding monocyclic analogs. They, however, possess very poor cation-binding ability for alkali and alkaline-earth metal ions. The poly- and bis(thiacrown ether)s also bind mercuric ions effectively, whereas the corresponding monomeric analogs do not at all. 相似文献
8.
9.
Satoshi Ito Kazuya Koizumi Katsuhiko Fukuda Naohiro Kameta Tsukasa Ikeda Toru Oba Kazuhisa Hiratani 《Tetrahedron letters》2006,47(48):8563-8566
A new series of BINOL-based macrocycles with two phenolic protons have been synthesized via oxidative coupling reaction using CuCl(OH)-TMEDA. 相似文献
10.
Toru Takagishi Naoki Matsui 《Journal of polymer science. Part A, Polymer chemistry》1987,25(9):2511-2520
The extent of binding of chrome violet, which is a monoazo dye and involves two hydroxyl groups in o and o′ positions to azo group, by polyvinylpyrrolidone is markedly enhanced in the presence of Co2+ ion. The amount of binding in the presence of 1 × 10?4 mol/L of Co2+ ion increases by a factor of about 10 compared to that in the absence of the metal ion. Ni2+ and Zn2+ ions do not perceptively influence the binding affinity of the dye. Cu2+ ion, in contrast, suppresses the binding. To investigate further the action of added metal ions, a cobalt–complex dye was prepared and its binding property for the polymer was compared to that of chrome violet in the presence of metal ions. Some possible mechanisms for the enhancement of chrome violet binding by the addition of Co2+ ion are described. 相似文献