On the causes of strength differences in molded plastics filled with mineral powder fillers

It has been established by investigating the effect of common mineral powder fillers on the rate and depth of resin cure that such additions may have an inhibiting or catalytic influence on the hardening process, depending on their nature and method of preparation. The fillers which catalyze the hardening process increase the strength and heat resistance of the cured plastics. When introduced in small amounts into resins used as binders for unsized glass fibers, these fillers equalize the rate and depth of cure in the resin layers, thus increasing the strength and heat stability of glass-reinforced plastics.Mekhanika Polimerov, Vol. 1, No. 5, pp. 58–65, 1965     

Stresses in various resins cured on glass films

By using Sanzharovskii's method for determining the stresses in lacquer coatings and employing as a model a layer of resin deposited on a glass film, it is possible to simulate the processes that take place in glass-reinforced plastics and determine the stresses that develop in different resins cured under various conditions. The method proposed makes it possible to estimate the effect on the stresses of the shrinkage of the resin, its elasticity, and the difference in the coefficients of thermal expansion of the resin and the glass. Such an investigation is desirable before selecting the composition of the resin, additional organic or mineral fillers and elasticizers, and the optimal curing regime for glass-reinforced plastics.All-Union Scientific-Research Institute of Aviation Materials, Moscow. Translated from Mekhanika Polimerov, No. 3, pp. 481–486, May–June, 1969.     

Investigation of the modulus of elasticity of carbon fibers

A simplified analysis of the dependence of the elastic properties and electrical conductivity of a carbon fiber on its orientation index is presented. The experimentally confirmed inverse correlation between the electrical resistivity and the speed of sound makes it possible to calculate the modulus of elasticity of carbon fibers from data on the bulk resistivity.Moscow Aviation Technological Institute. Translated from Mekhanika Polimerov, No. 5, pp. 846–850, September–October, 1971.     

Formation of a PIII−C(sp2) bond by addition of diphenyl(trimethylsilyl)phosphine to activated acetylenes

Diphenyl(trimethylsilyl)phosphine reacts with alkoxy(alkyl)acetylenes to give mixtures of addition products, (2-alkoxy-2-trimethylsilylalkenyl)diphenylphosphines and (2-alkoxyalkenyl)diphenylphosphines. The reaction is sensitive to the solvent; in MeCN, it gives only nonsilylated products. (1-Alkoxyethenyl)diphenylphosphines were obtained as the main products upon the reaction of Ph₂PSiMe₃ with terminal alkoxyalkynes, irrespective of the reaction conditions. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1792–1796, September, 1998.     

Strength of welded joints in polymer films and means of increasing it

The behavior of welded joints in films of elastic and rigid polymers under delaminating and shearing loads is analyzed. A dependence of the strength of welded joints on the character of stress distribution in them and the deformation properties of the material being welded is indicated. In this connection, means of raising the strength of lap and T-shaped joints are examined, which consist in lowering the stress concentration in them by increasing the volume of material in the seam zone which absorbs the load, or in strengthening it in the direction of action of the distorting force.     

Effect of elevated temperatures on the strength of cured resins and resin-based materials

An analysis of the relationship between the relative changes of compressive strength and weight loss for glass laminates has shown that at elevated temperatures (to 600° C) the changes in strength are primarily caused by processes of mechanical destruction of the resin phase. The process of thermo-oxidative degradation of the resin in the laminate is described by the same stages as were detected in studying cured resins.Moscow Aviation-Engineering Institute. Translated from Mekhanika Polimerov, Vol. 4, No. 5, pp. 832–838, September–October, 1968.     

Effect of elevated temperatures on the strength of cured resins and resin-based materials

Measurement of the loss of weight and ultimate compressive strength of phenol-formaldehyde resins under the influence of elevated temperatures has shown that during thermal degradation there is an abrupt transition from a first to a second and third structural stage with steadily increasing stabilization of the strength properties. Apart from the dependence on the heat treatment conditions, all the resins investigated were found to give a straight-line relation between the relative change in ultimate compressive strength and the relative change in weight for each structural stage. The investigation was conducted on standard specimens obtained by molding a mixture of hardening resin and the same resin in precured powdered form.